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note
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Using data provided in ref 13, a cross-ring Si-Si distance of 2.720 Å was calculated for 3.
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Some examples: (a) Fehlner, T. P. In Inorganometallic Chemistry; Fehlner, T. P., Ed.; Plenum: New York, 1992; Chapter 2. (b) Whitmire, K. H. Adv. Organmet. Chem. 1998, 42, 1-145. (c) Mathur, P. Adv. Organomet. Chem. 1997, 41, 243-314. (d) Lotz, S.; van Rooyen, P. H.; Meyer, R. Adv. Organomet. Chem. 1995, 37, 219-320, (e) Pindado, G. J.; Thorton-Pett, M.; Bochmann, M. Chem. Commun. 1997, 609-610. (f) Üffing, C.; Ecker, A.; Köppe, R.; Schnöckel, H. Organometallics 1998, 17, 2373-2375. (g) Garcia, J. J.; Arevalo, A.; Montile, V.; Del Rio, F.; Quiroz, B.; Adams, H.; Maitlis, P. M. Organometallics 1997, 16, 3216-3220. (h) Jemmis, E. D.; Giju, K. T. Angew. Chem., Int. Ed. Engl. 1997, 36, 606-608. (i) Klabunde, T.; Krebs, B. Struct. Bonding 1997, 89, 177-198. (j) Negeshi, E. Chem. Eur. J. 1999, 5, 411-420. (k) Schäfer, K.-O.; Bittl, R.; Zweygart, W.; Lendzian, F.; Haselhorst, G.; Weymüller, T.; Wiegardt, K.; Lubitz, W. J. Am. Chem. Soc. 1998, 120, 13104-13120. (l) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1999, 121, 117-127. (m) Lee, D.; Lippard, S. J. J. Am. Chem. Soc. 1998, 120, 12153-12154.
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Some examples: (a) Fehlner, T. P. In Inorganometallic Chemistry; Fehlner, T. P., Ed.; Plenum: New York, 1992; Chapter 2. (b) Whitmire, K. H. Adv. Organmet. Chem. 1998, 42, 1-145. (c) Mathur, P. Adv. Organomet. Chem. 1997, 41, 243-314. (d) Lotz, S.; van Rooyen, P. H.; Meyer, R. Adv. Organomet. Chem. 1995, 37, 219-320, (e) Pindado, G. J.; Thorton-Pett, M.; Bochmann, M. Chem. Commun. 1997, 609-610. (f) Üffing, C.; Ecker, A.; Köppe, R.; Schnöckel, H. Organometallics 1998, 17, 2373-2375. (g) Garcia, J. J.; Arevalo, A.; Montile, V.; Del Rio, F.; Quiroz, B.; Adams, H.; Maitlis, P. M. Organometallics 1997, 16, 3216-3220. (h) Jemmis, E. D.; Giju, K. T. Angew. Chem., Int. Ed. Engl. 1997, 36, 606-608. (i) Klabunde, T.; Krebs, B. Struct. Bonding 1997, 89, 177-198. (j) Negeshi, E. Chem. Eur. J. 1999, 5, 411-420. (k) Schäfer, K.-O.; Bittl, R.; Zweygart, W.; Lendzian, F.; Haselhorst, G.; Weymüller, T.; Wiegardt, K.; Lubitz, W. J. Am. Chem. Soc. 1998, 120, 13104-13120. (l) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1999, 121, 117-127. (m) Lee, D.; Lippard, S. J. J. Am. Chem. Soc. 1998, 120, 12153-12154.
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Some examples: (a) Fehlner, T. P. In Inorganometallic Chemistry; Fehlner, T. P., Ed.; Plenum: New York, 1992; Chapter 2. (b) Whitmire, K. H. Adv. Organmet. Chem. 1998, 42, 1-145. (c) Mathur, P. Adv. Organomet. Chem. 1997, 41, 243-314. (d) Lotz, S.; van Rooyen, P. H.; Meyer, R. Adv. Organomet. Chem. 1995, 37, 219-320, (e) Pindado, G. J.; Thorton-Pett, M.; Bochmann, M. Chem. Commun. 1997, 609-610. (f) Üffing, C.; Ecker, A.; Köppe, R.; Schnöckel, H. Organometallics 1998, 17, 2373-2375. (g) Garcia, J. J.; Arevalo, A.; Montile, V.; Del Rio, F.; Quiroz, B.; Adams, H.; Maitlis, P. M. Organometallics 1997, 16, 3216-3220. (h) Jemmis, E. D.; Giju, K. T. Angew. Chem., Int. Ed. Engl. 1997, 36, 606-608. (i) Klabunde, T.; Krebs, B. Struct. Bonding 1997, 89, 177-198. (j) Negeshi, E. Chem. Eur. J. 1999, 5, 411-420. (k) Schäfer, K.-O.; Bittl, R.; Zweygart, W.; Lendzian, F.; Haselhorst, G.; Weymüller, T.; Wiegardt, K.; Lubitz, W. J. Am. Chem. Soc. 1998, 120, 13104-13120. (l) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1999, 121, 117-127. (m) Lee, D.; Lippard, S. J. J. Am. Chem. Soc. 1998, 120, 12153-12154.
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Some examples: (a) Fehlner, T. P. In Inorganometallic Chemistry; Fehlner, T. P., Ed.; Plenum: New York, 1992; Chapter 2. (b) Whitmire, K. H. Adv. Organmet. Chem. 1998, 42, 1-145. (c) Mathur, P. Adv. Organomet. Chem. 1997, 41, 243-314. (d) Lotz, S.; van Rooyen, P. H.; Meyer, R. Adv. Organomet. Chem. 1995, 37, 219-320, (e) Pindado, G. J.; Thorton-Pett, M.; Bochmann, M. Chem. Commun. 1997, 609-610. (f) Üffing, C.; Ecker, A.; Köppe, R.; Schnöckel, H. Organometallics 1998, 17, 2373-2375. (g) Garcia, J. J.; Arevalo, A.; Montile, V.; Del Rio, F.; Quiroz, B.; Adams, H.; Maitlis, P. M. Organometallics 1997, 16, 3216-3220. (h) Jemmis, E. D.; Giju, K. T. Angew. Chem., Int. Ed. Engl. 1997, 36, 606-608. (i) Klabunde, T.; Krebs, B. Struct. Bonding 1997, 89, 177-198. (j) Negeshi, E. Chem. Eur. J. 1999, 5, 411-420. (k) Schäfer, K.-O.; Bittl, R.; Zweygart, W.; Lendzian, F.; Haselhorst, G.; Weymüller, T.; Wiegardt, K.; Lubitz, W. J. Am. Chem. Soc. 1998, 120, 13104-13120. (l) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1999, 121, 117-127. (m) Lee, D.; Lippard, S. J. J. Am. Chem. Soc. 1998, 120, 12153-12154.
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Some examples: (a) Fehlner, T. P. In Inorganometallic Chemistry; Fehlner, T. P., Ed.; Plenum: New York, 1992; Chapter 2. (b) Whitmire, K. H. Adv. Organmet. Chem. 1998, 42, 1-145. (c) Mathur, P. Adv. Organomet. Chem. 1997, 41, 243-314. (d) Lotz, S.; van Rooyen, P. H.; Meyer, R. Adv. Organomet. Chem. 1995, 37, 219-320, (e) Pindado, G. J.; Thorton-Pett, M.; Bochmann, M. Chem. Commun. 1997, 609-610. (f) Üffing, C.; Ecker, A.; Köppe, R.; Schnöckel, H. Organometallics 1998, 17, 2373-2375. (g) Garcia, J. J.; Arevalo, A.; Montile, V.; Del Rio, F.; Quiroz, B.; Adams, H.; Maitlis, P. M. Organometallics 1997, 16, 3216-3220. (h) Jemmis, E. D.; Giju, K. T. Angew. Chem., Int. Ed. Engl. 1997, 36, 606-608. (i) Klabunde, T.; Krebs, B. Struct. Bonding 1997, 89, 177-198. (j) Negeshi, E. Chem. Eur. J. 1999, 5, 411-420. (k) Schäfer, K.-O.; Bittl, R.; Zweygart, W.; Lendzian, F.; Haselhorst, G.; Weymüller, T.; Wiegardt, K.; Lubitz, W. J. Am. Chem. Soc. 1998, 120, 13104-13120. (l) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1999, 121, 117-127. (m) Lee, D.; Lippard, S. J. J. Am. Chem. Soc. 1998, 120, 12153-12154.
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Some examples: (a) Fehlner, T. P. In Inorganometallic Chemistry; Fehlner, T. P., Ed.; Plenum: New York, 1992; Chapter 2. (b) Whitmire, K. H. Adv. Organmet. Chem. 1998, 42, 1-145. (c) Mathur, P. Adv. Organomet. Chem. 1997, 41, 243-314. (d) Lotz, S.; van Rooyen, P. H.; Meyer, R. Adv. Organomet. Chem. 1995, 37, 219-320, (e) Pindado, G. J.; Thorton-Pett, M.; Bochmann, M. Chem. Commun. 1997, 609-610. (f) Üffing, C.; Ecker, A.; Köppe, R.; Schnöckel, H. Organometallics 1998, 17, 2373-2375. (g) Garcia, J. J.; Arevalo, A.; Montile, V.; Del Rio, F.; Quiroz, B.; Adams, H.; Maitlis, P. M. Organometallics 1997, 16, 3216-3220. (h) Jemmis, E. D.; Giju, K. T. Angew. Chem., Int. Ed. Engl. 1997, 36, 606-608. (i) Klabunde, T.; Krebs, B. Struct. Bonding 1997, 89, 177-198. (j) Negeshi, E. Chem. Eur. J. 1999, 5, 411-420. (k) Schäfer, K.-O.; Bittl, R.; Zweygart, W.; Lendzian, F.; Haselhorst, G.; Weymüller, T.; Wiegardt, K.; Lubitz, W. J. Am. Chem. Soc. 1998, 120, 13104-13120. (l) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1999, 121, 117-127. (m) Lee, D.; Lippard, S. J. J. Am. Chem. Soc. 1998, 120, 12153-12154.
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Some examples: (a) Fehlner, T. P. In Inorganometallic Chemistry; Fehlner, T. P., Ed.; Plenum: New York, 1992; Chapter 2. (b) Whitmire, K. H. Adv. Organmet. Chem. 1998, 42, 1-145. (c) Mathur, P. Adv. Organomet. Chem. 1997, 41, 243-314. (d) Lotz, S.; van Rooyen, P. H.; Meyer, R. Adv. Organomet. Chem. 1995, 37, 219-320, (e) Pindado, G. J.; Thorton-Pett, M.; Bochmann, M. Chem. Commun. 1997, 609-610. (f) Üffing, C.; Ecker, A.; Köppe, R.; Schnöckel, H. Organometallics 1998, 17, 2373-2375. (g) Garcia, J. J.; Arevalo, A.; Montile, V.; Del Rio, F.; Quiroz, B.; Adams, H.; Maitlis, P. M. Organometallics 1997, 16, 3216-3220. (h) Jemmis, E. D.; Giju, K. T. Angew. Chem., Int. Ed. Engl. 1997, 36, 606-608. (i) Klabunde, T.; Krebs, B. Struct. Bonding 1997, 89, 177-198. (j) Negeshi, E. Chem. Eur. J. 1999, 5, 411-420. (k) Schäfer, K.-O.; Bittl, R.; Zweygart, W.; Lendzian, F.; Haselhorst, G.; Weymüller, T.; Wiegardt, K.; Lubitz, W. J. Am. Chem. Soc. 1998, 120, 13104-13120. (l) Siegbahn, P. E. M.; Crabtree, R. H. J. Am. Chem. Soc. 1999, 121, 117-127. (m) Lee, D.; Lippard, S. J. J. Am. Chem. Soc. 1998, 120, 12153-12154.
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85037479404
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Spectra that illustrate the complex splitting pattern are shown in ref 10
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Spectra that illustrate the complex splitting pattern are shown in ref 10.
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65
-
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85037449033
-
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note
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o||. Conventional R-factors are calculated using the observed criterion. This criterion is irrelevant to the choice of reflections used in the refinement.
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66
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85037459161
-
-
note
-
2 and are statistically about twice as large as those based on F.
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67
-
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85037463087
-
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note
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2, where n = number of data and p = number of parameters refined.
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68
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0000604488
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85037467304
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note
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The cis and trans isomers are defined by the confirmation of the silicon substituents relative to the Si-Si vector.
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85037460202
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note
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29Si NMR spectra of 2b could not be observed because of the low natural abundance of this nucleus.
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82
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85037454374
-
-
note
-
195Pt at 1/9 probability. The latter situation was not observed due to its low probability.
-
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86
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0001076452
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Examples with alkyl phosphines: (a) Paonessa, R. S.; Prignano, A. L.; Trogler, W. C. Organometallics 1985, 4, 647-657. (b) Packett, D. L.; Syed, A.; Trogler, W. C. Organometallics 1988, 7, 159-166. (c) Mullica, D. F.; Sappenfield, E. L. Polyhedron 1991, 10, 867-872. (d) Latif, L. A.; Eaborn, C.; Pidcock, A. P. J. Organomet. Chem. 1994, 474, 217-221. (e) Koizumi, T.; Osakada, K.; Yamamoto, T. Organometallics 1997, 16, 6014-6015.
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Examples with alkyl phosphines: (a) Paonessa, R. S.; Prignano, A. L.; Trogler, W. C. Organometallics 1985, 4, 647-657. (b) Packett, D. L.; Syed, A.; Trogler, W. C. Organometallics 1988, 7, 159-166. (c) Mullica, D. F.; Sappenfield, E. L. Polyhedron 1991, 10, 867-872. (d) Latif, L. A.; Eaborn, C.; Pidcock, A. P. J. Organomet. Chem. 1994, 474, 217-221. (e) Koizumi, T.; Osakada, K.; Yamamoto, T. Organometallics 1997, 16, 6014-6015.
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Examples with alkyl phosphines: (a) Paonessa, R. S.; Prignano, A. L.; Trogler, W. C. Organometallics 1985, 4, 647-657. (b) Packett, D. L.; Syed, A.; Trogler, W. C. Organometallics 1988, 7, 159-166. (c) Mullica, D. F.; Sappenfield, E. L. Polyhedron 1991, 10, 867-872. (d) Latif, L. A.; Eaborn, C.; Pidcock, A. P. J. Organomet. Chem. 1994, 474, 217-221. (e) Koizumi, T.; Osakada, K.; Yamamoto, T. Organometallics 1997, 16, 6014-6015.
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