메뉴 건너뛰기




Volumn 5, Issue 1, 2006, Pages 31-40

Sterically encumbered lithium dialkynidoalanates Li[R2Al(-C≡C-R')2] [R=CH(SiMe3)2]

Author keywords

Alkynides; Aluminium; Lithium

Indexed keywords


EID: 49349086543     PISSN: 10241221     EISSN: 17451167     Source Type: Journal    
DOI: 10.1080/10241220600833414     Document Type: Conference Paper
Times cited : (10)

References (39)
  • 1
    • 0000493263 scopus 로고    scopus 로고
    • Pentacarba-arachno-tridecaalan (AlMe) 8(CCH2Ph)5H mit Al8C5-Gerü st-das erste polyedrische Carbaalan
    • W. Uhl, F. Breher. Pentacarba-arachno-tridecaalan (AlMe)8(CCH2Ph)5H mit Al8C5-Gerü st-das erste polyedrische Carbaalan. Angew. Chem., 111, 1578 (1999).
    • (1999) Angew. Chem , vol.111 , pp. 1578
    • Uhl, W.1    Breher, F.2
  • 3
    • 0000379342 scopus 로고    scopus 로고
    • Zwei neue Carbaalane: Verbindungen mit Al7C5-und zu [B11H11]27 isovalenzelektronischem Al7C4-Cluster
    • W. Uhl, F. Breher, A. Lü tzen, W. Saak. Zwei neue Carbaalane: Verbindungen mit Al7C5-und zu [B11H11]27 isovalenzelektronischem Al7C4-Cluster. Angew. Chem., 112, 414 (2000).
    • (2000) Angew. Chem , vol.112 , pp. 414
    • Uhl, W.1    Breher, F.2    Lützen, A.3    Saak, W.4
  • 5
    • 0001629106 scopus 로고    scopus 로고
    • New carbaalanes containing clusters of aluminum and carbon atoms: (AlEt) 8(CCH2C6H5)5H, (AlMe) 8(CCH2C6H5)5(C-C-C6H5), and (AlMe)7(CCH2CH3)4H2
    • W. Uhl, F. Breher, J. Grunenberg, A. Lü tzen, W. Saak. New Carbaalanes Containing Clusters of Aluminum and Carbon Atoms: (AlEt)8(CCH2C6H5)5H, (AlMe)8(CCH2C6H5)5(C-C-C6H5), and (AlMe)7(CCH2CH3)4H2. Quantum Chemical Characterization. Organometallics, 19, 4536 (2000).
    • (2000) Quantum Chemical Characterization. Organometallics , vol.19 , pp. 4536
    • Uhl, W.1    Breher, F.2    Grunenberg, J.3    Lützen, A.4    Saak, W.5
  • 7
    • 0035843078 scopus 로고    scopus 로고
    • Reactions of Carbaalanes with HBF4 and HCl: M3-Bridging Fluorine Atom in (AlEt) 7(C=CH-Ph)2(CCH2Ph)3(m3-F) versus Terminal Chlorine Atom in (AlMe)7(AlCl)(CCH2Ph)5H
    • W. Uhl, F. Breher, B. Neumü ller, A. Lü tzen, W. Saak, J. Grunenberg. Reactions of Carbaalanes with HBF4 and HCl: m3-Bridging Fluorine Atom in (AlEt)7(C=CH-Ph)2(CCH2Ph)3(m3-F) versus Terminal Chlorine Atom in (AlMe)7(AlCl)(CCH2Ph)5H. Organometallics, 20, 5478 (2001).
    • (2001) Organometallics , vol.20 , pp. 5478
    • Uhl, W.1    Breher, F.2    Neumüller, B.3    Lützen, A.4    Saak, W.5    Grunenberg, J.6
  • 8
    • 0037094003 scopus 로고    scopus 로고
    • Syntheses Structures, and surface aromaticity of the new carbaalane [(AlH)6 (AlNMe3)2(CCH2R)6] (R=Ph, CH2SiMe3) and a stepwise functionalization of the inner and outer sphere of the cluster
    • A. Stasch, M. Ferbinteanu, J. Prust, W. Zheng, F. Cimpoesu, H.W. Roesky, J. Magull, H.-G. Schmidt, M. Noltemeyer. Syntheses, Structures, and Surface Aromaticity of the New Carbaalane [(AlH)6 (AlNMe3)2(CCH2R)6] (R=Ph, CH2SiMe3) and a Stepwise Functionalization of the Inner and Outer Sphere of the Cluster. J. Am. Chem. Soc. 124, 5441 (2002).
    • (2002) J. Am. Chem. Soc , vol.124 , pp. 5441
    • Stasch, A.1    Ferbinteanu, M.2    Prust, J.3    Zheng, W.4    Cimpoesu, F.5    Roesky, H.W.6    Magull, J.7    Schmidt, H.-G.8    Noltemeyer, M.9
  • 10
    • 0033982327 scopus 로고    scopus 로고
    • Aluminium atoms on high connectivity sites in polyhedral polyborane analogous clusters: From aluminaboranes to carbaalanes
    • W. Uhl, F. Breher. Aluminium atoms on High Connectivity Sites in Polyhedral Polyborane Analogous Clusters: From Aluminaboranes to Carbaalanes. Eur. J. Inorg. Chem., 1 (2000).
    • (2000) Eur. J. Inorg. Chem , vol.1
    • Uhl, W.1    Breher, F.2
  • 11
    • 9144238718 scopus 로고    scopus 로고
    • Carbaalanes-A new class of compounds containing clusters of aluminium and carbon atoms
    • G. Meyer D. Naumann, L. Wesemann (Eds.) Wiley-VCH, Weinheim
    • W. Uhl. Carbaalanes-A New Class of Compounds Containing Clusters of Aluminium and Carbon Atoms. In Inorganic Chemistry Highlights, G. Meyer, D. Naumann, L. Wesemann (Eds.), p. 229, Wiley-VCH, Weinheim (2002).
    • (2002) Inorganic Chemistry Highlights , pp. 229
    • Uhl, W.1
  • 12
    • 0037668281 scopus 로고    scopus 로고
    • Hydrogallation of alkynes-syntheses of carbon-gallium cages possessing heteroadamantane structures
    • W. Uhl, L. Cuypers, B. Neumü ller, F. Weller. Hydrogallation of Alkynes-Syntheses of Carbon-Gallium Cages Possessing Heteroadamantane Structures. Organometallics, 21, 2365 (2002).
    • (2002) Organometallics , vol.21 , pp. 2365
    • Uhl, W.1    Cuypers, L.2    Neumüller, B.3    Weller, F.4
  • 13
    • 0000097902 scopus 로고
    • Crystal and molecular structure of tetramethylbis [m-(phenylethynyl)] digallium
    • B. Tecle, W.H. Ilsley, J.P. Oliver. Crystal and molecular structure of tetramethylbis [m-(phenylethynyl)] digallium. Inorg. Chem., 20, 2335 (1981).
    • (1981) Inorg. Chem , vol.20 , pp. 2335
    • Tecle, B.1    Ilsley, W.H.2    Oliver, J.P.3
  • 14
    • 0001137641 scopus 로고
    • Stereochemistry of polynuclear compounds of the main group elements Crystal structure and autoreactivity of the diphenyl(phenylethynyl)aluminum dimer. Model for p-complexation between alkynes and organoaluminum compounds
    • G.D. Stucky, A.M. McPherson, W.E. Rhine, J.J. Eisch, J.L. Considine, L. John. Stereochemistry of polynuclear compounds of the main group elements. Crystal structure and autoreactivity of the diphenyl(phenylethynyl)aluminum dimer. Model for p-complexation between alkynes and organoaluminum compounds. J. Am. Chem. Soc., 96, 1941 (1974).
    • (1974) J. Am. Chem. Soc , vol.96 , pp. 1941
    • Stucky, G.D.1    McPherson, A.M.2    Rhine, W.E.3    Eisch, J.J.4    Considine, J.L.5    John, L.6
  • 15
    • 0001276274 scopus 로고
    • Structural characterization of the acetylide bridge in dinuclear (m-C-C-SiMe3)-Al/Al and-Al/Zr complexes
    • G. Erker, M. Albrecht, C. Krü ger, M. Nolte, S. Werner. Structural characterization of the acetylide bridge in dinuclear (m-C-C-SiMe3)-Al/Al and-Al/Zr complexes. Organometallics, 12, 4979 (1993).
    • (1993) Organometallics , vol.12 , pp. 4979
    • Erker, G.1    Albrecht, M.2    Krüger, C.3    Nolte, M.4    Werner, S.5
  • 16
    • 0001263831 scopus 로고
    • The molecular structure of di(m-1-propynyl) bis(dimethylaluminum [(CH3)2Al(m-C-C-CH3)]2 determined by gas-phase electron diffraction
    • A. Almenningen, L. Fernholt, H. Haaland. The molecular structure of di(m-1-propynyl)bis(dimethylaluminum) [(CH3)2Al(m-C-C-CH3)]2 determined by gas-phase electron diffraction. J. Organomet. Chem., 155, 245 (1978).
    • (1978) J. Organomet. Chem , vol.155 , pp. 245
    • Almenningen, A.1    Fernholt, L.2    Haaland, H.3
  • 17
    • 0000813232 scopus 로고
    • Preparative spectroscopic and X-ray studies of bis(dimethylmetal)-di-(m-1-propynylene) of aluminum gallium and indium
    • W. Fries, W. Schwarz, H.-D. Hausen, J. Weidlein. Preparative, spectroscopic and X-ray studies of bis(dimethylmetal)-di-(m-1-propynylene) of aluminum, gallium and indium. J. Organomet. Chem., 159, 373 (1978).
    • (1978) J. Organomet. Chem , vol.159 , pp. 373
    • Fries, W.1    Schwarz, W.2    Hausen, H.-D.3    Weidlein, J.4
  • 18
    • 0035996898 scopus 로고    scopus 로고
    • Alkynyl aluminum compounds: Bonding modes and structures
    • W. Zheng, H.W. Roesky. Alkynyl aluminum compounds: bonding modes and structures. J. Chem. Soc. Dalton Trans., 2787, (2002).
    • (2002) J. Chem. Soc. Dalton Trans. , pp. 2787
    • Zheng, W.1    Roesky, H.W.2
  • 19
    • 9144256853 scopus 로고    scopus 로고
    • Two Different Structural Motifs Observed for Dimeric Dialkylaluminum and Dialkylgallium Alkynides [R2E-C-C-C6H5] 2
    • W. Uhl, F. Breher, S. Haddadpour, R. Koch, M. Matar. Two Different Structural Motifs Observed for Dimeric Dialkylaluminum and Dialkylgallium Alkynides [R2E-C-C-C6H5]2. Z. Anorg. Allg. Chem., 630, 1839 (2004).
    • (2004) Z. Anorg. Allg. Chem , vol.630 , pp. 1839
    • Uhl, W.1    Breher, F.2    Haddadpour, S.3    Koch, R.4    Matar, M.5
  • 20
    • 33646530767 scopus 로고    scopus 로고
    • Synthese eines funktionalen Aluminiumalkinids Me3C-C-C-AlBr2, und dessen Reaktionen mit der sperrigen Lithiumverbindung LiCH(SiMe3) 2
    • W. Uhl, E. Er, M. Matar. Synthese eines funktionalen Aluminiumalkinids Me3C-C-C-AlBr2, und dessen Reaktionen mit der sperrigen Lithiumverbindung LiCH(SiMe3)2. Z. Anorg. Allg. Chem., 632, 1011 (2006).
    • (2006) Z. Anorg. Allg. Chem , vol.632 , pp. 1011
    • Uhl, W.1    Er, E.2    Matar, M.3
  • 21
    • 0037861771 scopus 로고    scopus 로고
    • Reaction of AlCl monomers with acetylene in a solid argon matrix at 12 K: First characterization of the aluminum acetylide species Cl(H)AlCCH Featuring a Short Al-C Bond
    • H.-J. Himmel. Reaction of AlCl Monomers with Acetylene in a Solid Argon Matrix at 12 K: First Characterization of the Aluminum Acetylide Species Cl(H)AlCCH, Featuring a Short Al-C Bond. Organometallics, 22, 2679 (2003).
    • (2003) Organometallics , vol.22 , pp. 2679
    • Himmel, H.-J.1
  • 22
    • 0346527930 scopus 로고
    • Tetrakis [bis(trimethylsilyl)methyl]dialan(4), eine Verbindung mit Aluminium-Aluminium-Bindung
    • W. Uhl. Tetrakis [bis(trimethylsilyl)methyl]dialan(4), eine Verbindung mit Aluminium-Aluminium-Bindung. Z. Naturforsch., 43b, 1113 (1988).
    • (1988) Z. Naturforsch , vol.43 , pp. 1113
    • Uhl, W.1
  • 23
    • 84989029583 scopus 로고
    • Synthese und Molekü lstruktur eines 1-Sila-3-alanatetans
    • W. Uhl. Synthese und Molekü lstruktur eines 1-Sila-3-alanatetans. Z. Anorg. Allg. Chem., 579, 75 (1989).
    • (1989) Z. Anorg. Allg. Chem , vol.579 , pp. 75
    • Uhl, W.1
  • 26
    • 18844448008 scopus 로고    scopus 로고
    • Hydroaluminierungsreaktionen mit dem sperrigen Dialkylaluminiumhydrid [(Me3Si)2HC]2Al-H-Unterdrü ckung von Folgereaktionen
    • W. Uhl, M. Matar. Hydroaluminierungsreaktionen mit dem sperrigen Dialkylaluminiumhydrid[(Me3Si)2HC]2Al-H-Unterdrü ckung von Folgereaktionen. Z. Anorg. Allg. Chem., 631, 1177 (2005).
    • (2005) Z. Anorg. Allg. Chem , vol.631 , pp. 1177
    • Uhl, W.1    Matar, M.2
  • 27
    • 12444303219 scopus 로고    scopus 로고
    • Hydroalumination of nitriles and isonitriles
    • W. Uhl, M. Matar. Hydroalumination of Nitriles and Isonitriles. Z. Naturforsch., 59b, 1214 (2004).
    • (2004) Z. Naturforsch , vol.59 , pp. 1214
    • Uhl, W.1    Matar, M.2
  • 28
    • 0036034973 scopus 로고    scopus 로고
    • Insertion von Rhodizonsä ure in die Gallium-Gallium-bzw. Indium-Indium-Bindungen von Digallan(4)-bzw. Diindan(4)-Verbindungen
    • W. Uhl, M. Prö tt. Insertion von Rhodizonsä ure in die Gallium-Gallium-bzw. Indium-Indium-Bindungen von Digallan(4)-bzw. Diindan(4)-Verbindungen. Z. Anorg. Allg. Chem., 628, 2259 (2002).
    • (2002) Z. Anorg. Allg. Chem , vol.628 , pp. 2259
    • Uhl, W.1    Prött, M.2
  • 29
    • 0002956662 scopus 로고    scopus 로고
    • A methylene bridged dialuminium compound as a chelating Lewis acid-complexation of azide and acetate anions by R2Al-CH2-AlR2 [R=CH(SiMe3)2]
    • W. Uhl, F. Hannemann. A methylene bridged dialuminium compound as a chelating Lewis acid-complexation of azide and acetate anions by R2Al-CH2-AlR2 [R=CH(SiMe3)2]. J. Organomet. Chem., 579, 18 (1999).
    • (1999) J. Organomet. Chem , vol.579 , pp. 18
    • Uhl, W.1    Hannemann, F.2
  • 30
    • 0000009021 scopus 로고    scopus 로고
    • Synthesis of an aluminatacyclopropene derivative with an alc2 heterocycle and an exocyclic AlR2 substituent; Evidence for a non-classical bonding situation
    • W. Uhl, T. Spies, R. Koch, W. Saak. Synthesis of an Aluminatacyclopropene Derivative with an AlC2 Heterocycle and an Exocyclic AlR2 Substituent; Evidence for a Non-Classical Bonding Situation. Organometallics, 18, 4598 (1999).
    • (1999) Organometallics , vol.18 , pp. 4598
    • Uhl, W.1    Spies, T.2    Koch, R.3    Saak, W.4
  • 31
    • 0000767703 scopus 로고
    • Thermolyse sterisch ü berladener Alanate; Synthese zweier neuer 1-Sila-3-alanata-cyclobutan-Derivate mit AlC2Si-Heterozyklus
    • W. Uhl, M. Koch, J. Wagner. Thermolyse sterisch ü berladener Alanate; Synthese zweier neuer 1-Sila-3-alanata-cyclobutan-Derivate mit AlC2Si-Heterozyklus. Z. Anorg. Allg. Chem., 621, 249 (1995).
    • (1995) Z. Anorg. Allg. Chem , vol.621 , pp. 249
    • Uhl, W.1    Koch, M.2    Wagner, J.3
  • 33
    • 0035982498 scopus 로고    scopus 로고
    • An unsolvated lithium trihydroaluminate and the corresponding trialkynylaluminates supported by an anionic triazacyclononane ligand
    • C. Cui, J.A.R. Schmidt, J. Arnold. An unsolvated lithium trihydroaluminate and the corresponding trialkynylaluminates supported by an anionic triazacyclononane ligand. J. Chem. Soc. Dalton Trans., 2992 (2002).
    • (2002) J. Chem. Soc. Dalton Trans , vol.2992
    • Cui, C.1    Schmidt, J.A.R.2    Arnold, J.3
  • 35
    • 0001709840 scopus 로고    scopus 로고
    • Organoaluminates with three terminal phenylethynyl groups and their interactions with alkali metal cations
    • M. Schiefer, H. Hatop, H.W. Roesky, H.-G. Schmidt, M. Noltemeyer. Organoaluminates with Three Terminal Phenylethynyl Groups and Their Interactions with Alkali Metal Cations. Organometallics, 21, 1300 (2002).
    • (2002) Organometallics , vol.21 , pp. 1300
    • Schiefer, M.1    Hatop, H.2    Roesky, H.W.3    Schmidt, H.-G.4    Noltemeyer, M.5
  • 36
    • 33748213531 scopus 로고
    • Solvent-free [tris(trimethylsilyl)methyl]lithium
    • W. Hiller, M. Layh, W. Uhl. Solvent-free [tris(trimethylsilyl)methyl]lithium. Angew. Chem. Int. Ed. Engl., 30, 325 (1991).
    • (1991) Angew. Chem. Int. Ed. Engl , vol.30 , pp. 325
    • Hiller, W.1    Layh, M.2    Uhl, W.3
  • 37
    • 33748226760 scopus 로고
    • Structures of the classical synthesis reagents (BuLi)6 and (Me3CLi) 4 and the metastable (Me3CLi.OEt2) 2
    • T. Kottke, D. Stalke. Structures of the classical synthesis reagents (BuLi)6 and (Me3CLi)4 and the metastable (Me3CLi.OEt2)2. Angew. Chem. Int. Ed. Engl., 32, 580 (1993).
    • (1993) Angew. Chem. Int. Ed. Engl , vol.32 , pp. 580
    • Kottke, T.1    Stalke, D.2
  • 38
    • 0039973069 scopus 로고
    • Die Reaktionen des tert.Butyl-lithiums mit Aluminiumtribromid; Molekü lstrukturen von [HAl(CMe3) 2] 3 und [LiHAl(CMe3)3]2
    • W. Uhl. Die Reaktionen des tert.Butyl-lithiums mit Aluminiumtribromid; Molekü lstrukturen von [HAl(CMe3)2]3 und [LiHAl(CMe3)3]2. Z. Anorg. Allg. Chem., 570, 37 (1989).
    • (1989) Z. Anorg. Allg. Chem , vol.570 , pp. 37
    • Uhl, W.1
  • 39
    • 84989026829 scopus 로고
    • Synthese und Molekü lstruktur des (N,N0-Dimethylpiperazin)lithium-(m-hydrido)(tert-butyl)bis [bis(trimethylsilyl)methyl]alanats mit intramolekularer Wechselwirkung zwischen Lithium und C-H-s-Bindungen
    • W. Uhl, J.E.O. Schnepf. Synthese und Molekü lstruktur des (N,N0-Dimethylpiperazin)lithium-(m-hydrido)(tert-butyl)bis [bis(trimethylsilyl)methyl]alanats mit intramolekularer Wechselwirkung zwischen Lithium und C-H-s-Bindungen. Z. Anorg. Allg. Chem., 595, 225 (1991).
    • (1991) Z. Anorg. Allg. Chem , vol.595 , pp. 225
    • Uhl, W.1    Schnepf, J.E.O.2


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.