Two new carbaalanes: Compounds with an Al7C5 and a [B11H11]2 analogous Al7C4 cluster

Angewandte Chemie - International Edition

Volumn 39, Issue 2, 2000, Pages 406-409

  Uhl, Werner ^a,b   Breher, Frank ^a   Lützen, Arne ^a   Saak, Wolfgang ^a  

^a UNIVERSITY OF OLDENBURG   (Germany)

^b PHILIPPS UNIVERSITY MARBURG   (Germany)

Author keywords

Aluminum; Cluster compounds; Electron deficiency

Indexed keywords

ALUMINUM DERIVATIVE; BORANE DERIVATIVE;

ARTICLE; CRYSTALLIZATION; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; SYNTHESIS;

EID: 0034677159     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/(SICI)1521-3773(20000117)39:2<406::AID-ANIE406>3.0.CO;2-5     Document Type: Article

References (21)

1. D. M. Schubert, M. A. Bandman, W. S. Rees, Jr., C. B. Knobler, P. Lu, W. Nam, M. F. Hawthorne, Organometallics 1990, 9, 2046; C. A. Morrison, B. A. Smart, P. T. Brain, D. W. H. Rankin, A. J. Downs, J. Chem. Soc. Dalton Trans. 1998, 2155.
2. D. M. Schubert, M. A. Bandman, W. S. Rees, Jr., C. B. Knobler, P. Lu, W. Nam, M. F. Hawthorne, Organometallics 1990, 9, 2046; C. A. Morrison, B. A. Smart, P. T. Brain, D. W. H. Rankin, A. J. Downs, J. Chem. Soc. Dalton Trans. 1998, 2155.
3. W. Uhl, F. Breher, Angew. Chem. 1999, 111, 1578; Angew. Chem. Int. Ed. 1999, 38, 1477. Polyboranes by hydroboration: B. Wrackmeyer, H. J. Schanz, M. Hofmann, P. von R. Schleyer, R. Boese, Eur. J. Inorg. Chem. 1999, 533; B. Wrackmeyer, H. J. Schanz, M. Hofmann, P. von R. Schleyer, Eur. J. Inorg. Chem. 1998, 633; R. Köster, G. Seidel, B. Wrackmeyer, Angew. Chem. 1994, 106, 2380; Angew. Chem. Int. Ed. Engl. 1994, 33, 2294.
4. W. Uhl, F. Breher, Angew. Chem. 1999, 111, 1578; Angew. Chem. Int. Ed. 1999, 38, 1477. Polyboranes by hydroboration: B. Wrackmeyer, H. J. Schanz, M. Hofmann, P. von R. Schleyer, R. Boese, Eur. J. Inorg. Chem. 1999, 533; B. Wrackmeyer, H. J. Schanz, M. Hofmann, P. von R. Schleyer, Eur. J. Inorg. Chem. 1998, 633; R. Köster, G. Seidel, B. Wrackmeyer, Angew. Chem. 1994, 106, 2380; Angew. Chem. Int. Ed. Engl. 1994, 33, 2294.
5. W. Uhl, F. Breher, Angew. Chem. 1999, 111, 1578; Angew. Chem. Int. Ed. 1999, 38, 1477. Polyboranes by hydroboration: B. Wrackmeyer, H. J. Schanz, M. Hofmann, P. von R. Schleyer, R. Boese, Eur. J. Inorg. Chem. 1999, 533; B. Wrackmeyer, H. J. Schanz, M. Hofmann, P. von R. Schleyer, Eur. J. Inorg. Chem. 1998, 633; R. Köster, G. Seidel, B. Wrackmeyer, Angew. Chem. 1994, 106, 2380; Angew. Chem. Int. Ed. Engl. 1994, 33, 2294.
6. W. Uhl, F. Breher, Angew. Chem. 1999, 111, 1578; Angew. Chem. Int. Ed. 1999, 38, 1477. Polyboranes by hydroboration: B. Wrackmeyer, H. J. Schanz, M. Hofmann, P. von R. Schleyer, R. Boese, Eur. J. Inorg. Chem. 1999, 533; B. Wrackmeyer, H. J. Schanz, M. Hofmann, P. von R. Schleyer, Eur. J. Inorg. Chem. 1998, 633; R. Köster, G. Seidel, B. Wrackmeyer, Angew. Chem. 1994, 106, 2380; Angew. Chem. Int. Ed. Engl. 1994, 33, 2294.
7. W. Uhl, F. Breher, Angew. Chem. 1999, 111, 1578; Angew. Chem. Int. Ed. 1999, 38, 1477. Polyboranes by hydroboration: B. Wrackmeyer, H. J. Schanz, M. Hofmann, P. von R. Schleyer, R. Boese, Eur. J. Inorg. Chem. 1999, 533; B. Wrackmeyer, H. J. Schanz, M. Hofmann, P. von R. Schleyer, Eur. J. Inorg. Chem. 1998, 633; R. Köster, G. Seidel, B. Wrackmeyer, Angew. Chem. 1994, 106, 2380; Angew. Chem. Int. Ed. Engl. 1994, 33, 2294.
8. W. Uhl, F. Breher, Angew. Chem. 1999, 111, 1578; Angew. Chem. Int. Ed. 1999, 38, 1477. Polyboranes by hydroboration: B. Wrackmeyer, H. J. Schanz, M. Hofmann, P. von R. Schleyer, R. Boese, Eur. J. Inorg. Chem. 1999, 533; B. Wrackmeyer, H. J. Schanz, M. Hofmann, P. von R. Schleyer, Eur. J. Inorg. Chem. 1998, 633; R. Köster, G. Seidel, B. Wrackmeyer, Angew. Chem. 1994, 106, 2380; Angew. Chem. Int. Ed. Engl. 1994, 33, 2294.
9. K. Wade, Adv. Inorg. Chem. Radiochem. 1976, 18, 1.
10. 3. The positions of the hydrogen atoms H1 were obtained from a difference Fourier synthesis, they were refined isotropically. Crystallographic data (excluding structure factors) for the structures reported in this paper have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC 127469 (2) and CCDC 127470 (3). Copies of the data can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK (fax: (+44) 1223-336-033; e-mail: deposit@ccdc.cam.ac.uk).
11. R. G. Vranka, E. L. Amma, J. Am. Chem. Soc. 1967, 89, 3121; J. C. Huffman, W. E. Streib, J. Chem. Soc. Chem. Commun. 1971, 911.
12. R. G. Vranka, E. L. Amma, J. Am. Chem. Soc. 1967, 89, 3121; J. C. Huffman, W. E. Streib, J. Chem. Soc. Chem. Commun. 1971, 911.
13. W. Uhl, Z. Naturforsch, B 1988, 43, 1113; R. J. Wehmschulte, K. Ruhlandt-Senge, M. M. Olmstead, H. Hope, B. E. Sturgeon, P.P. Power, Inorg. Chem. 1993, 32, 2983.
14. W. Uhl, Z. Naturforsch, B 1988, 43, 1113; R. J. Wehmschulte, K. Ruhlandt-Senge, M. M. Olmstead, H. Hope, B. E. Sturgeon, P.P. Power, Inorg. Chem. 1993, 32, 2983.
15. J. Bicerano, D. S. Marynick, W. N. Lipscomb, Inorg. Chem. 1978, 17, 3443; M. Gielen, Polyhedron 1988, 7, 363; P. von Ragué Schleyer, K. Najafian, A. M. Mebel, Inorg. Chem. 1998, 37, 6765.
16. J. Bicerano, D. S. Marynick, W. N. Lipscomb, Inorg. Chem. 1978, 17, 3443; M. Gielen, Polyhedron 1988, 7, 363; P. von Ragué Schleyer, K. Najafian, A. M. Mebel, Inorg. Chem. 1998, 37, 6765.
17. J. Bicerano, D. S. Marynick, W. N. Lipscomb, Inorg. Chem. 1978, 17, 3443; M. Gielen, Polyhedron 1988, 7, 363; P. von Ragué Schleyer, K. Najafian, A. M. Mebel, Inorg. Chem. 1998, 37, 6765.
18. E. H. Wong, L. Prasad, E. J. Gabe, M. G. Gatter, Inorg. Chem. 1983, 22, 1143; O. Volkov, W. Dirk, U. Englert, P. Paetzold, Z. Anorg. Allg. Chem. 1999, 625, 1193.
19. E. H. Wong, L. Prasad, E. J. Gabe, M. G. Gatter, Inorg. Chem. 1983, 22, 1143; O. Volkov, W. Dirk, U. Englert, P. Paetzold, Z. Anorg. Allg. Chem. 1999, 625, 1193.
20. A review about carbaalanes and other cluster compounds containing aluminium atoms on high-connectivity sites in: W. Uhl, F. Breher, Eur. J. Inorg. Chem. 2000, 1.
21. H. Lehmkuhl, K. Ziegler, Methoden Org. Chem. (Houben-Weyl) 4th ed. 1952, Vol. XIII14, p 58.