New carbaalanes - (AlMe)8(CCH2Me)5(C≡C-Me) and the THF adduct (AlMe)8(CCH2Me)5H·2THF

European Journal of Inorganic Chemistry

Volumn , Issue 12, 2001, Pages 3059-3066

  Uhl, Werner ^a   Breher, Frank ^a   Mbonimana, Alphonse ^a   Gauss, Jürgen ^b   Haase, Detlev ^c   Lützen, Arne ^c   Saak, Wolfgang ^c  

^a PHILIPPS UNIVERSITY MARBURG   (Germany)

^b JOHANNES GUTENBERG UNIVERSITY   (Germany)

^c UNIVERSITY OF OLDENBURG   (Germany)

Author keywords

Aluminium; Carbaalanes; Clusters; NMR spectroscopy; Quantum chemical calculations

Indexed keywords

ALUMINUM; ATOMS; CHEMICAL SHIFT; CRYSTAL ATOMIC STRUCTURE; HYDROGEN; QUANTUM CHEMISTRY; RECRYSTALLIZATION (METALLURGY);

CARBAALANES; CLUSTER; CRYSTAL STRUCTURE DETERMINATION; HYDROALUMINATION; HYDROGEN ATOMS; NMR-SPECTROSCOPY; NONCOORDINATING SOLVENTS; QUANTUM CHEMICAL CALCULATIONS; QUANTUM-CHEMICAL CALCULATION; RECRYSTALLISATION; ALUMINUM ATOMS;

NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY;

ALUMINUM DERIVATIVE;

ARTICLE; CHEMICAL BOND; CRYSTAL STRUCTURE; CRYSTALLIZATION; MOLECULAR STABILITY; NUCLEAR MAGNETIC RESONANCE;

EID: 0035208439     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/1099-0682(200112)2001:12<3059::AID-EJIC3059>3.0.CO;2-Z     Document Type: Article

References (49)

1. W. Uhl, F. Breher, Eur. J. Inorg. Chem. 2000, 1.
2. W. Uhl, F. Breher, Angew. Chem. 1999, 111, 1578;
3. Angew. Chem. Int. Ed. 1999, 38, 1477.
4. W. Uhl, F. Breher, A. Lützen, W. Saak, Angew. Chem. 2000, 112, 414;
5. Angew. Chem. Int. Ed. 2000, 39, 406.
6. W. Uhl, F. Breher, J. Grunenberg, A. Lützen, W. Saak, Organometallics 2000, 19, 4536.
7. O. Volkov, W. Dirk, U. Englert, P. Paetzold, Z. Anorg. Allg. Chem. 1999, 625, 1193;
8. E. H. Wong, L. Prasad, E. J. Gabe, M. G. Gatter, Inorg. Chem. 1983, 22, 1143.
9. 3: δ = 2.71. O. T. Beachley, Jr., L. Victoriano, Organometallics 1988, 7, 63.
10. H. Günther, NMR-Spektroskopie, Georg Thieme Verlag, Stuttgart, 1983, p. 229.
11. R. G. Vranka, E. L. Amma, J. Am. Chem. Soc. 1967, 89, 3121;
12. J. C. Huffman, W. E. Streib, J. Chem. Soc., Chem. Commun. 1971, 911;
13. A. Almenningen, G. A. Anderson, F. R. Forgaard, A. Haaland, Acta Chem. Scand 1972, 26, 2315.
14. W. Uhl, Z. Naturforsch. B., Chem. Sci. 1988, 43, 1113;
15. R. J. Wehmschulte, K. Ruhlandt-Senge, M. M. Olmstead, H. Hope, B. E. Sturgeon, P. P. Power, Inorg. Chem. 1993, 32, 2983;
16. N. Wiberg, K. Amelunxen, T. Blank, H. Nöth, J. Knizek, Organometallics 1998, 17, 5431.
17. W. Uhl, Z. Anorg. Allg. Chem. 1989, 570, 37.
18. A. Haaland, in Coordination Chemistry of Aluminum (Ed.: G. H. Robinson), VCH, New York, 1993;
19. W. Uhl, M. Koch, S. Pohl, W. Saak, W. Hiller, M. Heckel, Z. Naturforsch., Teil B 1995, 50, 635.
20. R. Benn, A. Rufińska, H. Lehmkuhl, E. Janssen, C. Krüger, Angew. Chem. 1983, 95, 808;
21. Angew. Chem. Int. Ed. Engl. 1983, 22, 779;
22. R. Benn, A. Rufińska, Angew. Chem. 1986, 98, 851;
23. Angew. Chem. Int. Ed. Engl. 1986, 25, 861;
24. J. F. Hinton, R. W. Briggs in NMR and the Periodic Table (Eds.: R. K. Harris, B. E. Mann), Academic Press, London, 1978.
25. J. Gauss, U. Schneider, R. Ahlrichs, C. Dohmeier, H. Schnöckel, J. Am. Chem. Soc. 1993, 115, 2402.
26. C. Klemp, M. Bruns, J. Gauss, U. Häussermann, G. Stösser, L. Van Wüllen, M. Jansen, H. Schnöckel, J. Am. Chem. Soc. in press.
27. C. Dohmeier, H. Schnöckel, C. Robl, U. Schneider, R. Ahlrichs, Angew. Chem. 1993, 105, 1714;
28. Angew. Chem. Int. Ed. Engl. 1993, 32, 1655.
29. W. Uhl, F. Breher, B. Neumüller, J. Grunenberg, A. Lützen, W. Saak, Organometallics, in press.
30. H. Lehmkuhl, K. Ziegler, in Methods of Organic Chemistry (Houben-Weyl), 4th ed., Thieme-Verlag, Stuttgart, 1970; vol. XIII/4, pp. 58-59.
31. W. Uhl, J. Wagner, D. Fenske, G. Baum, Z. Anorg. Allg. Chem. 1992, 612, 25.
32. 2Al-C≡C-Me by a very complicated route has been reported previously; its characterization was incomplete: H. Demarne, P. Cadiot, Bull. Soc. Chim. Fr. 1968, 205;
33. A. Almenningen, L. Fernholt, A. Haaland, J. Organomet. Chem. 1978, 155, 245; see ref.[14].
34. International Tables for Crystallography, Space Group Symmetry (Ed.: T. Hahn), Kluwer Academic Publishers, Dordrecht, Boston, London, 1989, vol. A.
35. SHELXTL-Plus, Release 4.2 for Siemens R3 Crystallographic Research Systems, Siemens Analytical X-ray Instruments Inc., Madison, USA, 1990;
36. G. M. Sheldrick, SHELXL-97, Program for the Refinement of Crystal Structures, Universität Göttingen, 1997.
37. The crystallographic data for 5 and 6 (excluding structure factors) have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication nos. CCDC-160388 (5) and -160389 (6). Copies of the data can be obtained free of charge on application to The Director, CCDC, 12 Union Road, Cambridge CB2 1EZ, U.K. [Fax: (internat.) +44 (0)1223 336033; E-mail: deposit@chemcrys.cam.ac.uk].
38. See, for example: R. G. Parr, W. Yang, Density-Functional Theory of Atoms and Molecules, Clarendon Press, New York, 1989, and references therein.
39. A. D. Becke, Phys. Rev. 1998, A38, 3098;
40. J. P. Perdew, Phys. Rev. 1996, B33, 8822.
41. K. Eichkorn, O. Treutler, H. Öhm, M. Häser, R. Ahlrichs, Chem. Phys. Lett. 1995, 240, 283.
42. A. Schäfer, H. Horn, R. Ahlrichs, J. Chem. Phys. 1992, 97, 2571.
43. R. Ditchfield, Mol. Phys. 1974, 27, 789;
44. K. Wolinski, J. F. Hinton, P. Pulay, J. Am. Chem. Soc, 1990, 112, 8251;
45. M. Häser, R. Ahlrichs, H. P. Baron, P. Weis, H. Horn, Theoret. Chim. Acta 1992, 83, 455.
46. H. Nöth, Z. Naturforsch., Teil B 1980, 35, 119.
47. J. Gauss, Chem. Phys. Lett. 1992, 191, 614;
48. M. Kollwitz, J. Gauss, Chem. Phys. Lett. 1996, 260, 639.
49. R. Ahlrichs, M. Bär, M. Häser, H. Horn, C. Kölmel, Chem. Phys. Lett. 1989, 162, 165.