S42- rings, disulfides, and sulfides in transition-metal complexes: The subtle interplay of oxidation and structure

Angewandte Chemie - International Edition

Volumn 47, Issue 15, 2008, Pages 2864-2868

  Mealli, Carlo ^a   Ienco, Andrea ^a   Poduska, Anne ^b   Hoffmann, Roald ^b  

^a ICCOM CNR   (Italy)

^b Department of Obstetrics Gynecology   (United States)

Author keywords

Density functional calculations; Disulfide coupling; Electronic structure; Jahn Teller distortion; Molecular orbital analysis

Indexed keywords

ELECTRIC NETWORK ANALYSIS;

DENSITY FUNCTIONAL CALCULATIONS; DISULFIDE COUPLING; ELECTRONIC STRUCTURE; JAHN-TELLER DISTORTION; MOLECULAR ORBITAL ANALYSIS;

CHEMICAL REACTIONS;

EID: 48849098009     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200705296     Document Type: Article

References (53)

1. T. Chivers, I. Drummond, Chem. Soc. Rev. 1973, 2, 233-248.
2. K. Raghavachari, C. McMichael Rohlfing, J. S. Binkley, J. Chem. Phys. 1990, 93, 5862-5874.
3. R. Tegman, Acta Crystallogr. Sect. B 1973, 29, 1463-1469.
4. a) T. Nishioka, H. Kitayama, B. K. Breedlove, K. Shiomi, I. Kinoshita, K. Isobe, Inorg. Chem. 2004, 43, 5688-5697;
5. b) K. Isobe, Y. Ozawa, A. Vazquez de Miguel, T. W. Zhu, K. M. Zhao, T. Nishioka, T. Ogura, T. Kitagawa, Angew. Chem. 1994, 106, 1934-1936;
6. Angew. Chem. Int. Ed. Engl. 1994, 33, 1882-1883.
7. A. Poduska, R. Hoffmann, A. Ienco, C. Mealli, unpublished results.
8. 4: a) R. Gleiter, J. Chem. Soc. A 1970, 3174;
9. b) T. Yamabe, K. Tanaka, A. K. Fukui, H. Kato, J. Phys. Chem. 1979, 83, 767-769);
10. 2+: c) T. S. Cameron, R. J. Deeth, I. Dionne, H. Du, H. D. B. Jenkins, I. Krossing, J. Passmore, H. K. Roobottom, Inorg. Chem. 2000, 39, 5614-5631.
11. Cambridge Structural Database System, Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge, CB2 1EZ, UK.
12. H. Brunner, A. Merz, J. Pfauntsch, O. Serhadli, J. Wachter, M. L. Ziegler, Inorg. Chem. 1988, 27, 2055-2058.
13. J. T. York, E. C. Brown, W. B. Tolman, Angew. Chem. 2005, 117, 7923-7926;
14. Angew. Chem. Int. Ed. 2005, 44, 7745-7748.
15. M. Rakowski DuBois, B. R. Jagirdar, S. Dietz, B. C. Noll, Organometallics 1997, 16, 294-296.
16. H. Brunner, W. Meier, J. Pfauntsch, E. Guggolz, T. Zahn, M. L. Ziegler, Organometallics 1982, 1, 1107-1113.
17. C. Mealli, A. Orlandini in Metal Clusters in Chemistry, Vol. 1 (Ed.: P. Braunstein, L. Oro, P. Raithby), Wiley-VCH, Weinheim, 1999.
18. C. H. Wie, L. F. Dahl, Inorg. Chem. 1964, 4, 1-11.
19. a) L. Eremenko, H. Berke, A. A. H. van der Zeijden, B. A. Kolobkov, V. M. Novotortsev, J. Organomet. Chem. 1994, 471, 123-132;
20. b) T. D. Weatherill, T. B. Rauchfuss, R. A. Scott, Inorg. Chem. 1986, 25, 1446-1450.
21. a) W. B. Tolman, Acc. Chem. Res. 1997, 30, 227-237;
22. b) E. A. Lewis, W. B. Tolman, Chem. Rev. 2004, 104, 1047-1076;
23. c) E. C. Brown, N. W. Aboelella, A. M. Reynolds, G. Aullòn, S. Alvarez, W. B. Tolman, Inorg. Chem. 2004, 43, 3335-3337.
24. a) K. Fujisawa, Y. Moro-oka, N. Kitajima, Chem. Commun. 1994, 623-624;
25. b) M. E. Helton, D. Maiti, L. N. Zakharov, A. L. Rheingold, J. A. Porco, K. D. Karlin, Angew. Chem. 2006, 118, 1156-1159;
26. Angew. Chem. Int. Ed. 2006, 45, 1138-1141.
27. E. C. Brown, N. E. Aboelella, A. M. Reynolds, G. Aullòn, S. Alvarez, W. B. Tolman, Inorg. Chem. 2004, 43, 3335-3337.
28. G. Aullòn, S. Alvarez, Eur. J. Inorg. Chem. 2004, 4430-4438.
29. C. Mealli, S. Midollini, Inorg. Chem. 1983, 22, 2785-2786.
30. R. J. Pleus, H. Waden, W. Saak, D. Haase, S. Pohl, J. Chem. Soc. Dalton Trans. 1999, 2601-2610.
31. E. C. Brown, J. T. York, W. E. Antholine, E. Ruiz, S. Alvarez, W. B. Tolman, J. Am. Chem. Soc. 2005, 127, 13752-13753.
32. C. A. Ghilardi, S. Midollini, A. Orlandini, G. Scapacci, J. Chem. Soc. Dalton Trans. 1992, 2909-2910.
33. 2 cluster compounds, where M is a metal fragment and E a main-group element or fragment: S. Kahlal, J.-F. Halet, J.-Y. Saillard, Inorg. Chem. 1991, 30, 2567-2569;
34. F. Z. Trodi, G. Lucas, M. Bencharif, J.-F. Halet, S. Kahlal, J.-Y. Saillard, J. Cluster Sci. 2007, 18, 729-740, and references therein;
35. 3, E = As, Bi, Sb compounds are also relevant in this context, with their fully formed E-E bond: G. Huttner, U. Weber, B. Sigwarth, O. Scheidsteger, Angew. Chem. 1982, 94, 210-211;
36. Angew. Chem. Int. Ed. Engl. 1982, 21, 215-216;
37. B. Sigwarth, I. Zsolnai, H. Berke, G. Huttner, J. Organomet. Chem. 1982, 226, C5-C8;
38. G. Huttner, U. Weber, L. Zsolnai, Z. Naturforsch. B 1982, 37, 707-715.
39. A. P. Cole, D. E. Root, P. Mukherjee, E. I. Solomon, T. D. P. Stack, Science 1996, 273, 1848-1850.
40. 2- ring was not explicitly formulated: R. Sarangi, J. T. York, M. E. Helton, K. Fujisawa, K. D. Karlin, W. B. Tolman, K. O. Hodgson, B. Hedman, E. I. Solomon, J. Am. Chem. Soc. 2008, 130, 676-686.
41. a) D. M. Giolando, T. B. Rauchfuss, A. L. Rheingold, A. R. Wilson, Organometallics 1987, 6, 667-675;
42. b) J. Amarasekera, T. B. Rauchfuss, A. L. Rheingold, Inorg. Chem. 1987, 26, 2017;
43. c) P. M. Treichel, R. A. Crane, K, J. Haller, Polyhedron 1990, 9, 1893-1899;
44. d) A. A. Pasynskii, V. N. Grigor'ev, A. I. Blokhin, I. Yu. V. Torubaev, K. A. Lyssenko, V. V. Minin, Russ. J. Inorg. Chem. 2005, 50, 1450;
45. e) R. J. Pleus, W. Saak, S. Pohl, Z. Anorg. Allg. Chem. 2001, 627, 250-253.
46. a) C. Belin, T. Makani, J. Roziere, J. Chem. Soc. Chem. Commun. 1985, 118-119;
47. b) S. Inomata, T. Hiruma, H. Ogino, Chem. Lett. 1998, 309-310.
48. E. Stiefel, Pure Appl. Chem. 1998, 70, 889-896.
49. A. D. Becke, J. Chem. Phys. 1993, 98, 5648-5652;
50. C. Lee, W. Yang, R. Parr, Phys. Rev. B 1988, 37, 785-789.
51. Gaussian 03 (Rev. B.05), Gaussian, Inc., Wallingford, CT, 2004 (complete reference in the Supporting Information).
52. a) C. Mealli, D. M. Proserpio, J. Chem. Educ. 1990, 67, 399-402;
53. b) C. Mealli, A. Ienco, D. M. Proserpio, Book of Abstracts of the XXXIII ICCC, Florence, Italy, 1998, p. 510.