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Volumn 16, Issue 3, 1997, Pages 294-296

Syntheses of dinuclear rhenium complexes with disulfido and sulfido ligands

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EID: 0000038831     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om9608972     Document Type: Article
Times cited : (37)

References (88)
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    • 2 has also been mentioned briefly but not completely characterized: Herrmann, W. A. Comments Inorg. Chem. 1988, 7, 73. Herrmann, W. A. Angew. Chem., Int. Ed. Engl. 1988, 27, 1297.
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    • note
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    • Complete details of syntheses, spectroscopic data, and elemental analyses for the new compounds are given in the Supporting Information.
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    • note
    • 2).
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    • note
    • 2 = 0.0743 for 2320 independent reflections with I > 2.0σ(I).
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    • and references within
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    • + mass spectrum (m/e): 895 (P, very weak); 863 (P - S).
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    • 13 In the structural study the hydrogen atom on the anion was located by difference map (see Supporting Information).
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    • Addition of the relatively unactivated monosubstituted alkyne, phenylacetylene, to terminal sulfido ligands has also been observed: Kawaguchi, H.; Tatsumi, K. J. Am. Chem. Soc. 1995, 117, 3885.
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    • Olefin additions to sulfur atoms in dithiolene ligands have been reported: (a) Schrauzer, G. N. Mayweg, V. P. J. Am. Chem. Soc. 1965, 87, 1483. (b) Wing, R. M.; Tustin, G. C.; Okamura, W. H. J. Am. Chem. Soc. 1970, 92, 1935. Nucleophilic attacks of negatively charged sulfido complexes on activated olefins have been reported: (a) Seyferth, D.; Womack, G. B.; Henderson, R. S.; Cowie, M.; Hames, B. W. Organometallics 1986, 5, 1568. (b) Casewit, C. J.; Rakowski DuBois, M. J. Am. Chem. Soc. 1986, 108, 5482.
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    • Olefin additions to sulfur atoms in dithiolene ligands have been reported: (a) Schrauzer, G. N. Mayweg, V. P. J. Am. Chem. Soc. 1965, 87, 1483. (b) Wing, R. M.; Tustin, G. C.; Okamura, W. H. J. Am. Chem. Soc. 1970, 92, 1935. Nucleophilic attacks of negatively charged sulfido complexes on activated olefins have been reported: (a) Seyferth, D.; Womack, G. B.; Henderson, R. S.; Cowie, M.; Hames, B. W. Organometallics 1986, 5, 1568. (b) Casewit, C. J.; Rakowski DuBois, M. J. Am. Chem. Soc. 1986, 108, 5482.
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    • Olefin additions to sulfur atoms in dithiolene ligands have been reported: (a) Schrauzer, G. N. Mayweg, V. P. J. Am. Chem. Soc. 1965, 87, 1483. (b) Wing, R. M.; Tustin, G. C.; Okamura, W. H. J. Am. Chem. Soc. 1970, 92, 1935. Nucleophilic attacks of negatively charged sulfido complexes on activated olefins have been reported: (a) Seyferth, D.; Womack, G. B.; Henderson, R. S.; Cowie, M.; Hames, B. W. Organometallics 1986, 5, 1568. (b) Casewit, C. J.; Rakowski DuBois, M. J. Am. Chem. Soc. 1986, 108, 5482.
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    • note
    • 4).


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