Asymmetric synthesis of 3,4-annulated cyclopentenones from cycloalkenyl ketones and vinyl carbamates by diastereoselective carbonyl addition/conrotatory 4π ring closure

Synthesis

Volumn , Issue 14 SPEC. ISS., 2008, Pages 2264-2270

  Siemer, Michael ^a   Fröhlich, Roland ^a   Hoppe, Dieter ^a  

^a UNIVERSITY OF MÜNSTER   (Germany)

Author keywords

Asymmetric synthesis; Carbanion; Cyclopentenones; Electrocyclic reaction; Torquoselectivity

Indexed keywords

KETONES;

ASYMMETRIC SYNTHESIS; CARBANION; CYCLOPENTENONES; DIASTEREO-SELECTIVITY; DIASTEREOSELECTIVE; ELECTROCYCLIC REACTION; HOMOCHIRAL; RING CLOSURES; TORQUOSELECTIVITY; VINYL CARBAMATES;

ORGANIC COMPOUNDS;

2 BICYCLO[N.3.0]ALK 1 ENE ONE DERIVATIVE; 3,4 CYCLOPENTENONE DERIVATIVE; ALKENE DERIVATIVE; CARBAMIC ACID DERIVATIVE; CARBONYL DERIVATIVE; CYCLOALK 1 ENYL (1 DIBENZYLAMINO) KETONE DERIVATIVE; CYCLOALKENYL KETONE DERIVATIVE; KETONE DERIVATIVE; VINYL DERIVATIVE;

ARTICLE; ASYMMETRIC SYNTHESIS; CHEMICAL STRUCTURE; CYCLIZATION; CYCLOADDITION; ENANTIOMER; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; STEREOCHEMISTRY;

EID: 48549100206     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2008-1067150     Document Type: Article

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