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58149195599
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For borylative cyclization reactions with other boron reagents than diboron compounds, see:
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For recent examples of the synthesis of 3-alkylideneoxindoles with catalysis of transition metals, see:
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58149184498
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For oxindoles as synthetic intermediates in total synthesis, see
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For oxindoles as synthetic intermediates in total synthesis, see:
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37
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2442659012
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40
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33747199112
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58149185902
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The stereochemistry of the exocyclic double bond was assigned by a difference nOe study
-
The stereochemistry of the exocyclic double bond was assigned by a difference nOe study.
-
-
-
-
43
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58149198388
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The results with other catalysts (NMR yield/, Rh(cod) 2]BF4(36, Rh(cod)2]PF6 (35, Rh(cod)2]C104 (60, Rh(cod)2]BARF(45, Rh(cod)(MeCN)2]SbF6 (56, Rh(bpy)(cod)]SbF6 (trace, Ir(cod)2]BARF (8, Ir(cod)(MeCN)2]BARF 7
-
2]BARF (8%), [Ir(cod)(MeCN)2]BARF (7%).
-
-
-
-
44
-
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58149201749
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The borylated products 3 could be further purified by recrystallization. See the Supporting Information for details.
-
The borylated products 3 could be further purified by recrystallization. See the Supporting Information for details.
-
-
-
-
45
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58149198389
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A related rhodacycle intermediate is assumed for the Rh(I)-catalyzed Pauson-Khand-type reaction of 2-alkynylaryl isothiocyanates: Saito, T.; Nihei, H.; Otani, T.; Suyama, T.; Furukawa, N.; Saito, M. Chem. Commun. 2008, 172.
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58149200326
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Although the reaction in DCE-d4 was monitored by 1H NMR, no possible intermediate was detected
-
1H NMR, no possible intermediate was detected.
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