Double versus single helical structures of oligopyridine-dicarboxamide strands. Part 1: Effect of oligomer length

Tetrahedron

Volumn 60, Issue 44, 2004, Pages 10029-10038

  Jiang, Hua ^a   Maurizot, Victor ^a   Huc, Ivan ^a  

^a INSTITUT EUROPÉEN DE CHIMIE ET BIOLOGIE   (France)

Author keywords

Helical structures; Molecular recognition; Pi interactions; Self assembly

Indexed keywords

AMIDE; BENZYL DERIVATIVE; CARBAMIC ACID DERIVATIVE; DICARBOXYLIC ACID; MONOMER; OLIGOMER; PYRIDINE;

ARTICLE; DEGRADATION KINETICS; DIMERIZATION; ENTHALPY; ENTROPY; IN SITU HYBRIDIZATION; MOLECULAR DYNAMICS; MOLECULAR INTERACTION; MOLECULAR MECHANICS; NUCLEAR MAGNETIC RESONANCE; OLIGOMERIZATION; PRIORITY JOURNAL; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; TEMPERATURE DEPENDENCE;

EID: 4644313993     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2004.07.078     Document Type: Article

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40. Final products were purified by chromatography at least three times on TLC or radial chromatography prior to NMR studies. The impurities can be characterized as such and not as being other conformations/aggregates of the oligomers because: (i) TLC reveals their presence; (ii) the line shape of their signals remains sharp at any temperature even when the rest of the spectrum broadens due to coalescence phenomena; (iii) when the concentration is varied, the proportions of single and double helices varies but the quantity of 'impurity' is proportional to neither of them: it remains proportional to the total concentration of single and double helices.
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