-
3
-
-
0035781106
-
-
Hawker, C. J.; Bosman, A. W.; Harth, E. Chem. Rev. 2001,101, 3661-3668.
-
(2001)
Chem. Rev
, vol.101
, pp. 3661-3668
-
-
Hawker, C.J.1
Bosman, A.W.2
Harth, E.3
-
4
-
-
22744450025
-
-
(a) Moad, G.; Rizzardo, E.; Thang, S. H. Aust. J. Chem. 2005, 58, 379-410.
-
(2005)
Aust. J. Chem
, vol.58
, pp. 379-410
-
-
Moad, G.1
Rizzardo, E.2
Thang, S.H.3
-
5
-
-
30644477371
-
-
(b) Perrier, S.; Takolpuckdee, P. J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 5347-5393.
-
(2005)
J. Polym. Sci., Part A: Polym. Chem
, vol.43
, pp. 5347-5393
-
-
Perrier, S.1
Takolpuckdee, P.2
-
7
-
-
0032135925
-
-
(a) Chiefari, J.; Chong, Y. K.; Ercole, F.; Krstina, J.; Jeffery, J.; Le, T. P. T.; Mayadunne, R. T. A.; Meijs, G. F.; Moad, C. L.; Moad, G.; Rizzardo, E.; Thang, S. H. Macromolecules 1998, 31, 5559-5562.
-
(1998)
Macromolecules
, vol.31
, pp. 5559-5562
-
-
Chiefari, J.1
Chong, Y.K.2
Ercole, F.3
Krstina, J.4
Jeffery, J.5
Le, T.P.T.6
Mayadunne, R.T.A.7
Meijs, G.F.8
Moad, C.L.9
Moad, G.10
Rizzardo, E.11
Thang, S.H.12
-
8
-
-
0033646992
-
-
(b) Charmot, D.; Corpart, P.; Adam, H.; Zard, S. Z.; Biadatti, T.; Bouhadir, G. Macromol. Symp. 2000, 150, 23-32.
-
(2000)
Macromol. Symp
, vol.150
, pp. 23-32
-
-
Charmot, D.1
Corpart, P.2
Adam, H.3
Zard, S.Z.4
Biadatti, T.5
Bouhadir, G.6
-
9
-
-
45849098992
-
-
4b
-
4b
-
-
-
-
10
-
-
33847252111
-
-
For excellent reviews, see: a
-
For excellent reviews, see: (a) Lowe, A. B.; McCormick, C. L. Prog. Polym. Sci. 2007, 32, 283-351.
-
(2007)
Prog. Polym. Sci
, vol.32
, pp. 283-351
-
-
Lowe, A.B.1
McCormick, C.L.2
-
11
-
-
34250815935
-
-
(b) Barner, L.; Davis, T. P.; Stenzel, M. H.; Barner-Kowollik, C. Macromol. Rapid Commun. 2007, 28, 539-559.
-
(2007)
Macromol. Rapid Commun
, vol.28
, pp. 539-559
-
-
Barner, L.1
Davis, T.P.2
Stenzel, M.H.3
Barner-Kowollik, C.4
-
12
-
-
0036729860
-
-
For selected examples, see: a
-
For selected examples, see: (a) Quinn, J. F.; Chaplin, R. P.; Davis, T. P. J. Polym. Sci., Polym. Chem. 2002, 40, 2956-2966.
-
(2002)
J. Polym. Sci., Polym. Chem
, vol.40
, pp. 2956-2966
-
-
Quinn, J.F.1
Chaplin, R.P.2
Davis, T.P.3
-
13
-
-
7244224874
-
-
(b) Skaff, H.; Emrick, T. Angew. Chem., Int. Ed. 2004, 43, 5383-5386.
-
(2004)
Angew. Chem., Int. Ed
, vol.43
, pp. 5383-5386
-
-
Skaff, H.1
Emrick, T.2
-
14
-
-
7544242668
-
-
(c) Schilli, C. M.; Zhang, M. F.; Rizzardo, E.; Thang, S. H.; Chong, Y. K.; Edwards, K.; Karlsson, G.; Muller, A. H. E. Macromolecules 2004, 37, 7861-7866.
-
(2004)
Macromolecules
, vol.37
, pp. 7861-7866
-
-
Schilli, C.M.1
Zhang, M.F.2
Rizzardo, E.3
Thang, S.H.4
Chong, Y.K.5
Edwards, K.6
Karlsson, G.7
Muller, A.H.E.8
-
15
-
-
33748543244
-
-
(d) O'Reilly, R. K.; Joralemon, M. J.; Hawker, C. J.; Wooley, K. L. Chem.-Eur. J. 2006, 12, 6776-6786.
-
(2006)
Chem.-Eur. J
, vol.12
, pp. 6776-6786
-
-
O'Reilly, R.K.1
Joralemon, M.J.2
Hawker, C.J.3
Wooley, K.L.4
-
16
-
-
34548229470
-
-
(e) Cambre, J. N.; Roy, D.; Gondi, S. R.; Sumerlin, B. S. J. Am. Chem. Soc. 2007, 129, 10348-10349.
-
(2007)
J. Am. Chem. Soc
, vol.129
, pp. 10348-10349
-
-
Cambre, J.N.1
Roy, D.2
Gondi, S.R.3
Sumerlin, B.S.4
-
18
-
-
39149134297
-
-
For leading discussions of the mechanism of RAFT polymerizations, see: a
-
For leading discussions of the mechanism of RAFT polymerizations, see: (a) Moad, G.; Rizzardo, E.; Thang, S. H. Polymer 2008, 49, 1079-1131.
-
(2008)
Polymer
, vol.49
, pp. 1079-1131
-
-
Moad, G.1
Rizzardo, E.2
Thang, S.H.3
-
19
-
-
33750062586
-
-
(b) Barner-Kowollik, C.; Buback, M.; Charleux, B.; Coote, M. L.; Drache, M.; Fukuda, T.; Goto, A.; Klumperman, B.; Lowe, A. B.; Mcleary, J. B.; Moad, G.; Monteiro, M. J.; Sanderson, R. D.; Tonge, M. P.; Vana, P. J. Polym. Sci., Part A: Polym. Chem. 2006, 44, 5809-5831.
-
(2006)
J. Polym. Sci., Part A: Polym. Chem
, vol.44
, pp. 5809-5831
-
-
Barner-Kowollik, C.1
Buback, M.2
Charleux, B.3
Coote, M.L.4
Drache, M.5
Fukuda, T.6
Goto, A.7
Klumperman, B.8
Lowe, A.B.9
Mcleary, J.B.10
Moad, G.11
Monteiro, M.J.12
Sanderson, R.D.13
Tonge, M.P.14
Vana, P.15
-
20
-
-
0037426491
-
-
Chong, Y. K.; Krstina, J.; Le, T. P. T.; Moad, G.; Postma, A.; Rizzardo, E.; Thang, S. H. Macromolecules 2003, 36, 2256-2272.
-
(2003)
Macromolecules
, vol.36
, pp. 2256-2272
-
-
Chong, Y.K.1
Krstina, J.2
Le, T.P.T.3
Moad, G.4
Postma, A.5
Rizzardo, E.6
Thang, S.H.7
-
21
-
-
0037426460
-
-
Chiefari, J.; Mayadunne, R. T. A.; Moad, C. L.; Moad, G.; Rizzardo, E.; Postma, A.; Skidmore, M. A.; Thang, S. H. Macromolecules 2003, 36, 2273-2283.
-
(2003)
Macromolecules
, vol.36
, pp. 2273-2283
-
-
Chiefari, J.1
Mayadunne, R.T.A.2
Moad, C.L.3
Moad, G.4
Rizzardo, E.5
Postma, A.6
Skidmore, M.A.7
Thang, S.H.8
-
22
-
-
0038606275
-
-
Stenzel, M.; Cummins, L.; Roberts, G. E.; Davis, T. P.; Vana, P.; Barner-Kowollik, C. Macromol. Chem. Phys. 2003, 204, 1160-1168.
-
(2003)
Macromol. Chem. Phys
, vol.204
, pp. 1160-1168
-
-
Stenzel, M.1
Cummins, L.2
Roberts, G.E.3
Davis, T.P.4
Vana, P.5
Barner-Kowollik, C.6
-
23
-
-
2342491825
-
-
For examples of cationic dithioester-based RAFT agents containing ammonium groups distal to their dithio moieties, see: (a) Baussard, J.-F, Habib-Jiwan, J.-L, Laschewsky, A, Mertoglu, M, Storsberg, J. Polymer 2004, 45, 3615-3626
-
For examples of cationic dithioester-based RAFT agents containing ammonium groups distal to their dithio moieties, see: (a) Baussard, J.-F.; Habib-Jiwan, J.-L.; Laschewsky, A.; Mertoglu, M.; Storsberg, J. Polymer 2004, 45, 3615-3626.
-
-
-
-
24
-
-
18744369351
-
-
(b) Mertoglu, M.; Laschewsky, A.; Skrabania, K.; Wieland, C. Macromolecules 2005, 38, 3601-3614.
-
(2005)
Macromolecules
, vol.38
, pp. 3601-3614
-
-
Mertoglu, M.1
Laschewsky, A.2
Skrabania, K.3
Wieland, C.4
-
25
-
-
35348997354
-
-
For an example of a RAFT polymerization mediated by a quarternary dithiocarbamate, see
-
(c) Samakande, A.; Sanderson, R. D.; Hartmann, P. C. Synth. Commun. 2007, 37, 3861-3872. For an example of a RAFT polymerization mediated by a quarternary dithiocarbamate, see:
-
(2007)
Synth. Commun
, vol.37
, pp. 3861-3872
-
-
Samakande, A.1
Sanderson, R.D.2
Hartmann, P.C.3
-
26
-
-
0035538391
-
-
(d) Kanagasabapathy, S.; Sudalai, A.; Benicewicz, B. C. Macromol. Rapid Commun. 2001, 22, 1076-1080.
-
(2001)
Macromol. Rapid Commun
, vol.22
, pp. 1076-1080
-
-
Kanagasabapathy, S.1
Sudalai, A.2
Benicewicz, B.C.3
-
27
-
-
0002138516
-
-
(a) Bourissou, D.; Guerret, O.; Gabbaï, F. P.; Bertrand, G. Chem. Rev. 2000, 100, 39-92.
-
(2000)
Chem. Rev
, vol.100
, pp. 39-92
-
-
Bourissou, D.1
Guerret, O.2
Gabbaï, F.P.3
Bertrand, G.4
-
28
-
-
0030660076
-
-
(b) Herrmann, W. A.; Köcher, C. Angew. Chem., Int. Ed. Engl. 1997, 36, 2163-2165.
-
(1997)
Angew. Chem., Int. Ed. Engl
, vol.36
, pp. 2163-2165
-
-
Herrmann, W.A.1
Köcher, C.2
-
29
-
-
38349181434
-
-
(a) Kamber, N. E.; Jeong, W.; Waymouth, R. M.; Pratt, R. C.; Lohmeijer, B. G. G.; Hedrick, J. L. Chem. Rev. 2007, 107, 5813-5840.
-
(2007)
Chem. Rev
, vol.107
, pp. 5813-5840
-
-
Kamber, N.E.1
Jeong, W.2
Waymouth, R.M.3
Pratt, R.C.4
Lohmeijer, B.G.G.5
Hedrick, J.L.6
-
30
-
-
34250870731
-
-
(b) Marion, N.; Diez-González, M.; Nolan, S. P. Angew. Chem. Int. Ed. 2007, 46, 2988-3000.
-
(2007)
Angew. Chem. Int. Ed
, vol.46
, pp. 2988-3000
-
-
Marion, N.1
Diez-González, M.2
Nolan, S.P.3
-
31
-
-
9444269876
-
-
(c) Jensen, T. R.; Breyfogle, L. E.; Hillmyer, M. A.; Tolman, W. B. Chem. Commun. 2004, 2504-2505.
-
(2004)
Chem. Commun
, pp. 2504-2505
-
-
Jensen, T.R.1
Breyfogle, L.E.2
Hillmyer, M.A.3
Tolman, W.B.4
-
32
-
-
0037433492
-
-
(d) Nyce, G. W.; Glauser, T.; Connor, E. F.; Mock, A.; Waymouth, R. M.; Hedrick, J. L. J. Am. Chem. Soc 2003, 125, 3046-3056.
-
(2003)
J. Am. Chem. Soc
, vol.125
, pp. 3046-3056
-
-
Nyce, G.W.1
Glauser, T.2
Connor, E.F.3
Mock, A.4
Waymouth, R.M.5
Hedrick, J.L.6
-
33
-
-
0037065680
-
-
(e) Connor, E. F.; Nyce, G. W.; Myers, M.; Mock, A.; Hedrick, J. L. J. Am. Chem. Soc. 2002, 124, 914-915.
-
(2002)
J. Am. Chem. Soc
, vol.124
, pp. 914-915
-
-
Connor, E.F.1
Nyce, G.W.2
Myers, M.3
Mock, A.4
Hedrick, J.L.5
-
37
-
-
24744448661
-
-
(d) Boydston, A. J.; Williams, K. A.; Bielawski, C. W. J. Am. Chem. Soc. 2005, 127, 12496-12497.
-
(2005)
J. Am. Chem. Soc
, vol.127
, pp. 12496-12497
-
-
Boydston, A.J.1
Williams, K.A.2
Bielawski, C.W.3
-
38
-
-
33750345768
-
-
For a report describing the utility of 2 in Suzuki-Miyaura coupling reactions, see: Tudose, A.; Delaude, L.; André, B.; Demonceau, A. Tetrahedron Lett. 2006, 47, 8529-8533.
-
For a report describing the utility of 2 in Suzuki-Miyaura coupling reactions, see: Tudose, A.; Delaude, L.; André, B.; Demonceau, A. Tetrahedron Lett. 2006, 47, 8529-8533.
-
-
-
-
39
-
-
33644759185
-
-
The synthesis of 3 is similar to protocols used to prepare dithioester-based CTAs commonly used in RAFT polymerizations. See: Wood, M. R.; Duncalf, D. J.; Rannard, S. P.; Perrier, S. Org. Lett. 2006, 8, 553-556.
-
The synthesis of 3 is similar to protocols used to prepare dithioester-based CTAs commonly used in RAFT polymerizations. See: Wood, M. R.; Duncalf, D. J.; Rannard, S. P.; Perrier, S. Org. Lett. 2006, 8, 553-556.
-
-
-
-
40
-
-
45849142443
-
-
Rotational barriers were calculated at the Hartree-Fock 6-31G* level of theory, as implemented in the Spartan 2004 software package (Wavefunction, Inc., Irvine, CA 92612).
-
Rotational barriers were calculated at the Hartree-Fock 6-31G* level of theory, as implemented in the Spartan 2004 software package (Wavefunction, Inc., Irvine, CA 92612).
-
-
-
-
41
-
-
20444470809
-
-
For examples of dithioester-based RAFT agents where the dithioester moiety is attached to the 1- or 5-position of an imidazole, see: (a) Carter, S, Rimmer, S, Sturdy, A, Webb, M. Macromol. Biosci. 2005, 5, 373-378
-
For examples of dithioester-based RAFT agents where the dithioester moiety is attached to the 1- or 5-position of an imidazole, see: (a) Carter, S.; Rimmer, S.; Sturdy, A.; Webb, M. Macromol. Biosci. 2005, 5, 373-378.
-
-
-
-
42
-
-
27744434824
-
-
(b) Zhou, D.; Zhu, X.; Zhu, J.; Yin, H. J. Polym. Sci., Part A: Polym. Chem. 2005, 43, 4849-4856.
-
(2005)
J. Polym. Sci., Part A: Polym. Chem
, vol.43
, pp. 4849-4856
-
-
Zhou, D.1
Zhu, X.2
Zhu, J.3
Yin, H.4
-
43
-
-
0033204692
-
-
(c) Mayadunne, R. T. A.; Rizzardo, E.; Chiefari, J.; Chong, B. Y. K.; Moad, G.; Thang, S. H. Macromolecules 1999, 32, 6977-6980.
-
(1999)
Macromolecules
, vol.32
, pp. 6977-6980
-
-
Mayadunne, R.T.A.1
Rizzardo, E.2
Chiefari, J.3
Chong, B.Y.K.4
Moad, G.5
Thang, S.H.6
-
44
-
-
45849146433
-
CTA ratios (up to 200:1). After 2 days at 110 °C, no polymer was observed when either 3 or 4 was used as the CTA
-
As controls, polymerizations were performed in the absence of AIBN using various styrene
-
As controls, polymerizations were performed in the absence of AIBN using various styrene:CTA ratios (up to 200:1). After 2 days at 110 °C, no polymer was observed when either 3 or 4 was used as the CTA. These results suggested to us that AIBN was essential for forming active radicals and hence polymer.
-
These results suggested to us that AIBN was essential for forming active radicals and hence polymer
-
-
-
45
-
-
45849105455
-
-
Molecular weights and polydispersities were determined using gel permeation chromatography (eluent = DMF/LiBr or THF) and are reported relative to polystyrene standards.
-
Molecular weights and polydispersities were determined using gel permeation chromatography (eluent = DMF/LiBr or THF) and are reported relative to polystyrene standards.
-
-
-
-
46
-
-
45849106026
-
-
CTA.
-
CTA.
-
-
-
-
47
-
-
45849148404
-
-
3.
-
3.
-
-
-
-
48
-
-
35648987955
-
-
Vu, P. D.; Boydston, A. J.; Bielawski, C. W. Green Chem. 2007, 9, 1158-1159.
-
(2007)
Green Chem
, vol.9
, pp. 1158-1159
-
-
Vu, P.D.1
Boydston, A.J.2
Bielawski, C.W.3
|