Lewis base adducts of uranium triiodide and tris[bis(trimethylsilyl)amido] uranium

Inorganic Syntheses

Volumn 31, Issue , 1997, Pages 307-315

  Clark, David L ^a   Sattelberger, Alfred P ^a   Andersen, Richard A ^b  

^a LOS ALAMOS NATIONAL LABORATORY   (United States)

^b UNIVERSITY OF CALIFORNIA   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

AMIDES;

LEWIS BASE; METAL TURNINGS; TETRA-HYDROFURAN; TRIIODIDE; TRIMETHYLSILYL;

URANIUM COMPOUNDS;

EID: 0001559962     PISSN: 00738077     EISSN: None     Source Type: Book Series    
DOI: None     Document Type: Article

References (13)

1. J. J. Katz, L. R. Morss, and G. T. Seaborg, The Chemistry of the Actinide Elements, Vols. 1 and 2, Chapman and Hall, New York, 1986, and references therein.
2. D. L. Clark, A. P. Sattelberger, S. G. Bott, and R. N. Vrtis, Inorg. Cherry 28, 1771 (1989);
3. L. R. Avens, S. G. Bott, D. L. Clark, A. P. Sattelberger, J. G. Watkin, B. D. Zwick, Inorg. Chem., 33, 2248 (1994).
4. P. J. Fagan, J. M. Manriquez, T. J. Marks, C. S. Day, S. H. Vollmer, and V. W. Day, Organometallics, 1, 170 (1982).
5. R. A. Andersen, Inorg. Chem., 18, 1507 (1979).
6. D. F. Shriver and M. A. Drezdzon, The Manipulation of Air-Sensitive Compounds, 2nd ed., Wiley Interscience, New York, 1986.
7. A. L. Wayda and M. Y. Darensbourg, Experimental Organometallic Chemistry, ACS Symposium Series 357, American Chemical Society, Washington, DC, 1987.
8. The use of a helium atmosphere eliminates the static electricity problems that are often encountered in glove boxes operating under nitrogen or argon atmospheres.
9. 234 (6.75h).
10. At Los Alamos National Laboratory, we operate our radiological areas under the guidelines and specifications of DOE Order 5480.11.
11. 235. "Depleted uranium" is a term used to describe uranium metal that contains ∼0.2% of the 235 isotope. It is also referred to as D-38.
12. The checkers noted some slight differences (<1 ppm) in the chemical shifts they obtained versus those reported here. The chemical shifts of paramagnetic uranium(III) complexes are temperature and concentration dependent The data reported here were obtained on dilute solutions (∼0.05 M) at 20 ± 1°C at 250 MHz.
13. C. R. Krüger and H. Niederprüm, Inorg. Synth., 8, 15 (1966).