Rhodium(I), palladium(II) and platinum(II) coordination chemistry of the short-bite chiral ligands (Sc)-N,N-bis(diphenylphosphanyl)-sec- butylamine, (Ra,Ra)-N,N-bis(binaphthylphosphonito) phenylamine and (Ra,Sc)-N-(diphenylphosphanyl)-N- (binaphthylphosphonito)-sec-butylamine

European Journal of Inorganic Chemistry

Volumn , Issue 7, 2004, Pages 1447-1453

  Calabrò, Gianpiero ^a   Drommi, Dario ^a   Graiff, Claudia ^b   Faraone, Felice ^a   Tiripicchio, Antonio ^b  

^a UNIVERSITY OF MESSINA   (Italy)

^b UNIVERSITY OF PARMA   (Italy)

Author keywords

Chiral ligands; Enantioselectivity; Hydroformylation; Palladium; Platinum; Rhodium

Indexed keywords

ENANTIOSELECTIVITY; HYDROFORMYLATION; LIGANDS; PALLADIUM COMPOUNDS; PLATINUM COMPOUNDS; RHODIUM COMPOUNDS; STEREOCHEMISTRY; X RAY DIFFRACTION;

BINUCLEAR COMPOUNDS; CHIRAL LIGAND; CO-ORDINATION CHEMISTRIES; DICARBONYLS; HIGHER YIELD; MONO AND BINUCLEAR; MONONUCLEAR COMPOUNDS; PHOSPHONATES; SEC-BUTYLAMINE; X-RAY DIFFRACTION STUDIES;

CHLORINE COMPOUNDS;

BENZENE DERIVATIVE; CARBON MONOXIDE; CHLORINE DERIVATIVE; HEXANE; HYDROGEN; PALLADIUM COMPLEX; PHOSPHONIC ACID DERIVATIVE; PLATINUM DERIVATIVE; RHODIUM DERIVATIVE; STYRENE;

ARTICLE; CATALYSIS; CHELATION; CHEMICAL REACTION; DECOMPOSITION; HYDROFORMYLATION; HYDROLYSIS; OXIDATION; PRESSURE; PROTON NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS; TEMPERATURE; X RAY DIFFRACTION;

EID: 4544266382     PISSN: 14341948     EISSN: None     Source Type: Journal    
DOI: 10.1002/ejic.200300568     Document Type: Article

References (50)

1. For the most versatile classes of ligands, see the following reviews. Bisoxazolines: [1a] A. Pfaltz, Acc. Chem. Res. 1993, 26, 339.
2. [1b] A. K. Ghosh, P. Mathivanan, J. Cappiello, Tetrahedron: Asymmetry 1998, 9, 1.
3. [1c] J. S. Johnson, D. A. Evans, Acc. Chem. Res. 2000, 33, 325.
4. Phosphinooxazolines: [1d] G. Helmchen, A. Pfaltz, Acc. Chem. Res. 2000, 33, 336.
5. [1e] A. Pfaltz, Acta Chem. Scand., Ser. B 1996, 50, 189.
6. Phosphoramidites: [1f] B. L. Feringa, Acc. Chem. Res. 2000, 33, 346.
7. Wide-bite-angle ligands: [1g] P. C. J. Kamer, P. W. N. M. van Leeuwen, J. N. H. Reek, Acc. Chem. Res. 2001, 34, 895.
8. [1h] P. W. N. M. van Leeuwen, P. C. J. Kamer, J. N. H Reek, P. Dierkes, Chem. Rev. 2000, 100, 2741.
9. Ligands derived from the quinoline backbone: [1i] G. Franciò, C. G. Arena, F. Faraone, C. Graiff, M. Lanfranchi, A. Tiripicchio, Eur. J. Inorg. Chem. 1999, 1219.
10. [1j] G. Franciò, F. Faraone, W. Leitner, Angew. Chem. Int. Ed. 2000, 39, 1428.
11. [2a] J. K. Whitesell, Chem. Rev. 1989, 89, 1581.
12. [2b] L. Pu, Chem. Rev. 1998, 98, 2405.
13. [2c] C. Rosini, L. Franzini, A. Raffaelli, P. Salvadori, Synthesis 1992, 503.
14. [2d] T. Ohkuma, M. Koizumi, H. Doucet, T. Pham, M. Kozawa, K. Murata, E. Katayama, T. Yokozawa, T. Ikariya, R. Noyori, J. Am. Chem. Soc. 1998, 120, 13529 and references cited therein.
15. [2e] K. Mikami, S. Matsukawa, Nature 1997, 385, 613 and references cited therein.
16. G. Calabrò, D. Drommi, G. Bruno, F. Faraone, Dalton Trans. 2004, 81.
17. [4a] A. L. Balch, in Homogeneous Catalysis Using Metal Phosphine Complexes (Ed.: L. H. Pignolet), Plenum Press, New York, 1983, p. 167.
18. [4b] G. R. Newkome, Chem. Rev. 1993, 93, 2067.
19. [4c] R. Puddephatt, J. Chem. Soc. Rev. 1983, 12, 99.
20. [4d] B. Chaudret, B. Delavaux, R. Poilblanc, Coord. Chem. Rev. 1988, 86, 191.
21. [4e] M. S. Balakrishna, S. V. Reddy, S. S. Krishamurthy, J. F. Nixon, J. Burckett, St. Laurent, Coord. Chem. Rev. 1994, 129, 1.
22. [4f] B. R. Sutherland, M. Cowie, Organometallics 1985, 4, 1801.
23. [4g] J. T. Mague, Organometallics 1986, 5, 918.
24. [4h] S. Lo Schiavo, G. Bruno, F. Nicolò, P. Piraino, F. Faraone, Organometallics 1985, 4, 2091.
25. [4i] C. Arena, F. Faraone, M. Lanfranchi, E. Rotondo, A. Tiripicchio, Inorg. Chem. 1992, 31, 4797.
26. [4j] M. Cowie, G. Vasapollo, B. R. Sutherland, J. P. Ennett, Inorg. Chem. 1986, 25, 2648.
27. [4k] M. Cowie, T. G. Southern, Inorg. Chem. 1982, 21, 246.
28. [4l] B. A. Vaartstra, K. N. O'Brien, R. Eisenberg, M. Cowie, Inorg. Chem. 1988, 27, 3668.
29. [4m] D. J. Anderson, K. W. Kramarz, R. Eisenberg, Inorg. Chem. 1996, 35, 2688.
30. [4n] J. R. Torkelson, F. H. Antwi-Nsiah, R. McDonald, M. Cowie, J. G. Pruis, K. J. Jalkanen, R. L. DeKock, J. Am. Chem. Soc. 1999, 121, 3666.
31. [5a] E. Drend, D. Arnoldy, P. H. M. Budzelaar, J. Organomet. Chem. 1993, 455, 247.
32. [5b] Y. Gao, J. K. Kuncheria, H. A. Jenkins, R. J. Puddephatt, G. P. A. Yap, J. Chem. Soc., Dalton Trans. 2000, 3212.
33. [5c] A. Scrivanti, V. Beghetto, E. Campagna, M. Zenato, U. Matteoli, Organometallics 1998, 17, 630.
34. [5d] M. E. Broussard, B. Juma, S. G. Train, W. Peng, S. A. Laneman, G. G. Stanley, Science 1993, 260, 1784.
35. [5e] G. Franciò, R. Scopelliti, C. G. Arena, G. Bruno, D. Drommi, F. Faraone, Organometallics 1998, 17, 338.
36. [5f] S. J. Dossett, A. Gillon, G. Orpen, J. S. Fleming, P. G. Pringle, D. F. Wass, M. D. Jones, Chem. Commun. 2001, 699.
37. [6a] Y. Yamanoi, T. Imamoto, J. Org Chem. 1999, 64, 2988.
38. [6b] I. D. Gridnev, Y. Yamanoi, N. Higashi, H. Tsuruta, M. Yasutake, T. Imamoto, Adv. Synth. Catal. 2001, 343, 118.
39. [6c] A. Marinetti, C. Le Menn, L. Ricard, Organometallics 1995, 14, 4983.
40. [6d] R. P. Kamalesh Babu, S. S. Krishnamurthy, M. Nethaji, Tetrahedron: Asymmetry 1995, 6, 427.
41. [7a] P. W. Lednor, W. Beck, H. G. Fick, H. Zippel, Chem. Ber. 1978, 111, 615.
42. [7b] N. C. Payne, D. W. Stephan, J. Organomet. Chem. 1981, 221, 203.
43. E. J. Sekabunga, M. L. Smith, T. R. Webb, W. E. Hill, Inorg. Chem. 2002, 41, 1205.
44. S. Priya, M. S. Balakrishna, J. T. Mague, S. M. Mobin, Inorg. Chem. 2003, 42, 1272 and references cited therein.
45. [10a] J. P. Farr, F. E. Wood, A. L. Balch, Inorg. Chem. 1983, 22, 3387.
46. [10b] A. Maisonnat, J. P. Farr, A. L. Balch, Inorg. Chim. Acta 1981, 53, L217.
47. [10c] J. P. Farr, M. M. Olmstead, A. L. Balch, J. Am. Chem. Soc. 1980, 102, 6654.
48. II structure.
49. P. H. M. Budzelaar, J. H. G. Frijns, A. G. Orpen, Organometallics 1990, 9, 1222.
50. G. M. Sheldrick, SHELXTL v5.1: Program for the Refinement of Crystal Structures 97-2, University of Göttingen, Göttingen, Germany, 1998.