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Volumn 121, Issue 15, 1999, Pages 3666-3683

Metal-metal cooperativity effects in promoting C-H bond cleavage of a methyl group by an adjacent metal center

Author keywords

[No Author keywords available]

Indexed keywords

IRIDIUM COMPLEX; METAL COMPLEX;

EID: 0033594516     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja983525o     Document Type: Article
Times cited : (54)

References (84)
  • 2
    • 11944267679 scopus 로고
    • See for example: (a) Marks, T. J. Acc. Chem. Res. 1992, 25, 57. (b) Zaera, F. Chem. Rev. 1995, 95, 2651. (c) Atwood, J. D. Coord. Chem. Rev. 1988, 83, 93.
    • (1992) Acc. Chem. Res. , vol.25 , pp. 57
    • Marks, T.J.1
  • 3
    • 4243910579 scopus 로고
    • See for example: (a) Marks, T. J. Acc. Chem. Res. 1992, 25, 57. (b) Zaera, F. Chem. Rev. 1995, 95, 2651. (c) Atwood, J. D. Coord. Chem. Rev. 1988, 83, 93.
    • (1995) Chem. Rev. , vol.95 , pp. 2651
    • Zaera, F.1
  • 4
    • 0002983832 scopus 로고
    • See for example: (a) Marks, T. J. Acc. Chem. Res. 1992, 25, 57. (b) Zaera, F. Chem. Rev. 1995, 95, 2651. (c) Atwood, J. D. Coord. Chem. Rev. 1988, 83, 93.
    • (1988) Coord. Chem. Rev. , vol.83 , pp. 93
    • Atwood, J.D.1
  • 12
    • 0344817504 scopus 로고
    • See for example: (a) Schmidt, G. F.; Muetterties, E. L.; Beno, M. A.; Williams, J. M. Proc. Natl. Acad. Sci. U.S.A. 1981, 78, 1318. (b) Kulzick, M. A.; Price, R. T.; Andersen, R. A.; Muetterties, E. L. J. Organomet. Chem. 1987, 333, 105. (c) Reinking, M. K.; Fanwick, P. E.; Kubiak, C. P. Angew. Chem., Int. Ed. Engl. 1989, 28, 1377.
    • (1981) Proc. Natl. Acad. Sci. U.S.A. , vol.78 , pp. 1318
    • Schmidt, G.F.1    Muetterties, E.L.2    Beno, M.A.3    Williams, J.M.4
  • 13
    • 33645802338 scopus 로고
    • See for example: (a) Schmidt, G. F.; Muetterties, E. L.; Beno, M. A.; Williams, J. M. Proc. Natl. Acad. Sci. U.S.A. 1981, 78, 1318. (b) Kulzick, M. A.; Price, R. T.; Andersen, R. A.; Muetterties, E. L. J. Organomet. Chem. 1987, 333, 105. (c) Reinking, M. K.; Fanwick, P. E.; Kubiak, C. P. Angew. Chem., Int. Ed. Engl. 1989, 28, 1377.
    • (1987) J. Organomet. Chem. , vol.333 , pp. 105
    • Kulzick, M.A.1    Price, R.T.2    Andersen, R.A.3    Muetterties, E.L.4
  • 14
    • 84990137270 scopus 로고
    • See for example: (a) Schmidt, G. F.; Muetterties, E. L.; Beno, M. A.; Williams, J. M. Proc. Natl. Acad. Sci. U.S.A. 1981, 78, 1318. (b) Kulzick, M. A.; Price, R. T.; Andersen, R. A.; Muetterties, E. L. J. Organomet. Chem. 1987, 333, 105. (c) Reinking, M. K.; Fanwick, P. E.; Kubiak, C. P. Angew. Chem., Int. Ed. Engl. 1989, 28, 1377.
    • (1989) Angew. Chem., Int. Ed. Engl. , vol.28 , pp. 1377
    • Reinking, M.K.1    Fanwick, P.E.2    Kubiak, C.P.3
  • 15
    • 2142821880 scopus 로고
    • See for example: (a) Dawkins, G. M.; Green, M.; Orpen, A. G.; Stone, F. G. A. J. Chem. Soc. Chem. Commun. 1982, 41. (b) Calvert, R. B.; Shapley, J. R. J. Am. Chem. Soc. 1978, 100, 7726. (c) Brookhart, M.; Green, M. L. H.; Wong, L.-L. Prog. Inorg. Chem. 1988, 36, 1; and references therein.
    • (1982) J. Chem. Soc. Chem. Commun. , pp. 41
    • Dawkins, G.M.1    Green, M.2    Orpen, A.G.3    Stone, F.G.A.4
  • 16
    • 33947094328 scopus 로고
    • See for example: (a) Dawkins, G. M.; Green, M.; Orpen, A. G.; Stone, F. G. A. J. Chem. Soc. Chem. Commun. 1982, 41. (b) Calvert, R. B.; Shapley, J. R. J. Am. Chem. Soc. 1978, 100, 7726. (c) Brookhart, M.; Green, M. L. H.; Wong, L.-L. Prog. Inorg. Chem. 1988, 36, 1; and references therein.
    • (1978) J. Am. Chem. Soc. , vol.100 , pp. 7726
    • Calvert, R.B.1    Shapley, J.R.2
  • 17
    • 0002426616 scopus 로고
    • and references therein
    • See for example: (a) Dawkins, G. M.; Green, M.; Orpen, A. G.; Stone, F. G. A. J. Chem. Soc. Chem. Commun. 1982, 41. (b) Calvert, R. B.; Shapley, J. R. J. Am. Chem. Soc. 1978, 100, 7726. (c) Brookhart, M.; Green, M. L. H.; Wong, L.-L. Prog. Inorg. Chem. 1988, 36, 1; and references therein.
    • (1988) Prog. Inorg. Chem. , vol.36 , pp. 1
    • Brookhart, M.1    Green, M.L.H.2    Wong, L.-L.3
  • 24
    • 0345248645 scopus 로고    scopus 로고
    • note
    • 2) = 0.1273 (all data).
  • 50
  • 59
    • 0344817461 scopus 로고
    • (c) All publications in J. Organomet. Chem 1995, 504, 1-155.
    • (1995) J. Organomet. Chem , vol.504 , pp. 1-155
  • 73
    • 0000665643 scopus 로고
    • See for example: (a) Casey, C. P.; Fagan, P. J.; Miles, W. H. J. Am. Chem. Soc. 1982, 104, 1134. (b) Green, M. L. H.; Hughes, A. K.; Popham, N. A.; Stephens, A. H. H.; Wong, L.-L. J. Chem. Soc., Dalton Trans. 1992, 3077.
    • (1982) J. Am. Chem. Soc. , vol.104 , pp. 1134
    • Casey, C.P.1    Fagan, P.J.2    Miles, W.H.3
  • 75
    • 0344817455 scopus 로고    scopus 로고
    • note
    • See for example, compound 2 and refs 49a and 54.
  • 76
    • 0344385741 scopus 로고    scopus 로고
    • note
    • We were unable to locate the transition state between IIIb (agostic) and IIIh by using automated procedures in the Mulliken software. Therefore, we completed a linear synchronous transit calculation connecting IIIb (agostic) with IIIh. Then we picked selected points near the top of the energy barrier, and carried out several additional calculations in which we optimized all of the parameters except the Ir-Ir-H angle. We believe that we have located the transition state by this means to within 0.5 kcal/mol. Additional studies are in progress to further examine the nature of the transition state for this system.


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