Synthesis and Structure of the Diphenyl Binuclear Rhodium A-Frame Complex Rh2(μ-CO)(Ph)2(dmpm)2

Inorganic Chemistry

Volumn 35, Issue 9, 1996, Pages 2688-2691

  Joe Anderson, D ^a   Kramarz, Kurt W ^a   Eisenberg, Richard ^a  

^a UNIVERSITY OF ROCHESTER   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

EID: 2742588424     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic951095m     Document Type: Article

References (37)

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19. 2, S = scan rate, C = total integrated peak count, R = ratio of scan time to background counting time, B = total background count, Lp = Lorentz-polarization factor, and p = p-factor.
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32. For purposes of comparison, the Cambridge Crystal Structure Database (see ref 33) was searched for complexes of the general type A (see text) in which M = a metal from group 8, 9, or 10. A-frames with multiple atoms in the bridge position Y (e.g.. 1,2-alkynyl but not 1,1-carbonyl) were somewhat arbitrarily excluded, as were complexes in which the coordination number about the metal was greater than 5. Phosphine substituents (e.g., methyl, phenyl, or fluoro), the bis(phosphine) bridge Z, and the ligands X were left unspecified. With these criteria, 51 structures were found to have a boat configuration, while only 3 were found with a chairilke configuration.
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