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3: In this case, the Lewis acid presumably both aided formation of the imine and decreased the time required for the aziridine-forming reaction
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note
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6 were used, see Ref. 6.
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note
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2/MeOH (1:1) solution. Crystallographic data (excluding structure factors) for the structure of cis-1,2,3-triphenylaziridine 4d in this Letter have been deposited with the Cambridge Crystallographic Data Centre as supplementary publication number CCDC 685188. Copies of the data can be obtained, free of charge, on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK, (fax: +44 1223 336033 or e-mail: deposit@ccdc.cam.ac.uk.).
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note
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Selective cis-aziridine-forming reactions from imines and diazo compounds are also known to be catalyzed by Brønsted acids, see Ref. 4l.
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