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31
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0345695693
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note
-
The same selectivity is observed with a catalyst prepared with 1.0 equiv of borane-THF complex, but catalyst formation requires longer periods of time.
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32
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0345695694
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note
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13 by reaction of benzhydrylamine with 1.0 equiv of aldehyde in methylene chloride at rt in the presence of anhydrous magnesium sulfate. After filtration, the solvent is removed and the imine purifed by crystallization from ethanol with the exception of 8h which is an oil and was used without purification.
-
-
-
-
33
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0344401166
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note
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Imines derived from pivaldehyde and 1-naphthylaldehyde would not undergo reaction under the conditions in Table 2.
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34
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33947313851
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35
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0344832680
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note
-
The enantiomeric excess of the aziridine 10a can be improved from 97.0 to 99.2% with one crystallization from methylene chloride and pentane.
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36
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18444414821
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Armesto, D.; Ortiz, M. J.; Perez-Ossoria, R., J. Chem. Soc., Perkin Trans. 1 1986, 2021.
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