Spontaneous generation of amphiphilic block copolymer micelles with multiple morphologies through interfacial instabilities

Journal of the American Chemical Society

Volumn 130, Issue 23, 2008, Pages 7496-7502

  Zhu, Jintao ^a   Hayward, Ryan C ^a  

^a UNIVERSITY OF MASSACHUSETTS   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ADDITION REACTIONS; ANESTHETICS; BLOCK COPOLYMERS; BUTADIENE; COLLOIDS; COPOLYMERIZATION; DROP FORMATION; DROPS; ELECTRON BEAM LITHOGRAPHY; EMULSIFICATION; EMULSIONS; ESTERS; ETHYLENE; FLUID MECHANICS; HYDROPHOBICITY; IRON; IRON OXIDES; MICELLES; MORPHOLOGY; PLASTIC PRODUCTS; POLYMERS; STRUCTURE (COMPOSITION);

(ETHYLENE VINYL ALCOHOL) COPOLYMERS; AMERICAN CHEMICAL SOCIETY (ACS); AMPHIPHILIC BLOCK COPOLYMERS; AMPHIPHILIC COPOLYMERS; AMPHIPHILIC(AP); AQUEOUS PHASE; BLOCK COPOLYMER MICELLES; CAPROLACTONE (PCL); CHLOROFORM (CF); CYLINDRICAL MICELLES; EMULSION DROPLETS; GENERAL (CO); HOMO POLYMERS; HYDROPHOBIC BLOCKS; HYDROPHOBIC SPECIES; INTERFACIAL INSTABILITIES; IRON OXIDE NANOPARTICLES; MICELLAR AGGREGATES; ORGANIC PHASE; POLY METHYL METHACRYLATE (PMMA); POLYETHYLENE OXIDE (PEO); SPHERICAL(PIVOT); SPONTANEOUS GENERATION; WORM-LIKE MICELLES;

PHASE INTERFACES;

ALKENE DERIVATIVE; CHLOROFORM; COPOLYMER; MACROGOL; ORGANIC SOLVENT; POLY(1,4 BUTADIENE); POLY(METHYL METHACRYLATE); POLYCAPROLACTONE; POLYSTYRENE; WATER;

ARTICLE; EMULSION; EVAPORATION; MICELLE; MOLECULAR WEIGHT;

MAGNETICS; MICELLES; NANOPARTICLES; POLYETHYLENE GLYCOLS; POLYMETHYL METHACRYLATE; POLYSTYRENES; SPECTROMETRY, FLUORESCENCE;

EID: 44949251871     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja801268e     Document Type: Article

References (55)

1. Förster, S.; Konrad, M. J. Mater. Chem. 2003, 13 (11), 2671-2688.
2. Glass, R.; Möller, M.; Spatz, J. P. Nanotechnology 2003, 14 (10), 1153-1160.
3. Rösler, A.; Vandermeulen, G. W. M.; Klok, H. A. Adv. Drug Delivery Rev. 2001, 53 (1), 95-108.
4. Dalhaimer, P.; Engler, A. J.; Parthasarathy, R.; Discher, D. E. Biomacromolecules 2004, 5 (5), 1714-1719.
5. Gaucher, G.; Dufresne, M. H.; Sant, V. P.; Kang, N.; Maysinger, D.; Leroux, J. C. J. Controlled Release 2005, 109 (1-3), 169-188.
6. Riess, G. Prog. Polym. Sci. 2003, 28 (7), 1107-1170.
7. Geng, Y.; Discher, D. E. J. Am. Chem. Soc. 2005, 127 (37), 12780-12781.
8. Geng, Y.; Discher, D. E. Polymer 2006, 47 (7), 2519-2525.
9. Kim, Y.; Dalhaimer, P.; Christian, D. A.; Discher, D. E. Nanotechnology 2005, 16 (7), S484-S491.
10. Giacomelli, C.; Schmidt, V.; Borsali, R. Macromolecules 2007, 40 (6), 2148-2157.
11. Lodge, T. P.; Rasdal, A.; Li, Z. B.; Hillmyer, M. A. J. Am. Chem. Soc. 2005, 127 (50), 17608-17609.
12. Geng, Y.; Dalhaimer, P.; Cai, S. S.; Tsai, R.; Tewari, M.; Minko, T.; Discher, D. E. Nat. Nanotechnol. 2007, 2 (4), 249-255.
13. Lei, L. C.; Gohy, J. F.; Willet, N.; Zhang, J. X.; Varshney, S.; Jérôme, R. Macromolecules 2004, 37 (3), 1089-1094.
14. Chen, Z. Y.; Cui, H. G.; Hales, K.; Li, Z. B.; Qi, K.; Pochan, D. J.; Wooley, K. L. J. Am. Chem. Soc. 2005, 127 (24), 8592-8593.
15. Thünemann, A. F.; Kubowicz, S.; von Berlepsch, H.; Möhwald, H. Langmuir 2006, 22 (6), 2506-2510.
16. Li, Z. B.; Kesselman, E.; Talmon, Y.; Hillmyer, M. A.; Lodge, T. P. Science 2004, 306 (5693), 98-101.
17. Cui, H. G.; Chen, Z. Y.; Zhong, S.; Wooley, K. L.; Pochan, D. J. Science 2007, 317 (5838), 647-650.
18. Wang, X. S.; Guerin, G.; Wang, H.; Wang, Y. S.; Manners, I.; Winnik, M. A. Science 2007, 317 (5838), 644-647.
19. Zhong, S.; Cui, H. G.; Chen, Z. Y.; Wooley, K. L.; Pochan, D. J. Soft Matter 2008, 4 (1), 90-93.
20. Jain, S.; Bates, F. S. Science 2003, 300 (5618), 460-464.
21. Jain, S.; Bates, F. S. Macromolecules 2004, 37 (4), 1511-1523.
22. Brannan, A. K.; Bates, F. S. Macromolecules 2004, 37 (24), 8816-8819.
23. Nikova, A. T.; Gordon, V. D.; Cristobal, G.; Talingting, M. R.; Bell, D. C.; Evans, C.; Joanicot, M.; Zasadzinski, J. A.; Weitz, D. A. Macromolecules 2004, 37 (6), 2215-2218.
24. Zupancich, J. A.; Bates, F. S.; Hillmyer, M. A. Macromolecules 2006, 39 (13), 4286-4288.
25. Liu, G. J.; Yan, X. H.; Duncan, S. Macromolecules 2002, 35 (26), 9788-9793.
26. Zhang, L. F.; Eisenberg, A. J. Am. Chem. Soc. 1996, 118 (13), 3168-3181.
27. Zhang, L. F.; Eisenberg, A. J. Polym. Sci., Part B: Polym. Phys. 1999, 37 (13), 1469-1484.
28. Shen, H. W.; Zhang, L. F.; Eisenberg, A. J. Am. Chem. Soc. 1999, 121 (12), 2728-2740.
29. Erhardt, R.; Zhang, M. F.; Böker, A.; Zettl, H.; Abetz, C.; Frederik, P.; Krausch, G.; Abetz, V.; Müller, A. H. E. J. Am. Chem. Soc. 2003, 125 (11), 3260-3267.
30. Liu, G. J. Adv. Mater. 1997, 9 (5), 437-439.
31. Kubowicz, S.; Baussard, J. F.; Lutz, J. F.; Thünemann, A. F.; von Berlepsch, H.; Laschewsky, A. Angew. Chem., Int. Ed. 2005, 44 (33), 5262-5265.
32. Gohy, J. F.; Willet, N.; Varshney, S.; Zhang, J. X.; Jérôme, R. Angew. Chem., Int. Ed. 2001, 40 (17), 3214-3216.
33. Park, E. K.; Lee, S. B.; Lee, Y. M. Biomaterials 2005, 26 (9), 1053-1061.
34. Giacomelli, C.; Schmidt, V.; Borsali, R. Langmuir 2007, 23 (13), 6947-6955.
35. Kim, B. S.; Qiu, J. M.; Wang, J. P.; Taton, T. A. Nano Lett. 2005, 5 (10), 1987-1991.
36. Sanchez-Gaytan, B. L.; Cui, W. H.; Kim, Y. J.; Mendez-Polanco, M. A.; Duncan, T. V.; Fryd, M.; Wayland, B. B.; Park, S. J. Angew. Chem., Int. Ed. 2007, 46 (48), 9235-9238.
37. Yusuf, H.; Kim, W. G.; Lee, D. H.; Guo, Y. Y.; Moffitt, M. G. Langmuir 2007, 23 (2), 868-878.
38. Ai, H.; Flask, C.; Weinberg, B.; Shuai, X.; Pagel, M. D.; Farrell, D.; Duerk, J.; Gao, J. M. Adv. Mater. 2005, 17 (16), 1949-1952.
39. Safarik, I.; Safarikova, M. Monatsh. Chem. 2002, 133 (6), 737-759.
40. Wang, H.; Lin, W. J.; Fritz, K. P.; Scholes, G. D.; Winnik, M. A.; Manners, I. J. Am. Chem. Soc. 2007, 129 (43), 12924-12925.
41. The emulsion initially consists almost entirely of chloroform-in-water droplets, with the double emulsion structure emerging only as the droplets shrink and become supersaturated with water. Presumably this behavior reflects the increasing surface activity of PS-PEO copolymers as their concentration within the droplets increases.
42. López-Montilla, J. C.; Herrera-Morales, P. E.; Pandey, S.; Shah, D. O. J. Dispersion Sci. Technol. 2002, 23 (1-3), 219-268.
43. López-Montilla, J. C.; Herrera-Morales, P. E.; Shah, D. O. Langmuir 2002, 18 (11), 4258-4262.
44. Granek, R.; Ball, R. C.; Cates, M. E. J Phys II 1993, 3 (6), 829-849.
45. Granek, R. Langmuir 1996, 12 (21), 5022-5027.
46. Jiao, J. B.; Kramer, E. J.; de Vos, S.; Möller, M.; Koning, C. Macromolecules 1999, 32 (19), 6261-6269.
47. Jiao, J. B.; Kramer, E. J.; de Vos, S.; Möller, M.; Koning, C. Polymer 1999, 40 (12), 3585-3588.
48. Kim, B. J.; Kang, H. M.; Char, K.; Katsov, K.; Fredrickson, G. H.; Kramer, E. J. Macromolecules 2005, 38 (14), 6106-6114.
49. Girard-Reydet, E.; Pascault, J. P.; Brown, H. R. Macromolecules 2001, 34 (15), 5349-5353.
50. Zhu, J. T.; Hayward, R. C. Angew. Chem., Int. Ed. 2008, 47 (11), 2113-2116.
51. Gindy, M. E.; Panagiotopoulos, A. Z.; Prud'homme, R. K. Langmuir 2008, 24 (1), 83-90.
52. Whitmore, M. D.; Smith, T. W. Macromolecules 1994, 27 (17), 4673-4683.
53. Lei, L. C.; Gohy, J. F.; Willet, N.; Zhang, J. X.; Varshney, S.; Jérôme, R. Polymer 2004, 45 (13), 4375-4381.
54. Kang, Y. J.; Taton, T. A. Angew. Chem., Int. Ed. 2005, 44 (3), 409-412.
55. Euliss, L. E.; Grancharov, S. G.; O'Brien, S.; Deming, T. J.; Stucky, G. D.; Murray, C. B.; Held, G. A. Nano Lett. 2003, 3 (11), 1489-1493.