Unique toroidal morphology from composition and sequence control of triblock copolymers

Journal of the American Chemical Society

Volumn 127, Issue 24, 2005, Pages 8592-8593

  Chen, Zhiyun ^a   Cui, Honggang ^b   Hales, Kelly ^b   Li, Zhibin ^b   Qi, Kai ^a   Pochan, Darrin J ^b   Wooley, Karen L ^a  

^a WASHINGTON UNIVERSITY   (United States)

^b University of Delaware   (United States)

Author keywords

[No Author keywords available]

Indexed keywords

ACRYLIC ACID; ACRYLIC ACID METHYL ESTER; COPOLYMER; STYRENE; TRIBLOCK COPOLYMER; UNCLASSIFIED DRUG;

ARTICLE; CHEMICAL COMPOSITION; CHEMICAL STRUCTURE; HYDROPHILICITY; HYDROPHOBICITY; MATERIALS; POLYMERIZATION; REACTION ANALYSIS; STRUCTURE ANALYSIS; SYNTHESIS; THERMODYNAMICS; TRANSMISSION ELECTRON MICROSCOPY;

ACRYLIC RESINS; DRUG DELIVERY SYSTEMS; EDETIC ACID; HYDROPHOBICITY; MICROSCOPY, ELECTRON, TRANSMISSION; NANOSTRUCTURES; POLYMERS; POLYMETHACRYLIC ACIDS; POLYSTYRENES;

EID: 20944439172     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja050290p     Document Type: Article

References (34)

1. Halperin, A.; Tirrell, M.; Lodge, T. P. Adv. Polym. Sci. 1992, 100, 31.
2. Prochazka, K.; Martin, T. J.; Munk, P.; Webber, S. E. Macromolecules 1996, 29, 6518.
3. Stupp, S. I.; LeBonheur, V.; Walker, K.; Li, L. S.; Huggins, K. E.; Keser, M.; Amstutz, A. Science 1997, 276, 384.
4. Shen, H.; Eisenberg, A. Macromolecules 2000, 33, 2561.
5. Discher, D. E.; Eisenberg, A. Science 2002, 297, 967.
6. Yan, X.; Liu, G.; Li, Z. J. Am. Chem. Soc. 2004, 126, 10059.
7. Jain, S.; Bates, F. S. Science 2003, 300, 460.
8. Cornelissen, J. J. L. M.; Fischer, M.; Sommerdijk, N. A. J. M.; Nolte, R. J. M. Science 1998, 280, 1427.
9. Lodge, T. P.; Hillmyer, M. A.; Zhou, Z.; Talmon, Y. Macromolecules 2004, 37, 6680.
10. Bates, F. S. Science 1991, 251, 898.
11. Bellomo, E. G.; Wyrsta, M. D.; Pakstis, L.; Pochan, D. J.; Deming, T. J. Nat. Mater. 2004, 3, 244.
12. Thordarson, P.; Coumans, R. G. E.; Elemans, J. A. A. W.; Thomassen, P. J.; Visser, J.; Rowan, A. E.; Nolte, R. J. M. Angew. Chem., Int. Ed. 2004, 43, 4755.
13. Vriezema, D. M.; Kros, A.; de Gelder, R.; Cornelissen, J. J. L. M.; Rowan, A. E.; Nolte, R. J. M. Macromolecules 2004, 37, 4736.
14. Ahmed, F.; Discher, D. E. J. Controlled Release 2004, 96, 37.
15. Pan, D.; Turner, J. L.; Wooley, K. L. Chem. Commun. 2003, 19, 2400.
16. Rosler, A. V.; Guido W. M.; Klok, H.-A. Adv. Drug Delivery Rev. 2001. 53, 95.
17. Clendenning, S. B.; Fournier-Bidoz, S.; Pietrangelo, A.; Yang, G.; Han, S.; Brodersen, P. M.; Yip, C. M.; Lu, Z.-H.; Ozin, G. A.; Manners, I. J. Mater. Chem. 2004, 14, 1686.
18. Hartgerink, J. D.; Beniash, E.; Stupp, S. I. Science 2001, 294, 1684.
19. Li, M.; Cölfen, H.; Mann, S. J. Mater. Chem. 2004, 14, 2269.
20. Li, L.; Beniash, E.; Zubarev, E. R.; Xiang, W.; Rabatic, B. M.; Zhang, G.; Stupp, S. I. Nat. Mater. 2003, 2, 689.
21. Zhang, L.; Eisenberg, A. Science 1995, 268, 1728.
22. Bronich, T. K.; Popov, A. M.; Eisenberg, A.; Kabanov, V. A.; Kabanov, A. V. Langmuir 2000, 16, 481.
23. Dalhaimer, P.; Bermudez, H.; Discher, D. E. J. Polym. Sci., Part B: Polym. Phys. 2004, 42, 168.
24. Terreau, O.; Luo, L.; Eisenberg, A. Langmuir 2003, 19, 5601.
25. Discher, B. M.; Won, Y.-Y.; Ege, D. S.; Lee, J. C.-M.; Bates, F. S.; Discher, D. E.; Hammer, D. A. Science 1999, 284, 1143.
26. Yu, G.-e.; Eisenberg, A. Macromolecules 1998, 31, 5546.
27. Zhou, Z.; Li, Z.; Ren, Y.; Hillmyer, M. A.; Lodge, T. P. J. Am. Chem. Soc. 2003, 125, 10182.
28. Liu, S.; Armes, S. P. J. Am. Chem. Soc. 2001, 123, 9910.
29. Ma, Q.; Remsen, E. E.; Clark, C. G., Jr.; Kowalewski, T.; Wooley, K. L. Proc. Natl. Acad. Sci. U.S.A. 2002, 99, 5058.
30. Li, Z.; Kesselman, E.; Talmon, Y.; Hillmyer, M. A.; Lodge, T. P. Science 2004, 306, 98.
31. Pochan, D. J.; Chen, Z.; Cui, H.; Hales, K.; Qi, K.; Wooley, K. L. Science 2004, 306, 94.
32. Jain, S.; Bates, F. S. Macromolecules 2004, 37, 1511.
33. 2O was then added slowly (ca. 75% of initial volume per hour) until the desired solution composition was obtained.
34. All samples were deposited from the solvent mixtures onto carbon-coated copper grids and were negatively stained by uranyl acetate.