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Volumn 27, Issue 10, 2008, Pages 2215-2222

Dissociative route to C-H bond activation: DFT Study of ligand cyclometalation in a platinum(II) complex

Author keywords

[No Author keywords available]

Indexed keywords

DENSITY FUNCTIONAL THEORY; PLATINUM; PROBABILITY DENSITY FUNCTION;

EID: 44649109059     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om701070f     Document Type: Article
Times cited : (29)

References (115)
  • 1
    • 33947493717 scopus 로고    scopus 로고
    • A representative, but not comprehensive, list of reviews on C-H activation and functionalization includes: (a) Bergman, R. G. Nature 2007, 446, 391-393.
    • A representative, but not comprehensive, list of reviews on C-H activation and functionalization includes: (a) Bergman, R. G. Nature 2007, 446, 391-393.
  • 9
    • 27744542582 scopus 로고    scopus 로고
    • For recent reviews on cyclometalation, see: a
    • For recent reviews on cyclometalation, see: (a) Crabtree, R. H. J. Organomet. Chem. 2005, 690, 5451-5457.
    • (2005) J. Organomet. Chem , vol.690 , pp. 5451-5457
    • Crabtree, R.H.1
  • 12
    • 0142196638 scopus 로고    scopus 로고
    • (d) Werner, H. Dalton Trans. 2003, 20, 3829-3837.
    • (2003) Dalton Trans , vol.20 , pp. 3829-3837
    • Werner, H.1
  • 13
  • 34
    • 0034717432 scopus 로고    scopus 로고
    • Dissociative substitution is rather common for complexes of the type cis-[Pt(C,C)(S,S)] (C = strong a-donor carbon group; S = thioether, sulfoxide), no matter whether the carbon atom comes from an alkyl, an aryl, or a metalated aryl ligand. See: (a) Plutino, M. R.; Monsù Scolaro, L.; Romeo, R.; Grassi, A. Inorg. Chem. 2000, 39, 2712-2720.
    • Dissociative substitution is rather common for complexes of the type cis-[Pt(C,C)(S,S)] (C = strong a-donor carbon group; S = thioether, sulfoxide), no matter whether the carbon atom comes from an alkyl, an aryl, or a metalated aryl ligand. See: (a) Plutino, M. R.; Monsù Scolaro, L.; Romeo, R.; Grassi, A. Inorg. Chem. 2000, 39, 2712-2720.
  • 48
    • 44649195017 scopus 로고    scopus 로고
    • 3J(Pt,H) = 16.0 hz for 1b).
    • 3J(Pt,H) = 16.0 hz for 1b).
  • 50
    • 0002108854 scopus 로고
    • For reviews, see: b
    • For reviews, see: (b) Mislow, K. Acc. Chem. Res. 1976, 9, 26-33.
    • (1976) Acc. Chem. Res , vol.9 , pp. 26-33
    • Mislow, K.1
  • 91
    • 21844451374 scopus 로고    scopus 로고
    • and references therein
    • (b) Lersch, M.; Tilset, M. Chem. Rev. 2005, 105, 2471-2526, and references therein.
    • (2005) Chem. Rev , vol.105 , pp. 2471-2526
    • Lersch, M.1    Tilset, M.2
  • 101
    • 33746636494 scopus 로고    scopus 로고
    • and references therein
    • Romeo, R.; D'Amico, G. Organometallics 2006, 25, 3435-3446, and references therein.
    • (2006) Organometallics , vol.25 , pp. 3435-3446
    • Romeo, R.1    D'Amico, G.2
  • 106
    • 4243553426 scopus 로고
    • Becke, A. D. Phys. Rev. 1988, A38, 3098-3100.
    • (1988) Phys. Rev , vol.A38 , pp. 3098-3100
    • Becke, A.D.1
  • 107
    • 5944261746 scopus 로고
    • Perdew, J. P. Phys. Rev. 1986, B33, 8822-8824.
    • (1986) Phys. Rev , vol.B33 , pp. 8822-8824
    • Perdew, J.P.1
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    • 44649175645 scopus 로고    scopus 로고
    • 6.0; Schrodinger LLC, New York
    • Jaguar 6.0; Schrodinger LLC, New York, 2005.
    • (2005)
    • Jaguar1


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