Methyl(hydrido)platinum(IV) complexes that are resistant to reductive elimination, including the first (μ-hydrido)diplatinum(IV) complex

Journal of the American Chemical Society

Volumn 118, Issue 36, 1996, Pages 8745-8746

  Hill, Geoffrey S ^a   Puddephatt, Richard J ^a  

^a UNIVERSITY OF WESTERN ONTARIO   (Canada)

Author keywords

[No Author keywords available]

Indexed keywords

PLATINUM COMPLEX;

ARTICLE; COMPLEX FORMATION; NUCLEAR MAGNETIC RESONANCE; REACTION ANALYSIS;

EID: 0029797394     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja961404n     Document Type: Article

References (16)

1. (a) De Felice, V.; De Renzi, A.; Panunzi, A.; Tesauro, D. J. Organomet. Chem. 1995. 488, C13.
2. (b) Hill, G. S.; Rendina, L. M.; Puddephatt, R. J. Organometallics 1995, 14, 4966.
3. (c) Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. J. Am. Chem. Soc. 1995, 117, 9371.
4. (d) Stahl, S. S.; Labinger, J. A.; Bercaw, J. E. Personal communication.
5. (e) Canty, A. J. Personal communication.
6. (a) Hux, J. E.; Puddephatt, R. J. Inorg. Chim. Acta. 1985, 100, 1.
7. (b) Hux, J. E.; Puddephatt, R. J. J. Organomet. Chem. 1988, 346, C31.
8. 1
9. 2bpy].
10. 4.
11. 2(μ-H) groups are usually bent. The degree of bending must be small in this case due to steric effects between substituents on platinum.
12. (a) Brown, M. P.; Puddephatt, R. J.; Rashidi, M.; Seddon, K. R. J. Chem. Soc., Dalton Trans. 1978, 516.
13. (b) Brown, M. P.; Cooper, S. J.; Frew, A. A.; Manojlovic-Muir, Lj.; Muir, K. W.; Puddephatt, R. J.; Thompson, M. A. J. Chem. Soc., Dalton Trans. 1982, 299.
14. 1J(PtD) = 6.47.
15. 3 in refluxing acetone and is stable under these conditions.
16. The ligating ability of terminal hydrides in the synthesis of μ-hydrido complexes has been exploited before. Venanzi, L. M. Coord. Chem. Rev. 1982, 43, 251.