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Volumn , Issue 8, 2008, Pages 1189-1192

First asymmetric synthesis of piperidine alkaloid (-)-morusimic acid D

Author keywords

Aldol reaction; Alkaloids; Asymmetric synthesis; Imides; Morusimic acid D; N acyliminium ions; Piperidines

Indexed keywords

3 HYDROXYGLUTARIMIDE; ALKALOID DERIVATIVE; GLUTARIMIDE DERIVATIVE; MORUSIMIC ACID D; PIPERIDINE DERIVATIVE;

EID: 44349092998     PISSN: 09365214     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2008-1072737     Document Type: Article
Times cited : (25)

References (71)
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    • All new compounds gave satisfactory analytical and spectral data. Selected physical and spectral data for morusimic acid D methyl ester (22, pale yellow powder; mp 132-135°C; [α]D 20 -11.3 (c 0.4, CHCl3, IR (film, 3387, 2929, 2854, 1731, 1438, 1380, 1305, 1165, 1061 cm-1. 1H NMR (400 MHz, CD3OD, δ, 1.40 (s, 3 H, 1.22-1.68 (m, 20 H, 2.09 (m, 2 H, 2.30-2.50 (m, 2 H, 2.92 (m, 1 H, 3.08 (m, 1 H, 3.42 (s, 1 H, 3.64 (s, 3 H, 3.95 (m, 1 H, 13C NMR 100 MHz, CD3OD, δ, 16.00, 26.52, 26.56, 28.33, 30.43, 30.48, 30.52, 30.56, 30.59, 32.92, 34.26, 38.05, 43.25, 52.15, 58.49, 59.24, 69.23, 70.70, 173.92. ESI-HRMS: m/z calcd for C19H38NO4 [M, H, 344.2795; found: 344.2798
    • +: 344.2795; found: 344.2798.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.