Development of highly stereoselective asymmetric 6π- azaelectrocyclization of conformationally flexible linear 1-azatrienes. From determination of multifunctional chiral amines, 7-alkyl cis-1-amino-2-indanols, to application as a new synthetic strategy: Formal synthesis of 20-epiuleine

Journal of Organic Chemistry

Volumn 69, Issue 18, 2004, Pages 5906-5925

  Tanaka, Katsunori ^a   Kobayashi, Toyoharu ^a   Mori, Hajime ^a   Katsumura, Shigeo ^a  

^a KWANSEI GAKUIN UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

MANGANESE DIOXIDE; OPTICALLY ACTIVE COMPOUNDS; STEREOSELECTIVE; SYNTHETIC METHODS;

ALCOHOLS; AMINES; AROMATIC COMPOUNDS; CATALYST SELECTIVITY; CONFORMATIONS; MANGANESE COMPOUNDS; OXIDATION; SYNTHESIS (CHEMICAL);

STEREOCHEMISTRY;

1 AMINO 2 INDANOL DERIVATIVE; 1 AZATRIENE; 20 EPIULEINE; ALDEHYDE; AMINE; CARBONYL DERIVATIVE; INDOLE DERIVATIVE; MANGANESE DIOXIDE; NATURAL PRODUCT; PYRIDINE DERIVATIVE; UNCLASSIFIED DRUG;

ARTICLE; ASYMMETRIC SYNTHESIS; CHEMICAL REACTION; CHEMICAL STRUCTURE; CHIRALITY; CRYSTALLIZATION; CYCLIZATION; OXIDATION; PROTON NUCLEAR MAGNETIC RESONANCE; STEREOCHEMISTRY; SYNTHESIS; X RAY CRYSTALLOGRAPHY;

ALDEHYDES; ALKENES; AMINES; AZA COMPOUNDS; CATALYSIS; CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; INDANS; INDOLE ALKALOIDS; MOLECULAR CONFORMATION; MOLECULAR STRUCTURE; OXIDATION-REDUCTION; PYRIDINES; STEREOISOMERISM;

EID: 4344562128     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo049381f     Document Type: Article

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