Highly stereoselective construction of spiro[cyclopropane-1,4′-pyrazolin-5′-one]with 4-arylidene-3-methyl-1-phenyl-pyrazolin-5-one and arsonium ylide

Tetrahedron

Volumn 64, Issue 22, 2008, Pages 5156-5161

  Ren, Zhongjiao ^a   Cao, Weiguo ^a,b   Chen, Jie ^a   Chen, Yali ^a   Deng, Hongmei ^a   Shao, Min ^a   Wu, Danyi ^a  

^a SHANGHAI UNIVERSITY   (China)

^b SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

Author keywords

[No Author keywords available]

Indexed keywords

ARSINE; BENZENE DERIVATIVE; BICARBONATE; CYCLOPROPANE DERIVATIVE; ENDO 2,3 DIHYDRO 1 (4 CHLOROPHENYL) 2 (2 FUROYL) 7 METHYL 5 PHENYL 5,6 DIAZA SPIRO[2,4]HEPT EN 4 ONE; ENDO 2,3 DIHYDRO 1 BENZOYL 2 (4 CHLOROPHENYL) 7 METHYL 5 PHENYL 5,6 DIAZA SPIRO[2,4]HEPT 6 EN 4 ONE; ENDO 2,3 DIHYDRO 1 BENZOYL 2 (4 METHOXYPHENYL)7 METHYL 5 PHENYL 5,6 DIAZA SPIRO[2,4]HEPT 6 EN 4 ONE; ENDO 2,3 DIHYDRO 1 BENZOYL 7 METHYL 2,5 DIPHENYL 5,6 DIAZA SPIRO[2,4]HEPT 6 EN 4 ONE; ENDO 2,3 DIHYDRO 2 (4 CHLOROPHENYL) 4 METHYL 7 OXO 6 PHENYL 5,6 DIAZA SPIRO[2,4]HEPT 4 ENE 1 CARBOXYLIC ACID METHYL ESTER; ENDO 2,3 DIHYDRO 2 (4 METHOXY PHENYL) 4 METHYL 7 OXO 6 PHENYL 5,6 DIAZA SPIRO[2,4]HEPT 4 ENE 1 CARBOXYLIC ACID METHYL ESTER; ENDO 2,3 DIHYDRO 4 METHYL 7 OXO 2,6 DIPHENYL 5,6 DIAZA SPIRO[2,4]HEPT 4 ENE 1 CARBOXYLIC ACID METHYL ESTER; EXO 2,3 DIHYDRO 1 (4 CHLOROPHENYL) 2 (2 FUROYL) 7 METHYL 5 PHENYL 5,6 DIAZA SPIRO[2,4]HEPT 4 ONE; EXO 2,3 DIHYDRO 1 (4 CHLOROPHENYL) 2 (2 THIENOYL) 7 METHYL 5 PHENYL 5,6 DIAZA SPIRO[2,4]HEPT 4 ONE; EXO 2,3 DIHYDRO 1 (4 CHLOROPHENYL) 4 METHYL 7 OXO 6 PHENYL 5,6 DIAZA SPIRO[2,4]HEPT 4 ENE 1 CARBONITRILE; EXO 2,3 DIHYDRO 1 BENZOYL 2 (4 METHOXYPHENYL) 7 METHYL 5 PHENYL 5,6 DIAZA SPIRO[2,4]HEPT 6 EN 4 ONE; EXO 2,3 DIHYDRO 1 BENZOYL 3 (4 CHLOROPHENYL) 7 METHYL 5 PHENYL 5,6 DIAZA SPIRO[2,4]HEPT 6 EN 4 ONE; EXO 2,3 DIHYDRO 1 BENZOYL 7 METHYL 2,5 DIPHENYL 5,6 DIAZA SPIRO[2,4]HEPT 6 EN 4 ONE; EXO 2,3 DIHYDRO 2 (4 CHLOROPHENYL) 4 METHYL 7 OXO 6 PHENYL 5,6 DIAZA SPIRO[2,4]HEPT 4 ENE 1 CARBOXYLIC ACID METHYL ESTER; EXO 2,3 DIHYDRO 2 (4 METHOXY PHENYL) 4 METHYL 7 OXO 6 PHENYL 5,6 DIAZA SPIRO[2,4]HEPT 4 ENE 1 CARBOXYLIC ACID METHYL ESTER; EXO 2,3 DIHYDRO 4 METHYL 7 OXO 2,6 DIPHENYL 5,6 DIAZA SPIRO[2,4]HEPT 4 ENE 1 CARBOXYLIC ACID METHYL ESTER; KETONE DERIVATIVE; PYRAZOLINE DERIVATIVE;

ARTICLE; CATALYSIS; CHEMICAL STRUCTURE; CYCLOPROPANATION; INFRARED SPECTROSCOPY; MASS SPECTROMETRY; NUCLEAR MAGNETIC RESONANCE; PRIORITY JOURNAL; STEREOCHEMISTRY; X RAY DIFFRACTION;

EID: 42749097950     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2008.03.049     Document Type: Article

References (18)

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15. CCDC-648245 (3a) and CCDC-648246 (5c) contain all crystallographic details of this publication and are available free of charge at www.ccdc.cam.ac.uk or can be ordered from the following address: Cambridge Crystallographic Data Centre, 12 Union Road, GB-Cambridge CB21EZ; fax: +44 1223 336 033; or deposit@ccdc.cam.ac.uk.
16. Unit cell parameters (3a): a: 8.2396(2) Å; b: 10.9572(2) Å; c: 13.0351(3) Å; α: 73.5850(10); β: 81.840(2); γ: 68.5160(10); space group: P-1.
17. Unit cell parameters (5c): a: 22.721(3) Å; b: 10.4745(12) Å; c: 21.675(4) Å; α: 90; β: 120.629(2); γ: 90; space group: C2/c.
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