Bismuth triflate-catalyzed rearrangement of acetates of the Baylis-Hillman adducts into (E)-trisubstituted alkenes

Tetrahedron

Volumn 64, Issue 22, 2008, Pages 5150-5155

  Ollevier, Thierry ^a   Mwene Mbeja, Topwe M ^a  

^a UNIVERSITÉ LAVAL   (Canada)

Author keywords

Bismuth; Claisen; Green chemistry; Lewis acids; Morita Baylis Hillman; Rearrangement

Indexed keywords

2 CYANO 3 (2 TOLYL)ALLYL ACETATE; 2 CYANO 3 (4 CHLOROPHENYL)ALLYL ACETATE; 2 CYANO 3 (4 ETHYLPHENYL)ALLYL ACETATE; 2 CYANO 3 (4 ISOPROPYLPHENYL)ALLYL ACETATE; 2 CYANO 3 PHENYLALLYL ACETATE; 2 CYANO 3 TOLYLALLYL ACETATE; ACETIC ACID DERIVATIVE; ACRYLIC ACID METHYL ESTER; ACRYLONITRILE; ALKENE DERIVATIVE; BISMUTH; METHYL 2 (ACETOXYMETHYL) 3 (2 FLUOROPHENYL)ACRYLATE; METHYL 2 (ACETOXYMETHYL) 3 (4 BROMOPHENYL)ACRYLATE; METHYL 2 (ACETOXYMETHYL) 3 (4 CHLOROPHENYL)ACRYLATE; METHYL 2 (ACETOXYMETHYL) 3 (4 ETHYLPHENYL)ACRYLATE; METHYL 2 (ACETOXYMETHYL) 3 (4 FLUOROPHENYL)ACRYLATE; METHYL 2 (ACETOXYMETHYL) 3 (4 ISOPROPYLPHENYL)ACRYLATE; METHYL 2 (ACETOXYMETHYL) 3 2 TOLYLACRYLATE; METHYL 2 (ACETOXYMETHYL) 3 4 TOLYLACRYLATE; METHYL 2 (ACETOXYMETHYL) 3 [4 (TRIFLUOROMETHYL)PHENYL] ACRYLATE; METHYL 2 (ACETOXYMETHYL) 3 PHENYLACRYLATE; NITRILE; TRIFLUOROMETHANESULFONIC ACID;

ARTICLE; BAYLIS HILLMAN REACTION; CATALYSIS; CHEMICAL STRUCTURE; PRIORITY JOURNAL; REACTION ANALYSIS; SUBSTITUTION REACTION;

EID: 42749091315     PISSN: 00404020     EISSN: None     Source Type: Journal    
DOI: 10.1016/j.tet.2008.03.053     Document Type: Article

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