Thermal C2-C6 cyclization of enyne-carbodiimides: Experimental evidence contradicts a diradical and suggests a carbene intermediate

Journal of Organic Chemistry

Volumn 73, Issue 8, 2008, Pages 3005-3016

  Schmittel, Michael ^a   Steffen, Jens Peter ^a   Rodríguez, David ^a   Engelen, Bernward ^a   Neumann, Elmar ^a   Cinar, Mehmet Emin ^a  

^a UNIVERSITY OF SIEGEN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

CORRELATION THEORY; CYCLIZATION; DENSITY FUNCTIONAL THEORY; REACTION KINETICS; SUBSTITUTION REACTIONS;

COARCTATE CYCLIZATION; ENYNE-CARBODIIMIDES; INTERMOLECULAR TRAPPING; NONLINEAR HAMMETT CORRELATIONS;

NITROGEN COMPOUNDS;

AMPHOLYTE; CARBENE; CARBON; CYANAMIDE; HETEROCYCLIC COMPOUND; HYDROGEN; RADICAL; ALKADIENE; ALLENE; DRUG DERIVATIVE; FREE RADICAL; METHANE;

ARTICLE; CORRELATION ANALYSIS; CYCLIZATION; DENSITY FUNCTIONAL THEORY; ELECTRON TRANSPORT; KINETICS; NONLINEAR SYSTEM; THERMAL ANALYSIS; AMINATION; CHEMICAL STRUCTURE; CHEMISTRY; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; TEMPERATURE; X RAY CRYSTALLOGRAPHY;

ALKADIENES; AMINATION; CARBODIIMIDES; CARBON; CRYSTALLOGRAPHY, X-RAY; CYCLIZATION; FREE RADICALS; MAGNETIC RESONANCE SPECTROSCOPY; METHANE; MOLECULAR STRUCTURE; TEMPERATURE;

EID: 42149177341     PISSN: 00223263     EISSN: None     Source Type: Journal    
DOI: 10.1021/jo701966h     Document Type: Article

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