Determination of the origin of stereoselectivity in multiple-transition- state reactions using DFT calculations: Enantioselective synthesis of homoallylic alcohols from aliphatic methyl ketones via an auxiliary-mediated allylation

Journal of the American Chemical Society

Volumn 130, Issue 13, 2008, Pages 4386-4395

  Tietze, Lutz F ^a   Kinzel, Tom ^a   Schmatz, Stefan ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

[No Author keywords available]

Indexed keywords

DENSITY FUNCTIONAL THEORY; ENANTIOSELECTIVITY; KETONES; STEREOSELECTIVITY; SYNTHESIS (CHEMICAL);

ALIPHATIC METHYL KETONES; AUXILIARY-MEDIATED ALLYLATION; TRANSITION STATE REACTIONS;

ALCOHOLS;

ACETONE; ALCOHOL DERIVATIVE; ALIPHATIC KETONE; ALLYL COMPOUND; KETONE DERIVATIVE; TRIMETHYLSILYL DERIVATIVE;

ACCURACY; ALLYLATION; ARTICLE; CALCULATION; CONFORMATIONAL TRANSITION; DENSITY FUNCTIONAL THEORY; ENANTIOSELECTIVITY; ENERGY TRANSFER; GAS; REACTION ANALYSIS; SCREENING; STEREOCHEMISTRY; SYNTHESIS; THEORY;

ALKYLATION; COMPUTER SIMULATION; KETONES; MODELS, CHEMICAL; MOLECULAR STRUCTURE; PROPANOLS; QUANTUM THEORY; REPRODUCIBILITY OF RESULTS; STEREOISOMERISM;

EID: 41549112024     PISSN: 00027863     EISSN: None     Source Type: Journal    
DOI: 10.1021/ja078032a     Document Type: Article

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