Facial-selective allylation of methyl ketones for the asymmetric synthesis of tertiary homoallylic ethers

Synthesis

Volumn , Issue 13, 2004, Pages 2236-2239

  Tietze, Lutz F ^a   Hölsken, Sören ^a   Adrio, Jens ^a   Kinzel, Tom ^a   Wegner, Christoph ^a  

^a UNIVERSITY OF GÖTTINGEN   (Germany)

Author keywords

Allylations; Allylsilannes; Amino alcohols; Asymmetric synthesis; Birch reduction; Homoallylic alcohols

Indexed keywords

ALCOHOLS; ETHERS; ORGANIC ACIDS; STEREOCHEMISTRY;

BIRCH REDUCTION; HOMOALLYLIC ETHERS; METHYL KETONES;

KETONES;

1 (TERT BUTYLDIPHENYLSILYLOXY) 3 METHYLHEX 5 EN 3 OL; 1 TERT BUTYLDIPHENYLSILOXY 3 METHYL 3 (1' PHENYL 2' TRIFLUOROACETAMIDO 1' ETHOXY)HEX 5 ENE; 2,2,2 TRIFLUORO N (2 PHENYL 2 TRIMETHYLSILYLOXYETHYL)ACETAMIDE; ACETONE; ALLYL COMPOUND; ALLYLSILANE; ETHER DERIVATIVE; MANDELIC ACID; SILANE DERIVATIVE; TRIFLUOROMETHANESULFONIC ACID; UNCLASSIFIED DRUG;

ALLYLATION; ARTICLE; ASYMMETRIC SYNTHESIS; BIRCH REDUCTION; CATALYSIS; CHEMICAL STRUCTURE; REACTION ANALYSIS; STEREOCHEMISTRY;

EID: 4544310535     PISSN: 00397881     EISSN: None     Source Type: Journal    
DOI: 10.1055/s-2004-829153     Document Type: Article

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