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The resonance at δ 0.46 exhibits only about 5% of the intensity of the Zr-Me resonance of [Cp2ZrMe(C6D 5Cl, B(C6F5)4, δ 0.63) at -40 °C and is not observed at room temperature. Thus, it was not detected in the previous study6a and was only noted here because of the cross-peak in the 2D NOESY experiment
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6a and was only noted here because of the cross-peak in the 2D NOESY experiment.
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26
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0038614770
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Although often used as a catalyst, Cp2-ZrMe][B(C 6F5)4] has not to this point been well characterized. For 1H NMR data in C6D6, see Talsi, E. P, Eilerstein, J. L, Ystenes, M, Rytter, E. J. Organomet. Chem. 2003, 677, 10
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6, see Talsi, E. P.; Eilerstein, J. L.; Ystenes, M.; Rytter, E. J. Organomet. Chem. 2003, 677, 10.
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28
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0033740668
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and refs therein. For a review of metallocene cations as initiators of isobutene polymerization, see: a
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For a review of metallocene cations as initiators of isobutene polymerization, see: (a) Baird, M. C. Chem. Rev. 2000, 100, 1471 and refs therein.
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See also: (b) Carr, A. G.; Dawson, D. M.; Bochmann, M. Macromolecules 1998, 31, 2035.
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(d) Song, X.; Thornton-Pett, M.; Bochmann, M. Organometallics 1998, 17, 1004.
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41449111545
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5Cl possible, see: Dumas, J. P. C. R. Acad. Sci., Ser. C 1977, 284, 257.
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5Cl possible, see: Dumas, J. P. C. R. Acad. Sci., Ser. C 1977, 284, 257.
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34
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0035956457
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5Br used well below its mp, see Goodman, J. T.; Schrock, R. R. Organometallics 2001, 20, 5205.
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5Br used well below its mp, see Goodman, J. T.; Schrock, R. R. Organometallics 2001, 20, 5205.
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35
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41449101495
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Sandström, J. Dynamic NMR Spectroscopy; Academic Press: London, 1982; pp 79, 96. The coalescence temperature was ∼-50°C and the peak separation at -60°C was ∼15 Hz. However, the resonances were still broad, and Δν would probably be larger at the limiting spectrum.
-
(a) Sandström, J. Dynamic NMR Spectroscopy; Academic Press: London, 1982; pp 79, 96. The coalescence temperature was ∼-50°C and the peak separation at -60°C was ∼15 Hz. However, the resonances were still broad, and Δν would probably be larger at the limiting spectrum.
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37
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24944478794
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Wilkinson, G. W, Stone, F. G. A, Abel, K. W, Eds, Pergamon: Oxford, Chapter 23.2
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Cardin, D. J.; Lappert, M. F.; Raston, C. L.; Riley, P. I. In Comprehensive Organometallic Chemistry; Wilkinson, G. W., Stone, F. G. A., Abel, K. W., Eds.; Pergamon: Oxford, 1982; Vol. 3, Chapter 23.2.
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2 is also on occasion a byproduct of allyl formation. See (a) Wasserman, E.; Hsi, E.; Young, W.-T. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1998, 39, 425.
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2 is also on occasion a byproduct of allyl formation. See (a) Wasserman, E.; Hsi, E.; Young, W.-T. Polym. Prepr. (Am. Chem. Soc., Div. Polym. Chem.) 1998, 39, 425.
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