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Volumn 47, Issue 3, 2008, Pages 515-519

Encapsulation of fullerenes in a helical PMMA cavity leading to a robust processable complex with a macromolecular helicity memory

Author keywords

Chiral memory; Fullerenes; Helical structures; Nanotubes; Supramolecular chemistry

Indexed keywords

ALCOHOLS; ENCAPSULATION; FULLERENES; MACROMOLECULES; ROBUST CONTROL;

EID: 40949153409     PISSN: 14337851     EISSN: None     Source Type: Journal    
DOI: 10.1002/anie.200703655     Document Type: Article
Times cited : (144)

References (46)
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    • n = 21800 and mm/mr/rr = 97:3:0, in which m and r represent the it and st dyads of the meso and racemo sequences, respectively, and mm, mr, and rr are the corresponding triad sequences.
    • n = 21800 and mm/mr/rr = 97:3:0, in which m and r represent the it and st dyads of the meso and racemo sequences, respectively, and mm, mr, and rr are the corresponding triad sequences.
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    • In the TEM observations, low doses and short exposure times were carefully applied to minimize any electron beam damage, but the st-PMMA chains were damaged, resulting in release of the encapsulated C60 molecules from the st-PMMA nanotubes, and a uniform and long 1D array of C60 molecules, as expected from the AFM image Figure 3a, could not be observed; see Figure S7 in the Supporting Information for more details of the TEM observations
    • 60 molecules, as expected from the AFM image (Figure 3a), could not be observed; see Figure S7 in the Supporting Information for more details of the TEM observations.
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    • A macromolecular conformational change driven by chiral solvation was reported: M. M. Green, C. Khatri, N. C. Peterson, J. Am. Chem. Soc. 1993, 115, 4941-4942.
    • A macromolecular conformational change driven by chiral solvation was reported: M. M. Green, C. Khatri, N. C. Peterson, J. Am. Chem. Soc. 1993, 115, 4941-4942.
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    • 60 solution formed a gel in 10 and 20vol% 1 after 10 min and 15 h, respectively (Table S3 in the Supporting Information).
    • 60 solution formed a gel in 10 and 20vol% 1 after 10 min and 15 h, respectively (Table S3 in the Supporting Information).
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.