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In the present research, the furanose vs. pyranose structural problem is not specified in detail. The appearance of a clear exciton coupling band in bpydb supports the view that the two boronic acid groups are intramolecularly bridged by the monosaccharide. Judging from the distance between the two boronic acid groups (ca. 7.4 Å), the distance between the 1,2-diol and the 4,6-diol which are useful as building sites in D-glucopyranoside is too short whereas that between the 1,2-diol and the 5,6-diol which are useful as building sites in D-glucofuranoside is long enough to interact with the two boronic acids. We now believe that the furanose form is used for the intramolecular bridging of the two boronic acids.
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