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Volumn 27, Issue 4, 2008, Pages 626-636

A combined experimental-theoretical study on the lithiation/electrophilic quench sequence of (η5-cyclohexadienyl)Mn(CO)3 complexes

Author keywords

[No Author keywords available]

Indexed keywords

BOND LENGTH; CONFORMATIONS; DEPROTONATION; MANGANESE COMPOUNDS; METAL COMPLEXES; REGIOSELECTIVITY; SUBSTRATES;

EID: 40549126289     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om7010529     Document Type: Article
Times cited : (24)

References (68)
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    • Multiple metalated species can indeed be generated if more than one equivalent of base is employed in the lithiation of (η6-arene) Cr(CO)3 complexes: Gibson, S. E, Steed, J. W, Sur, S. J. Chem. Soc, Perkin Trans.1 2001, 636, and references therein
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    • The directed ortho-metalation is a well-known methodology in organic synthesis; see for example: (a) Hartung, C. G.; Snieckus, V. In Modern Arene Chemistry; Astruc, D., Ed.; Wiley-VCH: New York, 2002; Chapter 11, pp 330.
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    • The metal-metal exchange was nevertheless attempted on the mixture of the two stannylated regioisomers C2:C3, 55:45, giving a new ratio C2:C3, 82:18
    • 3 = 82:18.
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    • -1, 8783 independent reflections, R = 0.0303, wR = 0.0307. The structure was solved by direct methods using SHELXS86 and refined with full-matrix least-squares technique on F using the CRYSTALS programs. CCDC-650517 and the supporting information contain the supplementary crystallographic data for this paper.
    • -1, 8783 independent reflections, R = 0.0303, wR = 0.0307. The structure was solved by direct methods using SHELXS86 and refined with full-matrix least-squares technique on F using the CRYSTALS programs. CCDC-650517 and the supporting information contain the supplementary crystallographic data for this paper.
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    • The complexation of iodobenzene, according to the chlorobenzene complexation procedure, was unsuccessful in our hands: Chavarot, M.; Rose-Munch, F.; Rose, E., unpublished results.
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