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(a) Very recently, a Korean group reported a similar idea: G. Cho, J. Jang, S. Jung,, I.-S. Moon, J.-S. Lee, Y.-S. Cho, B. M. Fung, W.-L. Yuan and E. A. O'Rear, Langmuir, 2002, 18, 3430. However, our system has presented several new findings which were not attained by them: that is, (1) sol-gel polycondensation proceeds, without catalyst, utilizing the polymeric pyridine nitrogens as catalytic sites, (2) the mild conditions in (1) result in the finer silica network structure, (3) acidic, basic, and neutral conditions are all examined and (4) the thin silica film with a network structure is directly observed by TEM: N. Fujita, H. Otsuka, A. Takahara and S. Shinkai, Chem. Lett., 2003, 32, 352.
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82
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(a) Very recently, a Korean group reported a similar idea: G. Cho, J. Jang, S. Jung,, I.-S. Moon, J.-S. Lee, Y.-S. Cho, B. M. Fung, W.-L. Yuan and E. A. O'Rear, Langmuir, 2002, 18, 3430. However, our system has presented several new findings which were not attained by them: that is, (1) sol-gel polycondensation proceeds, without catalyst, utilizing the polymeric pyridine nitrogens as catalytic sites, (2) the mild conditions in (1) result in the finer silica network structure, (3) acidic, basic, and neutral conditions are all examined and (4) the thin silica film with a network structure is directly observed by TEM: N. Fujita, H. Otsuka, A. Takahara and S. Shinkai, Chem. Lett., 2003, 32, 352.
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83
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note
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The resultant silica material on the polymer film also gave the same porous silica layer as that shown in Fig. 2d after the calcination treatment. The same calcination process was adopted as that for the sample prepared by Method B.
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