Thin silica film with a network structure as prepared by surface sol-gel transcription on the poly(styrene-b-4-vinylpyridine) polymer film

Chemistry Letters

Volumn 32, Issue 4, 2003, Pages 352-353

  Fujita, Norifumi ^a   Otsuka, Hideyuki ^a   Takahara, Atsushi ^a   Shinkai, Seiji ^a  

^a KYUSHU UNIVERSITY   (Japan)

Author keywords

[No Author keywords available]

Indexed keywords

POLY(STRENE 4 VINYLPYRIDINE); POLYMER; SILICON DIOXIDE; UNCLASSIFIED DRUG;

ARTICLE; CATALYST; CHEMICAL STRUCTURE; FILM; GEL; POLYMERIZATION; SURFACE PROPERTY; TRANSMISSION ELECTRON MICROSCOPY;

EID: 0037824565     PISSN: 03667022     EISSN: None     Source Type: Journal    
DOI: 10.1246/cl.2003.352     Document Type: Article

References (27)

1. For recent reviews see: a) J. H. van Esch and B. L. Feringa, Angew. Chem., 39, 2263 (2000). b) D. J. Abdallah and R. G. Weiss, Adv. Mater., 12, 1237 (2000). c) G. F. Swiegers and T. J. Malefetse, Chem. Rev., 100, 3483 (2000). d) D. T. Bong, T. D. Clark, J. R. Granja, and M. R. Ghadiri, Angew. Chem., Int. Ed., 40, 988 (2001). e) L. J. Prins, D. N. Reinhoudt, and P. Timmerman, Angew. Chem., Int. Ed., 40, 2382 (2001). f) B. J. Hollida and C. A. Mirkin, Angew. Chem., Int. Ed., 40, 2022 (2001).
2. For recent reviews see: a) J. H. van Esch and B. L. Feringa, Angew. Chem., 39, 2263 (2000). b) D. J. Abdallah and R. G. Weiss, Adv. Mater., 12, 1237 (2000). c) G. F. Swiegers and T. J. Malefetse, Chem. Rev., 100, 3483 (2000). d) D. T. Bong, T. D. Clark, J. R. Granja, and M. R. Ghadiri, Angew. Chem., Int. Ed., 40, 988 (2001). e) L. J. Prins, D. N. Reinhoudt, and P. Timmerman, Angew. Chem., Int. Ed., 40, 2382 (2001). f) B. J. Hollida and C. A. Mirkin, Angew. Chem., Int. Ed., 40, 2022 (2001).
3. For recent reviews see: a) J. H. van Esch and B. L. Feringa, Angew. Chem., 39, 2263 (2000). b) D. J. Abdallah and R. G. Weiss, Adv. Mater., 12, 1237 (2000). c) G. F. Swiegers and T. J. Malefetse, Chem. Rev., 100, 3483 (2000). d) D. T. Bong, T. D. Clark, J. R. Granja, and M. R. Ghadiri, Angew. Chem., Int. Ed., 40, 988 (2001). e) L. J. Prins, D. N. Reinhoudt, and P. Timmerman, Angew. Chem., Int. Ed., 40, 2382 (2001). f) B. J. Hollida and C. A. Mirkin, Angew. Chem., Int. Ed., 40, 2022 (2001).
4. For recent reviews see: a) J. H. van Esch and B. L. Feringa, Angew. Chem., 39, 2263 (2000). b) D. J. Abdallah and R. G. Weiss, Adv. Mater., 12, 1237 (2000). c) G. F. Swiegers and T. J. Malefetse, Chem. Rev., 100, 3483 (2000). d) D. T. Bong, T. D. Clark, J. R. Granja, and M. R. Ghadiri, Angew. Chem., Int. Ed., 40, 988 (2001). e) L. J. Prins, D. N. Reinhoudt, and P. Timmerman, Angew. Chem., Int. Ed., 40, 2382 (2001). f) B. J. Hollida and C. A. Mirkin, Angew. Chem., Int. Ed., 40, 2022 (2001).
5. For recent reviews see: a) J. H. van Esch and B. L. Feringa, Angew. Chem., 39, 2263 (2000). b) D. J. Abdallah and R. G. Weiss, Adv. Mater., 12, 1237 (2000). c) G. F. Swiegers and T. J. Malefetse, Chem. Rev., 100, 3483 (2000). d) D. T. Bong, T. D. Clark, J. R. Granja, and M. R. Ghadiri, Angew. Chem., Int. Ed., 40, 988 (2001). e) L. J. Prins, D. N. Reinhoudt, and P. Timmerman, Angew. Chem., Int. Ed., 40, 2382 (2001). f) B. J. Hollida and C. A. Mirkin, Angew. Chem., Int. Ed., 40, 2022 (2001).
6. For recent reviews see: a) J. H. van Esch and B. L. Feringa, Angew. Chem., 39, 2263 (2000). b) D. J. Abdallah and R. G. Weiss, Adv. Mater., 12, 1237 (2000). c) G. F. Swiegers and T. J. Malefetse, Chem. Rev., 100, 3483 (2000). d) D. T. Bong, T. D. Clark, J. R. Granja, and M. R. Ghadiri, Angew. Chem., Int. Ed., 40, 988 (2001). e) L. J. Prins, D. N. Reinhoudt, and P. Timmerman, Angew. Chem., Int. Ed., 40, 2382 (2001). f) B. J. Hollida and C. A. Mirkin, Angew. Chem., Int. Ed., 40, 2022 (2001).
7. For recent reviews see: a) S. Weiner and L. Addadi, J. Mater. Chem., 7, 689 (1997). b) S. Mann, Angew. Chem., Int. Ed., 39, 3392 (2000). c) L. A. Estroff and A. D. Hamilton, Chem. Mater., 13, 3227 (2001).
8. For recent reviews see: a) S. Weiner and L. Addadi, J. Mater. Chem., 7, 689 (1997). b) S. Mann, Angew. Chem., Int. Ed., 39, 3392 (2000). c) L. A. Estroff and A. D. Hamilton, Chem. Mater., 13, 3227 (2001).
9. For recent reviews see: a) S. Weiner and L. Addadi, J. Mater. Chem., 7, 689 (1997). b) S. Mann, Angew. Chem., Int. Ed., 39, 3392 (2000). c) L. A. Estroff and A. D. Hamilton, Chem. Mater., 13, 3227 (2001).
10. For a recent review see: R. A. Caruso and M. Antonietti, Chem. Mater., 13, 3272 (2001).
11. D. H. W. Hubert, M. Jung, P. M. Frederik, P. H. H. Bomans, J. Meuldijk, and A. L. German, Adv. Mater., 12, 1286 (2000).
12. M. Adachi, T. Harada, and M. Harada, Langmuir, 15, 7097 (1999).
13. H. Imai, N. Takahashi, R. Tamura, and H. Hirashima, Langmuir, 17, 17 (2001).
14. X. D. Wang, W. L. Yang, Y. Tang, Y. J. Wang, S. K. Fu, and Z. Gao, Chem. Commun., 2000, 2161.
15. R. A. Caruso, A. Susha, and F. Caruso, Chem. Mater., 13, 400 (2001).
16. J. H. Jung, Y. Ono, and S. Shinkai, Angew. Chem., Int. Ed., 39, 1862 (2000).
17. J. H. Jung, Y. Ono, K. Hanabusa, and S. Shinkai, J. Am. Chem. Soc., 122, 5008 (2000).
18. J. H. Jung, Y. Ono, K. Sakurai, M. Sano, and S. Shinkai, J. Am. Chem. Soc., 122, 8648 (2000).
19. J. H. Jung, Y. Ono, and S. Shinkai, Chem. - Eur. J., 6, 4552 (2000).
20. K. Sugiyasu, S.-i. Tamaru, M. Takeuchi, D. Berthier, I. Huc, R. Oda, and S. Shinkai, Chem. Commun., 2002, 1212.
21. Y. Ono, Y. Kanekiyo, K. Inoue, J. Hojo, M. Nango, and S. Shinkai, Chem. Lett., 1999, 475.
22. K. J. C. Van Bommel, J. H. Jung, and S. Shinkai, Adv. Mater., 13, 1472 (2001).
23. H. Nakamura and Y. Matsui, J. Am. Chem. Soc., 117, 2651 (1995).
24. K. J. C. van Bommel and S. Shinkai, Langmuir, 18, 4544 (2002).
25. A. Friggeri, O. Gronwald, K. J. C. van Bommel, and S. Shinkai, Chem. Comuun., 2001, 2432.
26. Very recently, a Korean group reported the similar idea: G. Cho, J. Jang, S. Jung, I.-S. Moon, J.-S. Lee, Y.-S. Cho, B. M. Fung, W.-L. Yuan, and E. A. O'Rear, Langmuir, 18, 3430 (2002). However, our system has presented several new findings which were not attained by them: that is, (1) sol-gel polycondensation proceeds, without catalyst, utilizing the polymeric pyridine nitrogens as catalytic sites, (2) the mild condition in (1) results in the finer silica network structure, (3) the acidic, basic, and neutral conditions are all examined, and (4) the thin silica film with a network structure is directly observed by TEM.
27. The resultant silica material on the polymer film also gave the same porous silica layer as that of shown in Figure 2d after the calcination treatment. The same calcination process was adopted as that for the sample prepared by Method B.