Chemical substitutions in oxidized tourmaline in granite-related mineralized hydrothermal systems, western Turkey

Canadian Mineralogist

Volumn 45, Issue 6, 2007, Pages 1397-1413

  Oyman, Tolga ^a   Dyar, M Darby ^b  

^a DOKUZ EYLUL UNIVERSITY   (Turkey)

^b MOUNT HOLYOKE COLLEGE   (United States)

Author keywords

Electron microprobe data; K lada Au deposit; Kad kalesi Pb Zn Cu deposit; M ssbauer spectroscopy; Tourmaline; Tourmaline stability; Turkey

Indexed keywords

GRANITE; MINERALOGY; MOSSBAUER SPECTROSCOPY; SUBSTITUTION REACTIONS; VOLCANIC ROCKS;

CHEMICAL SUBSTITUTIONS; HYDROTHERMAL SYSTEMS; TOURMALINE;

SILICATE MINERALS;

CHEMICAL COMPOSITION; ELECTRON PROBE ANALYSIS; EMPLACEMENT; HYDROTHERMAL ALTERATION; HYDROTHERMAL SYSTEM; MINERALIZATION; MOSSBAUER SPECTROSCOPY; ORE DEPOSIT; ORE-FORMING FLUID; OXIDATION; SUBSTITUTION; TOURMALINE; VOLCANIC ROCK;

ANATOLIA; EURASIA; TURKEY;

EID: 39649099972     PISSN: 00084476     EISSN: None     Source Type: Journal    
DOI: 10.3749/canmin.45.6.1397     Document Type: Article

References (51)

1. BAKER, E.M., KIRWIN, D.J. & TAYLOR, R.G. (1986): Hydrothermal Breccia Pipes. Econ. Geol. Research Unit, James Cook Univ. of North Queensland, Contrib. 12.
2. BELOV, V.F., KHIMICH, T.A., SHPKO, M.N., VOSKRESENSKAYA, I.E. & OKULOV, E.N. (1973): Resonant gamma-resonance investigations of ferruginous tourmalines. Kristallografiya 18, 192-194 (in Russ.).
3. BÉZIAT, D., BOURGES, F., DEBAT, P., FUCHS, Y., LOMPO, M., MARTIN, F., NIKIÉMA, S. & TOLLON, F. (1999): The Guibaré and Fété Kolé gold-bearing tourmaline-quartz veins in the Birrimian greenstone belts of Burkina Faso. Can. Mineral. 37. 575-591.
4. BURNS, R.G. (1972): Mixed valencies and site occupancies of iron in silicate minerals from Mössbauer spectroscopy. Can. J. Spectros. 17, 51-59.
5. CARTEN, R.B. (1986): Sodium-calcium metasomatism: chemical, temporal, and spatial relationships at the Yerrington, Nevada, porphyry copper deposit. Econ. Geol. 81, 1495-1519.
6. CLARK, A.H. (1993): Are outsize porphyry-copper deposits either anatomically or environmentally distinctive? In Giant Ore Deposits (B.H.Whiting, C.J Hodgson & R. Mason, eds.). Soc. Econ. Geol., Spec. Publ. 2, 213-283.
7. DOGLIONI, C., AGOSTINI, S., CRESPI, M., INNOCENTI, F., MANETTI, P., RIGUZZI, F. & SAVAŞÇIN, Y. (2002): On the extension in western Anatolia and the Aegean Sea. J. Virtual Explorer 8, 161-176.
8. DYAR, M.D. (1984): Precision and interlaboratory reproducibility of measurements of the Mössbauer effect in minerals. Am. Mineral. 69, 1127-1144.
9. DYAR, M.D., TAYLOR, M.E., LUTZ, T.M., FRANCIS, C.A., GUIDOTTI, C.V. & WISE, M. (1998): Inclusive chemical characterization of tourmaline: Mössbauer study of Fe valence and site occupancy. Am. Mineral. 83, 848-864.
10. ELDORADO GOLD (2003): Kişladaǧ project feasibility study. Unpubl. Tech. Rep.
11. ERCAN, T., SATIR, M., SEVIN, D. & TÜRKECAN, A. (1997): Some new radiometric ages from Tertiary to Quaternary volcanic rocks from western Anatolia. General Directorate Mineral. Res. Expl. (MTA) Bull. 119, 103-112.
12. 3+ from Eibenstein, Austria: structural, chemical, and Mössbauer data. Can. Mineral. 42, 1057-1063.
13. FERROW, E.A. (1994): Mössbauer effect study of the crystal chemistry of tourmaline. Hyperfine Interact. 91, 689-695.
14. FERROW, E.A., ANNERSTEN, H. & GUNAWARDANE, R.P. (1988): Mössbauer effect study on the mixed valence state of iron in tourmaline. Mineral. Mag. 52, 221-228.
15. 2 conditions. Am. Mineral. 83, 525-534.
16. FUCHS, Y. & MAURY, R. (1995): Borosilicate alteration associated with U-Mo-Zn and Ag-Au-Zn deposits in volcanic rocks. Mineral. Deposita 30, 449-459.
17. GORELIKOVA, N.V., PERFIL'YEV, Y.D. & BUBESHKIN, A.M. (1976): Mössbauer data on distribution of Fe ions in tourmaline. Int. Geol. Rev. 20, 982-990.
18. GUSTAFSON, L.B. & QUIROGA, J.G. (1995): Patterns of mineralization and alteration below the porphyry copper orebody at El Salvador, Chile. Econ. Geol. 90, 2-16.
19. HAWTHORNE, F.C. & HENRY, D.J. (1999): Classification of the minerals of the tourmaline group. Eur. J. Mineral. 11, 201-215.
20. 2S-bearing aqueous solutions at 250-350°C. Geochim. Cosmochim. Acta 55, 2111-2126.
21. HENRY, D.J. & GUIDOTTI, C.V. (1985): Tourmaline as a petrogenetic indicator mineral: an example from the staurolite-grade metapelites of NW Maine. Am. Mineral. 70, 1-15.
22. INNOCENTI, F., AGOSTINI, S., DI VINCENZO, G., DOGLIONI, C., MANETTI, R, SAVAŞÇIN, M.Y. & TONARINI, S. (2005): Neogene and Quaternary volcanism in western Anatolia: magma sources and geodynamic evolution. Mar. Geol. 221, 397-421.
23. KOVAL, P.V., ZORINA, L.D., KITAJEV, N.A., SPIRIDONOV, A.M. & ARIUNBILEG, S. (1991): The use of tourmaline in geochemical prospecting for gold and copper mineralization. J. Geochem. Explor. 40, 349-360.
24. LEEMAN, W.P. & SISSON, V.B. (1996) Geochernistry of boron and its implications for crustal and mantle processes. In Boron: Mineralogy, Petrology, and Geochemistry (E.S. Grew & L.M. Anovitz, eds.). Rev. Mineral. 33, 645-707.
25. LONDON, D. & MANNING, D.A.C. (1995): Chemical variation and significance of tourmaline from southwest England. Econ. Geol. 90,495-519.
26. LUDDEN, J.N., DAIGNEAULT, R., ROBERT, F. & TAYLOR, R.P. (1984): Trace element mobility in alteration zones associated with Archean Au lode deposits. Econ. Geol. 79, 1131-1141.
27. LYNCH, G. & ORTEGA, J. (1997): Hydrothermal alteration and tourmaline-albite equilibria at the Coxheath porphyry Cu-Mo-Au deposit, Nova Scotia. Can. Mineral. 35, 79-94.
28. MANNING, D.A.C. (1982): Chemical and morphological variation in tourmalines from the Hub Kapong batholith of pen-insular Thailand. Mineral. Mag. 45, 139-147.
29. MATTSON, S.M. & ROSSMAN, G.R. (1984): Ferric iron in tourmaline. Phys. Chem. Minerals 11, 225-234.
30. MORGAN, G.B., VI & LONDON, D. (1989): Experimental reactions of amphibolite with boron-bearing aqueous fluids at 200 MPa: implications for tourmaline stability and partial melting in mafic rocks. Contrib. Mineral. Petrol. 102, 281-297.
31. MÜLLER, D. & GROVES, D.I. (1997): Potassic Igneous Rocks and Associated Gold-Copper Mineralization. Springer, Berlin. Germany.
32. OYMAN, T. (2000): Experimental Investigation of Stability of Calcic Boro-silicates; Application to Hydrothermal Mineralisation Systems in Aegean Region (Turkey). Ph.D. thesis, Graduate School of Natural and Applied Science, Dokuz Eylül University, Izmir. Turkey (in Turkish).
33. PICHAVANT, M. (1981): An experimental study of the effect of boron on a water saturated haplogranite at 1 kbar vapour pressure. Contrib. Mineral. Petrol. 76, 430-439.
34. 2+ octahedral ions. In Tourmaline 1997; Int. Symp. on Tourmaline (Nové Mestona Morave), 74-75.
35. PIŞKIN, O. (1980): Kadikalesi-Girelbelen (Bodrum Yarιmadasι) Hidrotermal-Kontak Metazomatik Pb-Zn-Cu Cevherleşmelerinin Mineralojik Jenetik Incelemesi. Dissertation for Associate Refereeship, Faculty of Earth Science, University of Ege, İzmir, Turkey.
36. PIŞKIN, Ö. & BERTRAND, J. (1980): Les minéralisations de plumb, zinc et cuivre de Kadιkalesi (presqu'ûle de Bodrum-Turquie). Schweiz. Mineral. Petrogr. Mitt. 60, 45-68.
37. PiŞKIN, Ö., DELALOYE, M. & FONTIGNIE, D. (1983): Données pétrochimiques et géochronologiques sur le magmatisme de la péninsule de Bodrum, sud-ouest de la Turquie. Eclogae geol. Helv. 76, 309-315.
38. ROBERT, F. & BROWN, A.C. (1986): Archean gold-bearing quartz veins at the Sigma mine, Abitibi greenstone belt, Quebec. II. Vein paragenesis and hydrothermal alteration. Econ. Geol. 81, 593-616.
39. ROBERT, U. & CANTAGREL, J.M. (1977): Le volcanisme basaltique dans le sud-est de la met Egée: données géochronologiques et relation avec la tectonique. Proc. Sixth Colloquium on the Geology of the Aegean Region II (Athens), 961-967.
40. SAEGUSA, N., PRICE, D.C. & SMITH, G. (1979): Analysis of the Mössbauer spectra of several iron-rich tourmalines. J. Phys. 40, 456-459.
41. SCHMIDT, M.W. & THOMPSON, A.B. (1996): Epidote in calc-alkaline magmas: an experimental study of stability, phase relationships, and the role of epidote in magmatic evolution. Am. Mineral. 81, 462-474.
42. SEYITOǦLU, G., ANDERSON, D., NOWELL, G. & SCOTT, B. (1997): The evolution from Miocene potassic to Quaternary sodic magmatism in western Turkey: implications for enrichment processes in the lithospheric mantle. J. Volcanol. Geotherm. Res. 76, 127-147.
43. SLACK, J.F. (1996): Tourmaline associations with hydrothermal ore deposits. In Boron: Mineralogy, Petrology and Geochemistry (E.S. Grew & L.M. Anovitz, eds.). Rev. Mineral. 33, 559-643.
44. ŞENGÖR, A.M.C. (1987): Cross-faults and differential stretching of hanging walls in regions of low-angle normal faulting: examples from western Turkey. In Continental Extensional Tectonics (M.P. Coward, J.E Dewey & P.L. Hancock, eds.). Geol. Soc., Spec. Publ. 28, 575-589.
45. ŞENGOR, A.M.C. & YILMAS, Y. (1981): Tethyan evolution of Turkey: a plate tectonic approach. Tectonophysics 75, 181-241.
46. TULLOCH, A.J. (1979): Secondary Ca-Al silicates as low-grade alteration products of granitoid biotite. Contrib. Mineral. Petrol. 69, 105-117.
47. WILLIAMS, W.C., MEISSI, E., MADRID, J. & DE MACHUCA, B.C. (1999): The San Jorge porphyry copper deposit, Mendoza, Argentina: a combination of orthomagmatic and hydrothermal mineralization. Ore Geol. Rev. 14. 185-201.
48. WIVEL, C. & MØRUP, S. (1981): Improved computational procedure for evaluation of overlapping hyperfine parameter distributions in Mössbauer spectra. J. Phys. E. Sci. Instrum. 14, 605-610.
49. WYBORN, D. (1994): Mantle magmatism and large gold-copper deposits. In Ore Deposit Studies and Exploration Models: Porphyry Copper-Gold Deposits. Short Course Manual. CODES, University of Tasmania, Hobart, 5.1-5.4.
50. YAVUZ, F., ISKENDEROǦLU, A. & JIANG, SHAOYONG (1999): Tourmaline compositions from the Salikvan porphyry Cu-Mo deposit and vicinity, northeastern Turkey. Can. Mineral. 37, 1007-1023.
51. ZWENG, P.L. & CLARK, A.H. (1995): Hypogene evolution of the Toquepala porphyry copper-molybdenum deposit, Moquegua, southeastern Peru. In Porphyry Copper Deposits of the American Cordillera (F.W. Pierce & J.G. Bolm, eds.). Arizona Geol. Soc. Digest 20, 566-612.