Fe-rich olenite with tetrahedrally coordinated Fe3+ from Eibenstein, Austria: Structural, chemical, and Mössbauer data

Canadian Mineralogist

Volumn 42, Issue 4, 2004, Pages 1057-1063

  Ertl, Andreas ^a   Pertlik, Franz ^a   Dyar, M Darby ^b   Prowatke, Stefan ^c   Hughes, John M ^d   Ludwig, Thomas ^c   Bernhardt, Heinz Jürgen ^e  

^a UNIVERSITY OF VIENNA   (Austria)

^b MOUNT HOLYOKE COLLEGE   (United States)

^c UNIVERSITY OF HEIDELBERG   (Germany)

^d MIAMI UNIVERSITY   (United States)

^e RUHR UNIVERSITY BOCHUM   (Germany)

Author keywords

Austria; Chemical analyses; Crystal structure; Eibenstein; Fe rich olenite; M ssbauer study

Indexed keywords

ALUMINUM; CHEMICAL ANALYSIS; LITHIUM; MANGANESE; SECONDARY ION MASS SPECTROMETRY; SILICON;

ELECTRON-MICROPROBE ANALYSIS; OLENITE; STRUCTURE REFINEMENT;

IRON;

CRYSTAL CHEMISTRY; CRYSTAL STRUCTURE; MOSSBAUER SPECTROSCOPY; OLENITE;

EID: 7944232585     PISSN: 00084476     EISSN: None     Source Type: Journal    
DOI: 10.2113/gscanmin.42.4.1057     Document Type: Article

References (34)

1. BLOODAXE, E.S., HUGHES, J.M., DYAR, M.D., GREW, E.S. & GUIDOTTI, C.V. (1999): Linking structure and chemistry in the schorl-dravite series. Am. Mineral. 84, 922-928.
2. DYAR, M.D., TAYLOR, M.E., LUTZ, T.M., FRANCIS, C.A., GUIDOTTI, C.V. & WISE, M. (1998): Inclusive chemical characterization of tourmaline: Mössbauer study of Fe valence and site occupancy. Am. Mineral. 83, 848-864.
3. DYAR, M.D., WIEDENBECK, M., ROBERTSON, D., CROSS, LR., DELANEY, J.S., FERGUSON, K., FRANCIS, C.A., GREW, E.S., GUIDOTTI, C.V., HERVIG, R.L., HUGHES, J.M., HUSLER, J., LEEMAN, W.P., MCGUIRE, A.V., RHEDE, D., ROTHE, H., PAUL, R.L., RICHARDS, I. & YATES, M. (2001): Reference minerals for the microanalysis of light elements. Geostandards Newsletter 25 441-463.
4. ERTL, A. (1995): Elbait, Olenit, Dravit-Buergerit-Mischkristalle, Dravit, Uvit und ein neuer Al-Turmalin (?) von öbsterreichischen Fundstellen. Mitt. Österr. Mineral. Ges. 140, 55-72.
5. ERTL, A., HUGHES, J.M. & MARLER, B. (2001a): Empirical formulae for the calculation of and X-O2 bond lengths in tourmaline and relations to tetrahedrally-coordinated boron. Neues Jahrb. Mineral., Monatsh., 548-557.
6. ERTL, A., HUGHES, J.M., PROWATKE, S., ROSSMAN, G.R., LONDON, D. & FRITZ, E.A. (2003): Mn-rich tourmaline from Austria: structure, chemistry, optical spectra, and relations to synthetic solid solutions. Am. Mineral. 88, 1369-1376.
7. ERTL, A., PERTLIK, F. & BERNHARDT, H.J. (1997): Investigations on olenite with excess boron from the Koralpe, Styria, Austria. Österr. Akad. Wissensch., Math.-naturw. Kl., Anz. Abt. 1, 134 3-10.
8. ERTL, A., PERTLIK, F. & BERNHARDT, H.J. (2001b): Ein hellblauer Olenit-Schörl-Dravit Mischkristall von Ebersdorf, Niederösterreich: Strukturanalyse und Chemie. Mitt. Österr. Mineral. Ges. 146, 75-77.
9. FEDERICO, M., ANDREOZZI, G.B., LUCCHESI, S., GRAZIANI, G. & CÉSAR-MENDES, J. (1998): Compositional variation of tourmaline in the granitic pegmatite dykes of the Cruzeiro mine, Minas Gerais, Brazil. Can. Mineral. 36, 415-431.
10. GRICE, J.D. & ERCIT, T.S. (1993): Ordering of Fe and Mg in the tourmaline crystal structure: the correct formula. Neues Jahrb. Mineral., Abh. 165, 245-266.
11. HAWTHORNE, F.C. (2002): Bond-valence constraints on the chemical composition of tourmaline. Can. Mineral. 40, 789-797.
12. HAWTHORNE, F.C. & HENRY, D.J. (1999): Classification of the minerals of the tourmaline group. Eur. J. Mineral. 11, 201-215.
13. HAWTHORNE, F.C., MACDONALD, D.J. & BURNS, P.C. (1993) Reassignment of cation site-occupancies in tourmaline: Al-Mg disorder in the crystal structure of dravite. Am. Mineral. 78, 265-270.
14. HUGHES, J.M., ERTL, A., DYAR, M.D., GREW, E.S., SHEARER, C.K., YATES, M.G. & GIUDOTTI, C.V. (2000): Tetrahedrally coordinated boron in a tourmaline: boron-rich olenite from Stoffhütte, Koralpe, Austria. Can. Mineral. 38, 861-868.
15. [4]B content in zoned Fe-bearing olenite from Koralpe, Austria. Am. Mineral. 89, 447-454.
16. KALT, A., SCHREYER, W., LUDWIG, T., PROWATKE, S., BERNHARDT, H.-J. & ERTL, A. (2001): Complete solid solution between magnesian schorl and lithian excess-boron olenite in a pegmatite from Koralpe (eastern Alps, Austria). Eur. J. Mineral. 13, 1191-1205.
17. LONG, G.J., CRANSHAW, T.E. & LONGWORTH, G. (1983): The ideal Mössbauer effect absorber thickness. Mössbauer Effect Ref. Data J. 6, 42-49.
18. MACDONALD, D.J. & HAWTHORNE, F.C. (1995): The crystal chemistry of Si = Al substitution in tourmaline. Can. Mineral. 33, 849-858.
19. MARLER, B., BOROWSKI, M., WODARA, U. & SCHREYER, W. (2002): Synthetic tourmaline (olenite) with excess boron replacing silicon in the tetrahedral site. II. Structure analysis. Eur. J. Mineral. 14 763-771.
20. MARLER, B. & ERTL, A. (2002): Nuclear magnetic resonance and infrared spectroscopic study of excess-boron olenite from Koralpe, Styria, Austria. Am. Mineral. 87, 364-367.
21. NOVÁK, M., SELWAY, J.B., ČERNÝ, P., HAWTHORNE, F.C. & OTTOLINI, L. (1999): Tourmaline of the elbaite-dravite series from an elbaite-subtype pegmatite at Bližná, southern Bohemia, Czech Republic. Eur. J. Mineral. 11, 557-568.
22. OTTOLINI, L., BOTTAZZI, P. & VANNUCCI, R. (1993): Quantification of lithium, beryllium, and boron in silicates by secondary ion mass spectrometry using conventional energy filtering. Anal. Chem. 65, 1960-1968.
23. PERKINS, W.T., PEARCE, N.J.G. & WESTGATE, J.A. (1997): The development of laser ablation ICP-MS and calibration strategies; examples from the analyses of trace elements in volcanic glass shards and sulfide minerals. Geostandards Newsletter 21, 115-144.
24. 3+-poor schorls: reinterpretation of the spectra on a basis of an ordered structure model. In Tourmaline '97; Int. Symp. on Tourmaline (Nové Mesto na Morave, Czech Republic), 74-75 (abstr.).
25. POUCHOU, J.L. & PICHOIR F. (1985): "PAP" procedure for improved quantitative microanalysis. Microbeam Anal. 54, 104-106.
26. PROWATKE, S., ERTL, A. & HUGHES, J.M. (2003): Tetrahedrally-coordinated Al in Mn-rich, Li- and Fe-bearing olenite from Eibenstein an der Thaya, Lower Austria: a chemical and structural investigation. Neues Jahrb. Mineral., Monatsh., 385-395.
27. RANCOURT, D.G. & PING, J.Y. (1991): Voigt-based methods for arbitrary-shape static hyperfine parameter distributions in Mö ssbauer spectroscopy. Nucl. Instrum. Methods Phys. Res. B58, 85-97.
28. SCHREYER, W., HUGHES, J.M., BERNHARDT, H.-J., KALT, A., PROWATKE, S. & ERTL, A. (2002): Reexamination of olenite from the type locality: detection of boron in tetrahedral coordination. Eur. J. Mineral. 14, 935-942.
29. SCHREYER, W., WODARA, U., MARLER, B., VAN AKEN, P.A., SEIFERT, F. & ROBERT, J.-L. (2000): Synthetic tourmaline (olenite) with excess boron replacing silicon in the tetrahedral site. 1. Synthesis conditions, chemical and spectroscopic evidence. Eur. J. Mineral. 12, 529-541.
30. 4, a new alkali-deficient tourmaline: description and crystal structure. Am. Mineral. 83 896-900.
31. SHELDRICK, G.M. (1976): Program for Crystal Structure Determination Univ. of Göttingen, Göttingen, Germany.
32. TAYLOR, M.C., COOPER, M.A. & HAWTHORNE, F.C. (1995): Local charge-compensation in hydroxyl-deficient uvite. Can. Mineral. 33, 1215-1221.
33. TINDLE, A.G., BREAKS, F.W. & SELWAY, J.B. (2002): Tourmaline in petalite- subtype granitic pegmatites: evidence of fractionation and contamination from the Pakeagama Lake and Separation Lake areas of northwestern Ontario, Canada. Can. Mineral. 40, 753-788.
34. WRIGHT, S.E., FOLEY, J.A. & HUGHES, J.M. (2000): Optimization of site occupancies in minerals using quadratic programming. Am. Mineral. 85, 524-531.