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2+ are suppressed in water, thus ruling out the assignment of the emissive MLCT band in 4 as phenanthroline-centered. (a) Durham, B.; Caspar, J. V.; Nagle, J. K.; Meyer, T. J. J. Am. Chem. Soc. 1982, 104, 4803-4810.
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note
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See Supporting Information.
-
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63
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3843101570
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-
1H NMR spectrum of dimer 6 showed the correct number of aliphatic, olefinic, and aromatic peaks, with an unusual downfield shift of both the olefin and bridgehead peaks upon dimerization. This possibly suggests the existence of tautomers of dimer 6 with unsaturation in the norbornene ring (see Supporting Information).
-
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64
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0342402449
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2+/3+ couple in dimer 6 are close in value (1.34/1.36 V). This might possibly indicate that the species is partially adsorbed onto the electrode. This phenomenon has been observed for other Ru-containing oligomers and might be due to the irreversible adsorption of some twice-reduced ruthenium onto the electrode. Abruna, H. D.; Teng, A. Y.; Samuel, G. J.; Meyer, T. J. J. Am. Chem. Soc. 1979, 101, 6745.
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