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Volumn 43, Issue 16, 2004, Pages 5112-5119

Ruthenium(II) dipyridoquinoxaline-norbornene: Synthesis, properties, crystal structure, and use as a ROMP monomer

Author keywords

[No Author keywords available]

Indexed keywords

BIPYRIDINE DERIVATIVE; DIMER; LIGAND; MONOMER; NORBORNENE DERIVATIVE; OLIGOMER; PHENANTHROLINE DERIVATIVE; QUINOXALINE DERIVATIVE; RUTHENIUM COMPLEX; RUTHENIUM DIPYRIDOQUINOXALINE NORBORNENE; SOLVENT; UNCLASSIFIED DRUG; WATER;

EID: 3843098161     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic0498438     Document Type: Article
Times cited : (29)

References (64)
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    • note
    • See Supporting Information.
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    • note
    • 1H NMR spectrum of dimer 6 showed the correct number of aliphatic, olefinic, and aromatic peaks, with an unusual downfield shift of both the olefin and bridgehead peaks upon dimerization. This possibly suggests the existence of tautomers of dimer 6 with unsaturation in the norbornene ring (see Supporting Information).
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    • 2+/3+ couple in dimer 6 are close in value (1.34/1.36 V). This might possibly indicate that the species is partially adsorbed onto the electrode. This phenomenon has been observed for other Ru-containing oligomers and might be due to the irreversible adsorption of some twice-reduced ruthenium onto the electrode. Abruna, H. D.; Teng, A. Y.; Samuel, G. J.; Meyer, T. J. J. Am. Chem. Soc. 1979, 101, 6745.
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* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.