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These bands could arise from both π-π* and n-π* transitions. See: Rillema, D. P.; Taghdiri, D. G.; Jones, D. S.; Keller, C. D.; Worl, L. A.; Meyer, T. J.; Levy, H. A. Inorg. Chem. 1987, 26, 578. Bodige, S.; Torres, A. S.; Maloney, D. J.; Tate, D.; Kinsel, G. R.; Walker, J. K.; MacDonnell, F. M. J. Am. Chem. Soc. 1997, 119, 10364.
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These bands could arise from both π-π* and n-π* transitions. See: Rillema, D. P.; Taghdiri, D. G.; Jones, D. S.; Keller, C. D.; Worl, L. A.; Meyer, T. J.; Levy, H. A. Inorg. Chem. 1987, 26, 578. Bodige, S.; Torres, A. S.; Maloney, D. J.; Tate, D.; Kinsel, G. R.; Walker, J. K.; MacDonnell, F. M. J. Am. Chem. Soc. 1997, 119, 10364.
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12944294165
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cm values in various solvents difficult.
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34
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12944290853
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note
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2+ is not possible because this complex is essentially nonluminescent.
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35
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12944282808
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53
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0000528608
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1 In addition, factors such as net charge of the molecule, nature of the ligand, and overall shape of the complex are all known to influence the propensity of a given ruthenium complex for intercalative binding with DNA (Morgan, R. J.; Chatterjee, S.; Baker, A. D.; Strekas, T. C. Inorg. Chem. 1991, 30, 2687 (and references therein)).
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58
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33751500644
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1 In addition, factors such as net charge of the molecule, nature of the ligand, and overall shape of the complex are all known to influence the propensity of a given ruthenium complex for intercalative binding with DNA (Morgan, R. J.; Chatterjee, S.; Baker, A. D.; Strekas, T. C. Inorg. Chem. 1991, 30, 2687 (and references therein)).
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12944268574
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3CN solutions of these two complexes.
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0026007185
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