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The direction of flow of electrons is formally opposite that of current, so, at V > 0, the current flows from EGaIn through the QDs to ITO, and at V < 0, the current flows from ITO through the QDs to EGaIn.
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It is possible that there is some coupling of the charge annihilation reaction to vibrational modes in the QDs, probably the long optical (LO) phonon (hω, 210 cm-1, the out-of-phase vibration of Cd and Se atoms, but, even if S, 1, this coupling (0.026 eV) is much smaller than that estimated for coupling to vibrations in the polymer [Nirmal, M, Brus, L. E. Acc. Chem. Res. 1999, 32, 407
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-1), the out-of-phase vibration of Cd and Se atoms - but, even if S = 1, this coupling (0.026 eV) is much smaller than that estimated for coupling to vibrations in the polymer [Nirmal, M.; Brus, L. E. Acc. Chem. Res. 1999, 32, 407].
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Figure 7 shows that |VON|(SSS) ∼ |V ON|(SML) > |VON|SL, We believe that, for a given |V| < |VON, the greater the resistivity of the array, the fewer electrons present at the interface between the QDs and PEDOT: PSS, and the smaller the Coulomb force that is available to precipitate annihilation of charge. Figure S4 shows that the junction SL is less resistive than SML and SSS
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ON|, the greater the resistivity of the array, the fewer electrons present at the interface between the QDs and PEDOT: PSS, and the smaller the Coulomb force that is available to precipitate annihilation of charge. Figure S4 shows that the junction SL is less resistive than SML and SSS.
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