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We preliminarily examined the Sonogashira coupling reaction catalyzed by the 2-(2-pyridyl)benzimidazole-PdCk complex. That is, when complex 1b (5 mol, CuI (12.5 mol , K3PO4 (1.1 equiv) were used, the reaction of 4-iodotoluene and ethynylbenzene proceeded to give the coupling product in 91% yield in DMF, 110°C, 4 h
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4 (1.1 equiv) were used, the reaction of 4-iodotoluene and ethynylbenzene proceeded to give the coupling product in 91% yield (in DMF, 110°C, 4 h).
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