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Volumn 26, Issue 26, 2007, Pages 6551-6555

Ligand effects of 2-(2-pyridyl)benzazole-Pd complexes on the X-ray cristallographic structures,1H NMR spectra, and catalytic activities in mizoroki-heck reactions

Author keywords

[No Author keywords available]

Indexed keywords

CATALYST ACTIVITY; LIGANDS; METAL COMPLEXES; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; PALLADIUM COMPOUNDS; X RAY CRYSTALLOGRAPHY;

EID: 38049128707     PISSN: 02767333     EISSN: None     Source Type: Journal    
DOI: 10.1021/om7008843     Document Type: Article
Times cited : (70)

References (56)
  • 3
    • 0008929363 scopus 로고    scopus 로고
    • Reports on palladium complex of 2-(2-pyridyl)benzothiazole: (a) Jindoy, L. F.; Livingstone, S. E. Inorg. Chim. Acta 1968, 119.
    • Reports on palladium complex of 2-(2-pyridyl)benzothiazole: (a) Jindoy, L. F.; Livingstone, S. E. Inorg. Chim. Acta 1968, 119.
  • 8
    • 84918728441 scopus 로고    scopus 로고
    • Other reported bidentated nitrogen-based palladium complex catalyzed Mizoroki - Heck reactions: (a) Cabri, W.; Candiani, I.; Bedeschi, A.; Santi, R. Synlett 1992, 871.
    • Other reported bidentated nitrogen-based palladium complex catalyzed Mizoroki - Heck reactions: (a) Cabri, W.; Candiani, I.; Bedeschi, A.; Santi, R. Synlett 1992, 871.
  • 24
    • 33751422553 scopus 로고    scopus 로고
    • Cui, X.; Zhou, Y.; Wang, N.; Liu, L.; Guo, Q.-X. Tetrahedron Lett. 2007, 48, 163. See also monodentate nitrogen-palladium- catalyzed Mizoroki-Heck reactions:
    • (q) Cui, X.; Zhou, Y.; Wang, N.; Liu, L.; Guo, Q.-X. Tetrahedron Lett. 2007, 48, 163. See also monodentate nitrogen-palladium- catalyzed Mizoroki-Heck reactions:
  • 40
    • 0037356545 scopus 로고    scopus 로고
    • For tridentate ligand, nitrogen-palladium-catalyzed Mizoroki-Heck reactions, see
    • For tridentate ligand, nitrogen-palladium-catalyzed Mizoroki-Heck reactions, see: Mazet, C.; Gade, L. H. Eur. J. Inorg. Chem. 2003, 1161.
    • (2003) Eur. J. Inorg. Chem , pp. 1161
    • Mazet, C.1    Gade, L.H.2
  • 44
    • 33645865241 scopus 로고    scopus 로고
    • Recent excellent review: Phan, N. T. S.; Sluys, M. V. D.; Jones, C. W. Adv. Synth. Catal. 2006, 348, 609.
    • (a) Recent excellent review: Phan, N. T. S.; Sluys, M. V. D.; Jones, C. W. Adv. Synth. Catal. 2006, 348, 609.
  • 56
    • 38049099569 scopus 로고    scopus 로고
    • We preliminarily examined the Sonogashira coupling reaction catalyzed by the 2-(2-pyridyl)benzimidazole-PdCk complex. That is, when complex 1b (5 mol, CuI (12.5 mol , K3PO4 (1.1 equiv) were used, the reaction of 4-iodotoluene and ethynylbenzene proceeded to give the coupling product in 91% yield in DMF, 110°C, 4 h
    • 4 (1.1 equiv) were used, the reaction of 4-iodotoluene and ethynylbenzene proceeded to give the coupling product in 91% yield (in DMF, 110°C, 4 h).


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