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Volumn , Issue 36, 2007, Pages 5633-5644

Synthesis, characterization, and sensitizing properties of heteroleptic RuII complexes based on 2,6-bis(1-pyrazolyl)pyridine and 2,2′-bipyridine-4,4′-dicarboxylic acid ligands

Author keywords

2,6 bis(1 pyrazolyl)pyridine; Dye sensitized solar cells; Heteroleptic RuII complexes; Protonation; Ruthenium

Indexed keywords

CHELATION; CHLORINE COMPOUNDS; DYE-SENSITIZED SOLAR CELLS; LIGANDS; MASS SPECTROMETRY; NANOCRYSTALS; NUCLEAR MAGNETIC RESONANCE SPECTROSCOPY; RUTHENIUM; RUTHENIUM COMPOUNDS; SINGLE CRYSTALS; SYNTHESIS (CHEMICAL); TITANIUM DIOXIDE; X RAY DIFFRACTION;

EID: 38049125471     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200700287     Document Type: Article
Times cited : (46)

References (83)
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    • 2) with the N719 dye gave an overall conversion efficiency of 12.23%; see: S. Ito, Md. K. Nazeeruddin, P. Liska, P. Comte, R. Charvet, P. Péchy, M. Jirousek, A. Kay, S. M. Zakeeruddin, M. Grätzel, Prog. Photovolt. Res. Appl. 2006, 14, 589-601;
    • 2) with the N719 dye gave an overall conversion efficiency of 12.23%; see: S. Ito, Md. K. Nazeeruddin, P. Liska, P. Comte, R. Charvet, P. Péchy, M. Jirousek, A. Kay, S. M. Zakeeruddin, M. Grätzel, Prog. Photovolt. Res. Appl. 2006, 14, 589-601;
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    • II complexes containing this class of planar tridentate nitrogen donor ligands are known: a D. L. Jameson, J. K. Blaho, K. T. Kruger, K. A. Goldsby, Inorg. Chem. 1989, 28, 4312-4314;
    • II complexes containing this class of planar tridentate nitrogen donor ligands are known: a) D. L. Jameson, J. K. Blaho, K. T. Kruger, K. A. Goldsby, Inorg. Chem. 1989, 28, 4312-4314;
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    • This complex was prepared by a slight modification of the published procedure and was characterized by IR spectroscopy and elevmental analysis before use in the next step
    • C. A. Bessel, R. F. See, D. L. Jameson, M. R. Churchill, K. J. Takeuchi, J. Chem. Soc., Dalton Trans. 1993, 1563-1576. This complex was prepared by a slight modification of the published procedure and was characterized by IR spectroscopy and elevmental analysis before use in the next step.
    • (1993) J. Chem. Soc., Dalton Trans , pp. 1563-1576
    • Bessel, C.A.1    See, R.F.2    Jameson, D.L.3    Churchill, M.R.4    Takeuchi, K.J.5
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    • 1H NMR spectroscopy. Work is in progress to elucidate the experimental conditions in order to avoid the formation of the side products.
    • 1H NMR spectroscopy. Work is in progress to elucidate the experimental conditions in order to avoid the formation of the side products.
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    • In the case of the previously reported [Ru(bdmpp)(NCS, dcbpyH 2, PF6) complex, the νas(NCS) band in the IR spectrum is not so strong. It appears as a shoulder indicating probably that the NCS ligand is coordinated via the sulfur atom as well. Preliminary photo-electrochemical experiments with the crystallized sample containing only the N-isomer showed an improved power conversion efficiency of η, 1.86, instead of 1.70
    • as(NCS) band in the IR spectrum is not so strong. It appears as a shoulder indicating probably that the NCS ligand is coordinated via the sulfur atom as well. Preliminary photo-electrochemical experiments with the crystallized sample containing only the N-isomer showed an improved power conversion efficiency of η = 1.86% (instead of 1.70%).
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    • [15] therein.
    • [15] therein.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.