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Volumn 43, Issue 8, 2004, Pages 2548-2555

A Luminescent Platinum(II) 2,6-Bis(N-pyrazolyl)pyridine Complex

Author keywords

[No Author keywords available]

Indexed keywords

1,6 BIS(N PYRAZOLYL)PYRIDINE; 2,6 BIS(3,5 DIMETHYL N PYRAZOLYL)PYRIDINE; CATION; LIGAND; METAL; PLATINUM COMPLEX; PYRAZOLE DERIVATIVE; PYRIDINE DERIVATIVE; UNCLASSIFIED DRUG;

EID: 1942467992     PISSN: 00201669     EISSN: None     Source Type: Journal    
DOI: 10.1021/ic035066k     Document Type: Article
Times cited : (46)

References (87)
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    • The possibility of Pt d → p transitions can be excluded on energetic grounds since these transitions in Pt(II) complexes generally occur at wavelengths shorter than 250 nm (Mason, W. R.; Gray, H. B. J. Am. Chem. Soc. 1968, 90, 5721-5729. Patterson, H. H.; Tewksbury, J. C.; Martin, M.; Krogh-Jesperson, M.-B.; LoMenzo, J. A.; Hooper, H. O.; Viswanath, A. K. Inorg. Chem. 1981, 20, 2297-2301. Roberts, D. A.; Mason, W. R.; Geoffroy, G. L. Inorg. Chem. 1981, 20, 789-796. Isci, H.; Mason, W. R. Inorg. Chem. 1984, 23, 1565-1569. Mason, W. R. Inorg. Chem. 1986, 25, 2925-2929).
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    • The possibility of Pt d → p transitions can be excluded on energetic grounds since these transitions in Pt(II) complexes generally occur at wavelengths shorter than 250 nm (Mason, W. R.; Gray, H. B. J. Am. Chem. Soc. 1968, 90, 5721-5729. Patterson, H. H.; Tewksbury, J. C.; Martin, M.; Krogh-Jesperson, M.-B.; LoMenzo, J. A.; Hooper, H. O.; Viswanath, A. K. Inorg. Chem. 1981, 20, 2297-2301. Roberts, D. A.; Mason, W. R.; Geoffroy, G. L. Inorg. Chem. 1981, 20, 789-796. Isci, H.; Mason, W. R. Inorg. Chem. 1984, 23, 1565-1569. Mason, W. R. Inorg. Chem. 1986, 25, 2925-2929).
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    • The possibility of Pt d → p transitions can be excluded on energetic grounds since these transitions in Pt(II) complexes generally occur at wavelengths shorter than 250 nm (Mason, W. R.; Gray, H. B. J. Am. Chem. Soc. 1968, 90, 5721-5729. Patterson, H. H.; Tewksbury, J. C.; Martin, M.; Krogh-Jesperson, M.-B.; LoMenzo, J. A.; Hooper, H. O.; Viswanath, A. K. Inorg. Chem. 1981, 20, 2297-2301. Roberts, D. A.; Mason, W. R.; Geoffroy, G. L. Inorg. Chem. 1981, 20, 789-796. Isci, H.; Mason, W. R. Inorg. Chem. 1984, 23, 1565-1569. Mason, W. R. Inorg. Chem. 1986, 25, 2925-2929).
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    • -1).
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    • The dσ* → π* assignment appears more likely since the energies of the emissions from tetracyanoplatinate salts with predominant lowest dσ*→ pσ excited state character only approach that observed here for very short metal⋯metal spacings ∼3.1 Å.37 The absence of a vibronic component characteristic of ligand excited-state distortion is consistent with the ∼80 K emission spectra of Pt(II) tpy dimers and linear chain compounds, in which this feature is sometimes, but not always, evident.35,36
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    • note
    • -1).


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.