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3CN) programs were used for data collection and data processing, respectively. Bruker Analytical X-ray Instruments, Inc., Madison, WI.
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SADABS was used for the application of semiempirical absorption and beam corrections for the CCD data. G. M. Sheldrick, University of Goettingen, Goettingen, Germany, 1996.
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3CN) were used for the structure solutions and generation of figures and tables. G. M. Sheldrick, University of Goettingen, Goettingen, Germany, and Siemens Analytical X-ray Instruments, Inc., Madison, WI.
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2+ (0.18 V).
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A similar band assignment has been made for a Eu(III) and Tb(III) complexes with a related ligand, 2,6-bis(3-carboxy-1-pyrazolyl)-pyridine (Remuiñán, M. J.; Román, H.; Alonso, M. T.; Rodríguez-Ubis, J. C. J. Chem. Soc., Perkins Trans. 2 1993, 1099-1102).
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The possibility of Pt d → p transitions can be excluded on energetic grounds since these transitions in Pt(II) complexes generally occur at wavelengths shorter than 250 nm (Mason, W. R.; Gray, H. B. J. Am. Chem. Soc. 1968, 90, 5721-5729. Patterson, H. H.; Tewksbury, J. C.; Martin, M.; Krogh-Jesperson, M.-B.; LoMenzo, J. A.; Hooper, H. O.; Viswanath, A. K. Inorg. Chem. 1981, 20, 2297-2301. Roberts, D. A.; Mason, W. R.; Geoffroy, G. L. Inorg. Chem. 1981, 20, 789-796. Isci, H.; Mason, W. R. Inorg. Chem. 1984, 23, 1565-1569. Mason, W. R. Inorg. Chem. 1986, 25, 2925-2929).
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