Dramatic electronic effect of fluoro substituents on the olefin polymerization activity of mono β-diiminato titanium complexes

Journal of Polymer Science, Part A: Polymer Chemistry

Volumn 46, Issue 1, 2008, Pages 211-217

  Xie, Guangyong ^a,b   Qian, Changtao ^a  

^a SHANGHAI INSTITUTE OF ORGANIC CHEMISTRY   (China)

^b SOUTH CENTRAL UNIVERSITY FOR NATIONALITIES   (China)

Author keywords

diiminato titanium complex; Catalysts; Copolymerization; Electronic effects; Fluoro substituent; Polyethylene

Indexed keywords

CHEMICAL BONDS; COMPLEXATION; COPOLYMERIZATION; POLYETHYLENES; SYNTHESIS (CHEMICAL); TITANIUM COMPOUNDS;

COMONOMER CONCENTRATIONS; DIIMINATO LIGANDS; ELECTRONIC EFFECTS; FLUORO SUBSTITUENTS;

OLEFINS;

EID: 37749038571     PISSN: 0887624X     EISSN: 10990518     Source Type: Journal    
DOI: 10.1002/pola.22373     Document Type: Article

References (34)

1. (a) Britovsek, G. J. P.; Gibson, V. C.; Wass, D. F. Angew Chem Int Ed Engl 1999, 38, 428-447;
2. (b) Gibson, V. C.; Spitzmesser, S. K. Chem Rev 2003, 103, 283-315.
3. Ittel, S. D.; Johnson, L. K.; Brookhart, M. Chem Rev 2000, 100, 1169-1204.
4. Bourget-Merle, L.; Lappert, M. F.; Severn, J. R. Chem Rev 2002, 102, 3031-3065.
5. Jin, X.; Novak, B. M. Macromolecules 2000, 33, 6205-6207.
6. Vollmerhaus, R.; Rahim, M.; Tomaszewski, R.; Xin, S. X.; Taylor, N. J.; Collins, S. Organometallics 2000, 19, 2161-2169.
7. Hayes, P. G.; Piers, W E.; Lee, L. W. M.; Knight, L. K.; Parvez, M.; Elsegood, M. R. J.; Clegg, W. Organometallics 2001, 20, 2533-2544.
8. Hayes, P. G.; Piers, W E.; McDonald, R. J Am Chem Soc 2002, 124, 2132-2133.
9. Kim, W. K; Fevola, M. J.; Liable-Sands, L. M.; Rheingold, A. L.; Theopold, K. H. Organometallics 1998, 17, 4541-1543.
10. Budzelaar, P. H. M.; van Oort, A. B.; Orpen, A. G. Eur J Inorg Chem 1998, 1485-1494.
11. Tang, L.; Duan, Y.; Li, X.; Li, Y. J Organomet Chem 2006, 691, 2023-2030.
12. Gibson, V. C.; Newton, C.; Redshaw, C.; Solan, G. A.; White, A. J. P.; Williams, D. J. Eur J Inorg Chem 2001, 1895-1903.
13. MacAdams, L. A.; Kim, W.-K.; Liable-Sands, L. M.; Guzei, I. A.; Rheingold, A. L.; Theopold, K. H. Organometallics 2002, 21, 952.
14. Chen, Y.; Qian, C.; Sun, J. Organometallics 2003, 22, 1231-1236.
15. Chen, Y.; Chen, R.; Qian, C.; Dong, X.; Sun, J. Organometallics 2003, 22, 4312-4321.
16. Kissin, Y. V.; Qian, C.; Xie, G.; Chen, Y. J Polym Sei Part A: Polym Chem 2006, 44, 6159-6170.
17. st International Conference on Organometallic Chemistry, Program and Abstract Book, P114, Vancouver, Canada, July 25-30, 2004.
18. Panda, A.; Stender, M.; Wright, R. J.; Olmstead, M. M.; Klavins, P.; Power, P. P. Inorg Chem 2002, 41, 3909-3916.
19. Budzelaar, P. H. M.; Moonen, N. N. P.; de Gelder, R.; Smits, J. M. M.; Gal, A. W. Eur J Inorg Chem 2000, 753-769.
20. Kakaliou, L.; Scanlon, W. J., IV; Qian, B.; Baek, S. W; Smith, M. R., III; Motry, D. H. Inorg Chem 1999, 38, 5964-5977.
21. Mitani, M.; Mohri, J.; Yoshida, Y.; Saito, J.; Ishii, S.; Tsuru, K.; Matsui, S.; Furuyama, R.; Nakano, T.; Tanaka, H.; Kojoh, S.; Matsugi, T.; Kashiwa, N.; Fujita, T. J Am Chem Soc 2002, 124, 3327-3336.
22. Xie, G.; Qian, C.; unpublished results.
23. Matsui, S.; Fujita, T. Catal Today 2001, 66, 63-73.
24. Hou, Z. J Synth Org Chem Jpn 2005, 63, 1124.
25. Dankova, M.; Waymouth, R. M. Macromolecules 2003, 36, 3815-3820.
26. Bruaseth, I.; Rytter, E. Macromolecules 2003, 36, 3026-3034.
27. Reybuck, S. E.; Waymouth, R. M.; Macromolecules 2004, 37, 2342-2347.
28. Hu, W.; Sun, X.; Wang, C.; Gao, Y.; Tang, Y.; Shi, L.; Xia, W.; Sun, J.; Dai, H.; Li, X.; Yao, X.; Wang, X. Organometallics 2004, 23, 1684-1688.
29. Furuyama, R.; Mitani, M.; Mohri, J.; Mori, R.; Tanaka, H.; Fujita, T. Macromolecules 2005, 38, 1546-1552.
30. Reybuck, S. E.; Lincoln, A. L.; Ma, S.; Waymouth, R. M. Macromolecules 2005, 38, 2552-2558.
31. Wang, C.; Sun, X.; Guo, Y.; Gao, Y.; Liu, B.; Ma, Z.; Xia, W.; Shi, L.; Tang Y. Macromol Rapid Commun 2005, 26, 1609-1614.
32. Cho, D. J.; Wu, C. J.; Sujith, S.; Han, W.; Kang, S. O.; Lee, B. Y. Organometallics 2006, 25, 2133-2134.
33. Hsieh, E. T.; Randall, J. C. Macromolecules 1982, 15, 1402.
34. Randall, J. C. J Macromol Sci Rev Macromol Chem Phys 1989, 29, 201.