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Volumn 38, Issue 5, 2005, Pages 1546-1552

Ethylene/higher α-olefin copolymerization behavior of fluorinated bis(phenoxy-imine)titanium complexes with methylalumoxane: Synthesis of new polyethylene-based block copolymers

Author keywords

[No Author keywords available]

Indexed keywords

BLOCK COPOLYMERS; CATALYSIS; COMPLEXATION; COPOLYMERIZATION; DIFFERENTIAL SCANNING CALORIMETRY; ETHYLENE; MOLECULAR WEIGHT; POLYETHYLENES; PROBABILITY DENSITY FUNCTION; SYNTHESIS (CHEMICAL);

EID: 15244360709     PISSN: 00249297     EISSN: None     Source Type: Journal    
DOI: 10.1021/ma0481104     Document Type: Article
Times cited : (136)

References (69)
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    • For a recent review see: Coates, G. W.; Hustad, P. D.; Reinartz, S. Angew. Chem., Int. Ed. 2002, 41, 2236-2257. For living olefin polymerization with phenoxy-based catalysts, see: Suzuki, Y.; Terao, H.; Fujita, T. Bull. Chem. Soc. Jpn. 2003, 76, 1493-1517.
    • (2002) Angew. Chem., Int. Ed. , vol.41 , pp. 2236-2257
    • Coates, G.W.1    Hustad, P.D.2    Reinartz, S.3
  • 4
    • 0042763632 scopus 로고    scopus 로고
    • For a recent review see: Coates, G. W.; Hustad, P. D.; Reinartz, S. Angew. Chem., Int. Ed. 2002, 41, 2236-2257. For living olefin polymerization with phenoxy-based catalysts, see: Suzuki, Y.; Terao, H.; Fujita, T. Bull. Chem. Soc. Jpn. 2003, 76, 1493-1517.
    • (2003) Bull. Chem. Soc. Jpn. , vol.76 , pp. 1493-1517
    • Suzuki, Y.1    Terao, H.2    Fujita, T.3
  • 5
    • 0013217248 scopus 로고    scopus 로고
    • Recent advances in the rational design of catalysts for living olefin polymerization have allowed the catalytic production of living-polymerization- based polymers; see; Mitani, M.; Mohri, J.; Furuyama, R.; Ishii, S.; Fujita, T. Chem. Lett. 2003, 32, 238-239.
    • (2003) Chem. Lett. , vol.32 , pp. 238-239
    • Mitani, M.1    Mohri, J.2    Furuyama, R.3    Ishii, S.4    Fujita, T.5
  • 43
    • 0003476960 scopus 로고
    • PCT international application 9112285
    • (d) Turner, H. W.; Hlatky, G. G. (Exxon). PCT International Application 9112285,1991; Chem. Abstr. 1992, 116, 61330t.
    • (1991) Chem. Abstr. , vol.116
    • Turner, H.W.1    Hlatky, G.G.2
  • 67
    • 15244363114 scopus 로고    scopus 로고
    • US Pat. 6562930, (filing date Sept 18, 2001)
    • Coates, G. W.; Tian, J.; Hustad, P. D. US Pat. 6562930, 2003 (filing date Sept 18, 2001).
    • (2003)
    • Coates, G.W.1    Tian, J.2    Hustad, P.D.3
  • 68
    • 15244361874 scopus 로고    scopus 로고
    • note
    • 2-symmetric isomer.
  • 69
    • 15244360038 scopus 로고    scopus 로고
    • note
    • It has been demonstrated that, although the first discovery of the living behavior was made with a pentafluorinated version of the catalysts (see ref 4f), only a single o-F is a requirement for the living polymerization of ethylene, and the corresponding non-F and o-methylated versions do not promote living ethylene polymerization under identical conditions (see refs 4g and 10c). These results indicate that steric factors do not play a key role in the achievement of living ethylene polymerization.


* 이 정보는 Elsevier사의 SCOPUS DB에서 KISTI가 분석하여 추출한 것입니다.