Formation of unprecedented actinide≡carbon triple bonds in uranium methylidyne molecules

Proceedings of the National Academy of Sciences of the United States of America

Volumn 104, Issue 48, 2007, Pages 18919-18924

  Lyon, Jonathan T ^a   Hu, Han Shi ^b   Andrews, Lester ^a   Li, Jun ^b  

^a UNIVERSITY OF VIRGINIA   (United States)

^b Tsinghua University   (China)

Author keywords

Actinide multiple bond; Heavy element; Laser ablation; Matrix isolation; Relativistic quantum chemistry

Indexed keywords

ACTINIDE; CARBON; FLUORIDE; TRIHALOMETHANE; URANIUM DERIVATIVE;

ARTICLE; CHEMICAL BOND; CHEMICAL REACTION; ELECTRON; INFRARED SPECTROSCOPY; OXIDATION; PRIORITY JOURNAL; QUANTUM CHEMISTRY;

EID: 37649020164     PISSN: 00278424     EISSN: 10916490     Source Type: Journal    
DOI: 10.1073/pnas.0707035104     Document Type: Article

References (65)

1. Lewis GN (1916) J Am Chem Soc 38:762-785.
2. Pauling L (1964) Nature 203:182-183.
3. Cotton FA, Curtis NF, Harris CB, Johnson BFG, Lippard SJ, Mague JT, Robinson WR, Wood JS (1964) Science 145:1305-1307.
4. Fischer EO (1976) Adv Organometallic Chem 14:1-32.
5. Schrock RR (1983) Science 219:13-18.
6. Lee M, Lenman M, Banas A, Bafor M, Singh S, Schweizer M, Nilsson R, Liljenberg C, Dahlqvist A, Gummeson PO, et al. (1998) Science 280:915-918.
7. Sekiguchi A, Kinjo R, Ichinohe M (2004) Science 305:1755-1757.
8. Cotton FA, Nocera DG (2000) Acc Chem Res 33:483-490.
9. Suzuki N, Nishiura M, Wakatsuki Y (2002) Science 295:660-663.
10. Frenking G (2005) Science 310:796-797.
11. Nguyen T, Sutton AD, Brynda M, Fettiger JC, Long GJ, Power PP (2005) Science 310:844-847.
12. Piro NA, Figueroa JS, McKellar JT, Cummins CC (2006) Science 313:1276-1279.
13. Radius U, Breher F (2006) Angew Chem Int Ed 45:3006-3010.
14. Berry JF, Bill E, Bothe E, Geoge SD, Mienert B, Neese F, Wieghardt K (2006) Science 312:1937-1941.
15. Mindiola DJ (2006) Acc Chem Res 39:813-821.
16. Cummins CC (2006) Angew Chem Int Ed 45:862-870.
17. Pyykkö P, Riedel S, Patzschke M (2005) Chem Eur J 11:3511-3520.
18. Gagliardi L, Roos BO (2005) Nature 433:848-851.
19. Straka M, Pyykkö P (2005) J Am Chem Soc 127:13090-13091.
20. Cavigliasso G, Kaltsoyannis N (2006) Inorg Chem 45:6828-6839.
21. Frenking G, Tonner R (2007) Nature 446:276-277.
22. Burns CJ (2005) Science 309:1823-1824.
23. Arney DSJ, Burns CJ, Smith DC (1992) J Am Chem Soc 114:10068-10069.
24. Hayton TW, Boncella JM, Scott BL, Palmer PD, Batista ER, Hay PJ (2005) Science 310:1941-1943.
25. Castro-Rodriguez I, Nakai H, Zakharov LN, Rheingold AL, Meyer K (2004) Science 305:1757-1759.
26. Evans WJ, Kozimor SA, Ziller JW (2005) Science 309:1835-1838.
27. Gagliardi L, Pyykkö P (2004) Angew Chem Int Ed 43:1573-1576.
28. Ephritikhine M (2006) Dalton Trans 2501-2516.
29. Brennan JG, Andersen RA (1985) J Am Chem Soc 107:514-516.
30. Arney DS, Burns CJ, Schnabel RC (1996) J Am Chem Soc 118:6780-6781.
31. Green DW, Reedy GT (1976) J Chem Phys 65:2921-2922.
32. Li J, Bursten BE, Liang B, Andrews L (2002) Science 295:2242-2245.
33. Zhou M, Andrews L (1999) J Chem Phys 111:11044-11049.
34. Pepper M, Bursten BE (1991) Chem Rev 91:719-741.
35. Clark DL (2000) Los Alamos Sci 26:364-381.
36. Schrock RR (2002) Chem Rev 102:145-179.
37. Andrews L, Cho HG (2006) Organometallics 25:4040-4053.
38. Andrews L, Cho HG (2005) J Phys Chem A 109:6796-6798.
39. Lyon JT, Andrews L (2005) Inorg Chem 44:8610-8616.
40. Lyon JT, Andrews L (2005) Inorg Chem 45:1847-1852.
41. Lyon JT, Andrews L, Malmqvist PÅ, Roos BO, Wang T, Bursten BE (2006) Inorg Chem 46:4917-4925.
42. Cho HG, Andrews L (2005) Chem Eur J 11:5017-5023.
43. Cho HG, Andrews L (2005) J Am Chem Soc 127:8226-8231.
44. Cho HG, Andrews L (2005) Organometallics 24:5678-5685.
45. Cho HG, Andrews L, Marsden C (2005) Inorg Chem 44:7634-7643.
46. Cho HG, Andrews L (2006) J Phys Chem A 110:13151-13163.
47. Lyon JT, Andrews L (2007) Organometallics 26:2519-2527.
48. Lyon JT, Cho HG, Andrews L, Hu HS, Li J (2007) Inorg Chem 46:8728-8738.
49. Souter PF, Kushto GP, Andrews L, Neurock M (1997) J Am Chem Soc 119:1682-1687.
50. Andrews L, Citra A (2002) Chem Rev 102:885-911.
51. Perdew JP, Wang Y (1992) Phys Rev B 45:13244-13249.
52. te Velde G, Bickelhaupt FM, van Gisbergen SJA, Guerra CF, Baerends EJ, Snijders JG, Ziegler T (2001) J Comput Chem 22:931-967.
53. van Lenthe E, Baerends EJ, Snijders JG (1993) J Chem Phys 99:4597-4610.
54. Raghavachari K, Trucks GW, Pople JA, Head-Gordon M (1989) Chem Phys Lett 157:479-483.
55. Küchle W, Dolg M, Stoll H, Preuss H (1994) J Chem Phys 100:7535-7542.
56. Ditchfield R, Hehre WJ, Pople JA (1971) J Chem Phys 54:724-728.
57. Hunt RD, Thompson C, Hassanzadeh P, Andrews L (1994) Inorg Chem 33:388-391.
58. Lyon JT, Andrews L (2006) Inorg Chem 45:9858-9863.
59. 4).
60. Reed AE, Curtiss LA, Weinhold F (1988) Chem Rev 88:899-926.
61. Cramer RE, Maynard RB, Paw JC, Gilje JW (1981) J Am Chem Soc 103:3589-3590.
62. Becke AD, Edgecombe KE (1990) J Chem Phys 92:5397-5403.
63. Silvi B, Savin A (1994) Nature 371:683-686.
64. Tatsumi K, Hoffmann R (1980) J Am Chem Soc 19:2656-2658.
65. Kaltsoyannis N (2003) Chem Soc Rev 32:9-16.