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2, 50 g, $19.90 (223883).
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2, 50 g, $19.90 (223883).
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78
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37249013594
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Refer to the Supporting Information for a tabular comparison of the reactivities of the dienyl azides with Cu(OTf)2 and Rh 2(O2CC3F7)4 catalysts
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4 catalysts.
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8d: Lakhlifi, T.; Sedqui, A.; Fathi, T.; Laude, B.; Robert, J.-F. Can. J. Chem. 1994, 72, 1417.
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8g: Pale-Grosdemange C.; Chuche, J. Tetrahedron 1989, 45, 3397.
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86
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37249073632
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1,2-Alkyl shifts were observed in the thermal nitrene variant of this reaction; see ref 11c
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1,2-Alkyl shifts were observed in the thermal nitrene variant of this reaction; see ref 11c.
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87
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37249028423
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3 produced pyrroles (8a-e) quantitatively.
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3 produced pyrroles (8a-e) quantitatively.
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10944234984
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For recent reviews on the formation and reactivity of metal nitrenoids formed from the reaction of metal complexes and azides, see: (a) Katsuki, T. Chem. Lett. 2005, 34, 1304.
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