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1
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(e) Leung, S. K.-A; Tsui, W. M.; Huang, J. S.; Che, C.-M.; Liang, J. L.; Zhu, N. J. Am. Chem. Soc. 2005, 127, 16629.
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Espino, C.G.1
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For oxidative coupling of amines and aldehydes; a
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For oxidative coupling of amines and aldehydes; (a) Marko, I. E.; Mekhalfia, A. Tetrahedron Lett. 1990, 31, 7237.
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Marko, I.E.1
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33845401262
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For oxidative coupling of sulfonamides and aldehydes: a
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For oxidative coupling of sulfonamides and aldehydes: (a) Vogt, H.; Baumann, T.; Nieger, M.; Bräse, S. Eur. J. Org. Chem. 2006, 5315.
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Eur. J. Org. Chem
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Vogt, H.1
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(b) Baumann, T.; Bächle, M.; Bräse, S. Org. Lett. 2006, 8, 3797.
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Espino, C. G.; Fiori, K. W.; Kim, M.; Du Bois, J. J. Am. Chem. Soc. 2004, 126, 15378.
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21
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36448952901
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Benzaldehyde was found to oxidize to benzoic acid under the reaction conditions
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Benzaldehyde was found to oxidize to benzoic acid under the reaction conditions.
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22
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36448941649
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A reaction run in the absence of aldehyde with p-toluenesulfonamide exhibited decomposition <15 min at 50°C.
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A reaction run in the absence of aldehyde with p-toluenesulfonamide exhibited decomposition <15 min at 50°C.
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23
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0000886888
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Davis, F. A.; Chattopadhyay, S.; Towson, J. C.; Lal, S. L.; Reddy, T. J. Org. Chem. 1988, 53, 2087.
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24
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36448996434
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1H NMR.
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1H NMR.
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25
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0042998747
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(a) Müller, P.; Baud, C.; Jacquier, Y.; Moran, M.; Nägeli, I. J. Phys. Org. Chem. 1996, 9, 341.
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(b) Müller, P.; Baud, C.; Nägeli, I. J. Phys. Org. Chem. 1998, 11, 597.
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(c) Zhang, J.; Chan, P. W. H.; Che, C.-M. Tetrahedron Lett. 2005, 46, 5403.
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Zhang, J.1
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29
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36448978104
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Competition of p-anisaldehyde and benzaldehyde in the amidation of ethyl benzene afforded a 5:1 increase in relative rate.
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Competition of p-anisaldehyde and benzaldehyde in the amidation of ethyl benzene afforded a 5:1 increase in relative rate.
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30
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36448941020
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In the process of obtaining a direct Hammett correlation, we found no significant rate changes with p-Cl, p-tBu, or p-CN, see Supporting Information
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tBu, or p-CN. (see Supporting Information.)
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31
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33646230522
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-1 (ref 10b)). See also: Griller, D.; Ingold, K. U. Acc. Chem. Res. 1980, 13, 317.
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-1 (ref 10b)). See also: Griller, D.; Ingold, K. U. Acc. Chem. Res. 1980, 13, 317.
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32
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36448965444
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Reactivity was still observed when BHT (1 equiv) was introduced to the coupling of benzene sulfonamide (1a) and benzaldehyde.
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Reactivity was still observed when BHT (1 equiv) was introduced to the coupling of benzene sulfonamide (1a) and benzaldehyde.
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33
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0038321455
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Nägeli, I.; Bernardinelli, G.; Jacquier, Y.; Moran, M.; Müller, P. Helv. Chim. Acta 1997, 80, 1087.
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Nägeli, I.1
Bernardinelli, G.2
Jacquier, Y.3
Moran, M.4
Müller, P.5
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