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The crystal structure of 3 has already been reported in two different contexts: (i) at low temperature in the search for a typical hydrogen bonding and (ii) at room temperature where 3 is considered as a promising synthon for oligonuclear synthesis: a) T. Steiner, M. Tamm, A. Grzegorzewski, N. Schulte, N. Veldman, A. M. M. Schreurs, J. A. Kanters, J. Kroon, J. van der Maas, B. Lutz, J. Chem. Soc. Perkin Trans. 2 1996, 2441-2446;
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The crystal structure of 3 has already been reported in two different contexts: (i) at low temperature in the search for a typical hydrogen bonding and (ii) at room temperature where 3 is considered as a promising synthon for oligonuclear synthesis: a) T. Steiner, M. Tamm, A. Grzegorzewski, N. Schulte, N. Veldman, A. M. M. Schreurs, J. A. Kanters, J. Kroon, J. van der Maas, B. Lutz, J. Chem. Soc. Perkin Trans. 2 1996, 2441-2446;
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40
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[23], some metric parameters along with the crystal data are given in the Supporting Information.
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[23], some metric parameters along with the crystal data are given in the Supporting Information.
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The same rearrangement reaction has been encountered upon treatment of (dibromovinyl)[2.2]paracyclophane with an excess of sodium p-toluenethiolate, which affords the crystallographically characterised dithioether compound (Z)-[(p-tol-S)(H)-C=C(S-p-tol)(PCP)] (PCP = [2.2]paracyclophane) (S. Clément, M. Knorr, L. Guyard, C. Strohmann, manuscript in preparation).
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The same rearrangement reaction has been encountered upon treatment of (dibromovinyl)[2.2]paracyclophane with an excess of sodium p-toluenethiolate, which affords the crystallographically characterised dithioether compound (Z)-[(p-tol-S)(H)-C=C(S-p-tol)(PCP)] (PCP = [2.2]paracyclophane) (S. Clément, M. Knorr, L. Guyard, C. Strohmann, manuscript in preparation).
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