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35948952107
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2 coalesced at -15 and 25°C, respectively.
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2 coalesced at -15 and 25°C, respectively.
-
-
-
-
89
-
-
35948971882
-
-
2.
-
2.
-
-
-
-
91
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-
35948943204
-
-
If the aggregates consist of n pieces (n ≥ 3) of sulfinylporphyrins, more than one pair of S-oxo-linked diastereomers can be formed. The spectra shown in Figures 1b and 2b imply that the contribution of cyclic, linear, or branched higher oligomers is negligible in solution.
-
If the aggregates consist of n pieces (n ≥ 3) of sulfinylporphyrins, more than one pair of S-oxo-linked diastereomers can be formed. The spectra shown in Figures 1b and 2b imply that the contribution of cyclic, linear, or branched higher oligomers is negligible in solution.
-
-
-
-
92
-
-
35948933976
-
-
It is well-known that the meso-phenyl rings of tetraphenylporphyrin are not on the same plane of the porphyrin ring due to steric repulsion with neighboring β protons.
-
It is well-known that the meso-phenyl rings of tetraphenylporphyrin are not on the same plane of the porphyrin ring due to steric repulsion with neighboring β protons.
-
-
-
-
93
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0035927420
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In the primary electron donor P700 of cyanobacterial photosystem I, two chlorin planes of a chlorophyll pair are parallel at an interplanar distance of 3.6 Å and partially overlapping with a center-to-center distance of 6.3 Å; see: P. Jordan, P. Fromme, H. T. Witt, O. Klukas, W. Saenger, N. Krauß, Nature 2001, 411, 909
-
In the primary electron donor P700 of cyanobacterial photosystem I, two chlorin planes of a chlorophyll pair are parallel at an interplanar distance of 3.6 Å and partially overlapping with a center-to-center distance of 6.3 Å; see: P. Jordan, P. Fromme, H. T. Witt, O. Klukas, W. Saenger, N. Krauß, Nature 2001, 411, 909.
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94
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0001255839
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For examples, see: a
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For examples, see: a) S. Matile, N. Berova, K. Nakanishi, S. Novkova, I. Philipova, B. Blagoev, J. Am. Chem. Soc. 1995, 117, 7021;
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102
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0000328540
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-
For discussions on the excitonic coupling of covalently and noncovalently linked porphyrin dimers, see: a
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For discussions on the excitonic coupling of covalently and noncovalently linked porphyrin dimers, see: a) R. R. Bucks, S. G. Boxer, J. Am. Chem. Soc. 1982, 104, 340;
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105
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35948973655
-
-
-1, were deconvoluted into three Gaussian bands and analyzed by ORIGIN.
-
-1, were deconvoluted into three Gaussian bands and analyzed by ORIGIN.
-
-
-
-
106
-
-
5844252510
-
-
T values of dichloromethane and toluene are 40.7 and 33.9, respectively; see: C. Reichardt, Chem. Rev. 1994, 94, 2319.
-
T values of dichloromethane and toluene are 40.7 and 33.9, respectively; see: C. Reichardt, Chem. Rev. 1994, 94, 2319.
-
-
-
-
107
-
-
35948952504
-
-
3 at 25°C; see reference [4].
-
3 at 25°C; see reference [4].
-
-
-
-
108
-
-
35948931503
-
-
This value is close to the association constant of (S)-4Zn- OSPh2 adduct (49 M-1 in toluene at 25°C) determined by competitive titration; see Experimental Section
-
-1 in toluene at 25°C) determined by competitive titration; see Experimental Section.
-
-
-
-
109
-
-
35948993537
-
-
In the electrochemical measurements, the racemates of 4Zn and 5Zn were used. Thus, the voltammograms depicted in Figure 8 and Figure S14 of the Supporting Information are superimpositions of those of the homo- and heterodimers, although the differences in their oxidation potentials are considered to be very small
-
In the electrochemical measurements, the racemates of 4Zn and 5Zn were used. Thus, the voltammograms depicted in Figure 8 and Figure S14 of the Supporting Information are superimpositions of those of the homo- and heterodimers, although the differences in their oxidation potentials are considered to be very small.
-
-
-
-
110
-
-
0000584154
-
-
the authors systematically investigated the electrochemical and spectroscopic properties of two families of dimeric porphyrins and revealed the important role of electronic π-π interactions in their mixed-valence behavior
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Y. Le Mest, M. L'Her, N. H. Hendricks, K. Kim, J. P. Collman, Inorg. Chem. 1992, 31, 835; the authors systematically investigated the electrochemical and spectroscopic properties of two families of dimeric porphyrins and revealed the important role of electronic π-π interactions in their mixed-valence behavior.
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111
-
-
35948996274
-
-
[4f] The oxidation potentials of 4Zn and 5Zn versus SCE were calculated to be +0.77, +1.02, +1.20 V and +0.75, +1.01, +1.19 V, respectively.
-
[4f] The oxidation potentials of 4Zn and 5Zn versus SCE were calculated to be +0.77, +1.02, +1.20 V and +0.75, +1.01, +1.19 V, respectively.
-
-
-
-
112
-
-
35948986874
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SPECFIT Global Analysis System 2.10 (Rev. X), Spectrum Software Associates, Chapel Hill, NC (USA)
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R. A. Binstead, A. D. Zuberbühler, SPECFIT Global Analysis System 2.10 (Rev. X), Spectrum Software Associates, Chapel Hill, NC (USA), 1998.
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35948931897
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