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3-. In Noyori's proposal, the aggregation state is unknown.
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9- has been characterized by X-ray analysis and found to be reactive in the epoxidation of 2-cyclohexenol. See: Server-Carrió, J.; Bas-Serra, J.; Gonzàlez-Nuñez, M. E.; Garcìa-Gastaldi, A.; Jameson, G. B.; Baker, L. C. W.; Acerete, R. J. Am. Chem. Soc. 1999, 121, 977-984.
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23
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9644307998
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The catalytic activity of the lacunary complex is highly dependent on the pH at which it is isolated. For a discussion on the speculated structure of the active catalyst, see: Musaev, D. G.; Morokuma, K.; Geletii, Y. V.; Hill, C. L. Inorg. Chem. 2004, 43, 7702-7708.
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33748609212
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12- derivatives under MW-assisted catalysis.
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38
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41
-
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33748598563
-
-
note
-
3CN (0.6 mL), T = 50 °C.
-
-
-
-
42
-
-
0028880644
-
-
Analogous LFE correlations, obtained for a series of electrophilic peroxides, yield ρ values close to -1. See: (a) Bonchio, M.; Campestrini, S.; Conte, V.; Di Furia, F.; Moro, S. Tetrahedron 1995, 51, 12363-12372.
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44
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33646076936
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Lindsay Smith, J. R.; Gilbert, B. C.; Mairata i Payeras, A.; Murray, J.; Lowdon, T. R.; Oakes, J.; Pons i Prats, R.; Walton, P. H. J. Mol. Catal. A: Chem. 2006, 251, 114-122 and references therein.
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45
-
-
33748618802
-
-
note
-
-1 M; reaction conditions and saturation plot are included in Supporting Information.
-
-
-
-
46
-
-
33748621875
-
-
note
-
3-.
-
-
-
-
47
-
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33746551813
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Prabhakar, R.; Morokuma, K.; Hill, C. L.; Musaev, D. G. Inorg. Chem. 2006, 45, 5703-5709.
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48
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33645097189
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8c See also: Goto, Y.; Kamata, K.; Yamaguchi, K.; Uehara, K.; Hikichi, S.; Mizuno, N. Inorg. Chem. 2006, 45, 2347-2356 and references therein.
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49
-
-
33748584164
-
-
note
-
3CN = 0.5 mL, 72 h at T = -10 °C.
-
-
-
|