Synthesis and characterization of bis(dithiolene) tungsten(VI), -(V), and -(IV) complexes and their reactivities in coupled electron-proton transfer: A new series of active site models of tungstoenzymes

European Journal of Inorganic Chemistry

Volumn , Issue 29, 2007, Pages 4663-4668

  Sugimoto, Hideki ^a   Tarumizu, Makoto ^a   Miyake, Hiroyuki ^a   Tsukube, Hiroshi ^a  

^a Osaka Prefecture University   (Japan)

Author keywords

Bioinorganic chemistry; Enzyme models; Molybdenum; S ligands; Tungsten

Indexed keywords

ACTIVATION ENERGY; BIOCHEMISTRY; CHELATION; CHLORINE COMPOUNDS; CRYSTAL STRUCTURE; ISOMERIZATION; ISOMERS; LIGANDS; MOLECULES; MOLYBDENUM; PROTON TRANSFER; SPECTRUM ANALYSIS; SYNTHESIS (CHEMICAL); TEMPERATURE;

ACTIVE-SITE MODELING; BENZENEDITHIOLATE; BIOINORGANIC CHEMISTRY; DITHIOLENE; ELECTRON-PROTON TRANSFERS; ENZYME MODELS; ISOMERISATION; PROTON TRANSFER PROCESS; S LIGANDS; SYNTHESIS AND CHARACTERIZATIONS;

TUNGSTEN COMPOUNDS;

EID: 35349027221     PISSN: 14341948     EISSN: 10990682     Source Type: Journal    
DOI: 10.1002/ejic.200700602     Document Type: Article

References (33)

1. a) R. Hille, Chem. Rev. 1996, 96, 2757-2816;
2. b) M. K. Johnson, D. C. Rees, M. W. W. Adams, Chem. Rev. 1996, 96, 2817-2839;
3. c) S. J. N. Burgmayer, Prog. Inorg. Chem. 2004, 52, 491-532.
4. a) S. K. Das, D. Biswas, R. Maiti, S. Sarkar, J. Am. Chem. Soc. 1996, 118, 1387-1397;
5. b) E. S. Davis, G. M. Aston, R. L. Beddoes, D. Collison, A. Dinsmore, A. Docrat, J. A. Joule, C. R. Wilson, C. D. Garner, J. Chem. Soc. Dalton Trans. 1998, 3647-3656;
6. c) J. Jiang, R. H. Holm, Inorg. Chem. 2004, 43, 1302-1310;
7. d) J. H. Enemark, J. J. A. Cooney, J.-J. Wang, R. H. Holm, Chem. Rev. 2004, 104, 1175-1200;
8. e) J. McMaster, J. M. Tunney, C. D. Garner, Prog. Inorg. Chem. 2004, 52, 539-583.
9. Authors' examples: f) H. Sugimoto, M. Harihara, M. Shiro, K. Sugimoto, K. Tanaka, H. Miyake, H. Tsukube, Inorg. Chem. 2005, 44, 6386-6392;
10. g) H. Sugimoto, T. Sakurai, H. Miyake, K. Tanaka, H. Tsukube, Inorg. Chem. 2005, 44, 6927-6929;
11. h) H. Sugimoto, R. Tajima, T. Sakurai, H. Ohi, H. Miyake, S. Itoh, H. Tsukube, Angew. Chem. Int. Ed. 2006, 45, 3520-3522.
12. a) M. K. Chan, S. Mukund, A. Kletzin, M. W. W. Adams, D. C. Rees, Science 1995, 267, 1463-1469;
13. b) H. Schindelin, C. Kisker, J. Hilton, K. V. Rajagopalan, D. C. Rees, Science 1996, 272, 1615-1621;
14. c) Y. Hu, S. Faham, R. Roy, M. W. W. Adams, D. C. Rees, J. Mol. Biol. 1999, 286, 899-914;
15. d) J. M. Dias, M. E. Than, A. Humm, R. Huber, G. P. Bourenkov, H. D. Bartunik, S. Bursakov, J. Calvete, J. Caldeira, C. Carneiro, J. J. G. Moura, I. Moura, M. J. Romao, Structure 1999, 7, 65-79;
16. e) H.-K. Li, C. Temple, K. V. Rajagopalan, H. Schindelin, J. Am. Chem. Soc. 2000, 122, 7673-7680;
17. f) L. J. Stewart, S. Bailey, B. Bennett, J. M. Charnock, C. D. Garner, A. S. McAlpine, J. Mol. Biol. 2000, 299, 593-600.
18. a) C. E. Edwin, M. B. Hall, J. Am. Chem. Soc. 2001, 123, 5820-5821;
19. b) A. Thapper, R. J. Deeth, E. Nordlander, Inorg. Chem. 2002, 41, 6695-6702;
20. c) M. Kaupp, Angew. Chem. Int. Ed. 2004, 43, 546-549;
21. d) J. P. McNamara, J. A. Joule, I. H. Hiller, C. D. Garner, Chem. Commun. 2005, 177-179.
22. H. Sugimoto, M. Tarumizu, K. Tanaka, M. Miyake, H. Tsukube, Dalton Trans. 2005, 3558-3564.
23. H. Sugimoto, M. Tarumizu, H. Miyake, H. Tsukube, Eur. J. Inorg. Chem. 2006, 4494-4497.
24. H. Sugimoto, Y. Furukawa, M. Tarumizu, H. Miyake, K. Tanaka, H. Tsukube, Eur. J. Inorg. Chem. 2005, 3088-3091.
25. N. Ueyama, H. Oku, A. Nakamura, J. Am. Chem. Soc. 1992, 114, 7310-7311.
26. H. Oku, N. Ueyama, A. Nakamura, Bull. Chem. Soc. Jpn. 1996, 69, 3139-3150.
27. K.-M. Sung, R. H. Holm, Inorg. Chem. 2001, 40, 4518-4525.
28. C. Lorber, J. P. Donahue, C. A. Goddard, E. Nordlander, R. H. Holm, J. Am. Chem. Soc. 1998, 120, 8102-8112.
29. 2[4] were employed.
30. R. J. Abraham, J. Fisher, P. Loftus, Introduction to NMR Spectroscopy, John Wiley & Sons Ltd., England, 1988.
31. A. Altomare, M. Burla, M. Camalli, G. Cascarano, C. Giacovazzo, A. Guagliardi, A. Moliterni, G. Polidori, R. Spagna, J. Appl. Crystallogr. 1999, 32, 115-119.
32. P. T. Beurskens, G. Admiraal, G. Beurskens, W. P. Bosman, R. de Gelder, R. Israel, J. M. M. Smits, 1999. The DIRDIF-99 program system, Technical Report of the Crystallography Laboratory, University of Nijmegen, The Netherlands.
33. Crystal Structure Analysis Package, Rigaku and Rigaku/MSC, 2000-2004, 9009 New Trails Dr., The Woodlands, TX 77381, US.